Light emitting diode

[0002] This application claims the priority benefit of Taiwan application serial no. 90101241, filed Jan. 19, 2001.

[0003] 1. Field of Invention

[0004] The present invention relates to light emitting device. More particularly, the present invention relates to a structure of light emitting diode having a superlattices contact layer. The light emitting diode is a nitride-base III-N group compound semiconductor device.

[0005] 2. Description of Related Art

[0006] In recent years, gallium nitride-based III-N group compound semiconductor device, such as GaN, GaAlN, and GaInN, has been greatly taken as a light emitting device. FIG. 1 is a cross-sectional view, schematically illustrating structure of a conventional light emitting diode made of III-N group compound.

[0007] In FIG. 1, the light emitting diode is formed on a substrate 10, such as an Al₂O₃substrate. A nucleation layer 12 and an N-type conductive buffer layer 14 are sequentially formed over the substrate 10. The buffer layer 14 includes GaN doped with N-type dopant, so as to ease the crystal growth for the subsequent crystal growing process. There is a light-emitting active layer 18 over the buffer layer 14. Usually, the active layer 18 is confined by a confinement layer, that is, cladding layers 16, 20. The cladding layers 16, 20 are doped with opposite conductive type. For example, if the lower cladding layer 16 is the GaN layer doped with N-type dopants, the upper cladding layer 20 is the GaN layer doped with P-type dopants. Then, a contact layer 22 is formed on the upper cladding layer 20. The contact layer 22 a P-type GaN layer. A transparent electrode layer 24 is formed on the contact layer 22, where the transparent electrode layer usually includes a N-type material layer, such as indium tin oxide (ITO), cadmium tin oxide (CTO), or ultra-thin metal. The transparent electrode serves as an anode of the diode. Moreover, an electrode layer 26, serving as a cathode of the diode, is also formed on the buffer layer 14 but is separated from the cladding layers 16, 20 and the active layer 18.

[0008] FIG. 2 is a cross-sectional views, schematically illustrating a light emitting region for the light emitting diode in FIG. 1. In FIG. 2, when the electrodes 24, 26 are applied with a forward bias, the diode is conducted. At this situation, current can flow from the electrode 24 to the active layer 18. In the conventional manner, the P-type contact layer 22 of GaN cannot have high carrier concentration and has large contact resistance. This results in a poor quality of current spreading. The p-type electrode layer 24 also only covers a portion of the contact layer 22. As shown in FIG. 2, the area having current flow is about the width L of the electrode layer 24. This limits the light emitting area for the diode. The function of the active layer cannot be fully performed. The light emitting efficiency of the diode is then greatly reduced.

[0009] In summary, the conventional light emitting diode is restricted by the physical properties of the contact layer. The contact layer cannot be grown with a high hole concentration. This also causes the high fabrication cost and also causes low yield. Further still, the conventional structure cannot provide a diode with high light emitting efficiency. A large portion of the active layer 18 of the diode is not well utilized. Moreover, the conductive doping types for the electrode layer and the contact layer are different. It could cause a junction between them at the contact region, and affecting the operation of the diode.

[0010] The invention provides a structure of light emitting diode, which has a contact layer having structure of doped strained-layer supperlatices (SLS), so that the contact layer can easily have a high carrier concentration, resulting in high conductivity.

[0011] The invention provides a structure of light emitting diode, which uses strained-layer supperlatices structure to serve as a contact layer associating with the transparent electrode layer, so as to improve the light emitting efficiency and reduce the operation voltage.

[0012] The invention provides a structure of light emitting diode, which has a contact layer having structure of doped strained layer supperlatices (SLS). The dopant type in the contact layer is therefore not necessary to be restricted. The transparent electrode and the contact layer can even be the same conductive type, so that the junction between the transparent electrode and the contact layer is avoided.

[0013] The invention provides a stricture of light emitting diode, which has a contact layer having structure of doped strained-layer supperlatices (SLS). The transparent electrode has better contact quality. The area of the transparent electrode can be about equal o the area of the active layer. This can allow the current to flow through the larger area of the active layer, so that the effective light emitting area is increased, and the light emitting efficiency is accordingly increased.

[0014] The invention provides a structure of light emitting diode, which is formed on a substrate, including:

[0015] a nucleation layer and a buffer layer with a first conductive type are sequentially formed on the substrate. A lower cladding layer with the first conductive type is formed on the conductive buffer layer, wherein the doped materials in the first-type cladding layer and the conductive buffer layer have the same conductive type, such as P-type or N-type. An active layer is located on the first-type cladding layer to serve as a light emitting layer for the light emitting diode. An upper cladding layer with a second conductive type is located on the active layer. The first-type cladding layer and the second-type cladding layer have doped materials with opposite conductive type. A second-type contact layer is located on the second-type cladding layer. The contact layer includes semiconductor material with periodic variation and modulated doped, such as doped Mg, Zn, Be, Cd, CA, C, or Hg, all of which has a structure of strained-layer superlattices. A transparent electrode is located on the contact later to serve as an anode. Another electrode layer, serving as a cathode, contacts with the conductive buffer layer, and is separated from the lower and upper cladding layers, the active layer, the contact layer and the transparent electrode.

[0016] In the foregoing, the transparent electrode layer and the SLS layer can have different conductive types. The transparent electrode layer can have the conductive type of P-type or N-type.

[0017] The invention provides a structure of light emitting diode, having an SLS structure formed on the substrate. A conductive buffer layer is formed on the substrate, so as to ease the crystal growth for the subsequent process. The active layer is located over the lower cladding layer. The active layer includes doped III-N group compound semiconductors. The upper cladding layer is located on the active layer. The SLS layer is located on the upper cladding layer. The conductive type of the contact layer can be different from the upper cladding layer. A transparent electrode layer is located on the SLS layer. Another electrode layer has a contact with the conductive buffer layer but is separated from the active layer and the transparent electrode layer.

[0018] In the foregoing, the transparent electrode layer and the SLS layer can be the same conductive type with all P-type or all N-type. The transparent electrode layer and the SLS layer can also be different conductive type.

[0019] It is to be understood that both the foregoing general description and the following detailed description are exemplary, and are intended to provide further explanation of the invention as claimed.

[0020] The accompanying drawings are included to provide a further understanding of the invention, and are incorporated in and constitute a part of this specification. The drawings illustrate embodiments of the invention and, together with the description, serve to explain the principles of the invention. In the drawings,

[0021] FIG. 1 is a cross-sectional view, schematically illustrating structure of a conventional light emitting diode made of III-N group compound;

[0022] FIG. 2 is a cross-sectional views, schematically illustrating a light emitting region for the light emitting diode in FIG. 1;

[0023] FIG. 3 is a cross-sectional view, schematically illustrating a structure of light emitting diode including nitride-based III-N group compound, according to one preferred embodiment of this invention;

[0024] FIG. 4 is a cross-sectional views, schematically illustrating a light emitting region for the light emitting diode in FIG. 3, according to one preferred embodiment of this invention; and

[0025] FIG. 5 is a drawing, schematically illustrating a conductive mechanism for the light emitting diode.

[0026] The invention uses a strained-layer superlattices as a contact layer for a diode to improve the ability for growing a GaN-based semiconductor layer with high carrier concentration, which results in high conductivity, especially for P-type materials. Due to the property of low resistance, the current spreading can be at a better quality, whereby the current would not be confined to the region below the electrode and affect the light emitting efficiency. Moreover, the strained-layer superlattices can have higher carrier concentration, which allows the subsequent transparent electrode to have better ohmic contact. The Schottky contact, due to low carrier concentration, would not occur. The operation voltage for the device can also be reduced. Further still, the strained-layer superlattices and the transparent electrode can have the same conductive type. This also prevent the p-n junction between the strained-layer superlattices and the transparent electrode from occurring. The areas of the transparent electrode and the contact layer can be about the same. FIG. 3 is a cross-sectional view, schematically illustrating a structure of light emitting diode including GaN-based III-N group compound, according to one preferred embodiment of this invention.

[0027] In FIG. 3, a substrate 100 is provided first. The substrate 100 includes, for example, sapphire, SiC, ZnO, Si, GaP, GaAs, Al₂O₃, or any suitable material. Then a nucleation layer 110 is formed on the substrate 100. The nucleation layer 110 includes, for example, Al_uIn_vGa_l−u−vN (u, v≧0;0≦u+v≦1).

[0028] A first-conductive-type buffer layer 120 is formed on the nucleation layer 110. The buffer layer 120 includes, for example, Al_cIn_dGa_l−c−dN (c, d≧0; 0≦c+d<1). Generally, it is difficult to directly form a gallium nitride-based epitaxial layer with P-type or N-type on the substrate. This is because the gallium nitride-based semiconductor has poor match of the crystal lattice with the substrate. Usually, a gallium nitride-based compound semiconductor to serve as the nucleation layer 110 and the buffer layer 120 are formed beforehand. In the example, the buffer layer 120 includes, for example, the N-type Al_cIn_dGa_l−c−dN, so as to improve quality of the crystal growth of gallium nitride-based compound in the subsequent process later, and also increases the production yield.

[0029] An electrode 162, serving as a cathode of the light emitting diode, is formed on the buffer layer 120, and is located at a region separated from a lower confinement layer 130, an upper confinement layer 132, and an active layer 140. The electrode layer 162 can include Ti/Al, Ti/Al/Ti/Au, Ti/Al/Pt/Au, Ti/Al/Ni/Au, Ti/Al/Pd/Au, Ti/Al/Cr/Au, Ti/Al/Co/Au, Cr/Al/Cr/Au, Cr/Al/Pt/Au, Cr/Al/Pd/Au, Cr/Al/Ti/Au, Cr/Al/Co/Au, Cr/Al/Ni/Au, Pd/Al/Ti/Au, Pd/Al/Pt/Au, Pd/Al/Ni/Au, Pd/Al/Pd/Au, Pd/Al/Cr/Au, Pd/Al/Co/Au, Nd/Al/Pt/Au, Nd/Al/Ti/Au, Nd/Al/Ni/Au, Nd/Al/Cr/Au, Nd/Al/Co/Au, Hf/Al/Ti/Au, Hf/Al/Pt/Au, Hf/Al/Ni/Au, Hf/Al/Pd/Au, Hf/Al/Cr/Au, Hf/Al/Co/Au, Zr/Al/Ti/Au, Zr/Al/Pt/Au, Zr/Al/Ni/Au, Zr/Al/Pd/Au, Zr/Al/Cr/Au, Zr/Al/Co/Au, TiNx/Ti/Au, TiNx/Pt/Au, TiNx/Ni/Au, TiNx/Pd/Au, TiNx/Cr/Au, TiNx/Co/Au, TiWNx/Ti/Au, TiWNx/Pt/Au, TiWNx/Ni/Au, TiWNx/Pd/Au, TiWNx/Cr/Au, TiWNx/Co/Au, NiAl/Pt/Au, NiAl/Cr/Au, NiAl/Ni/Au, NiAl/ Ti/Au, Ti/NiAl/ Pt/Au, Ti/NiAl/Ti/Au, Ti/NiAl/Ni/Au, Ti/NiAl/Cr/Au, or any similar material, all of which have good ohmic contact with the conductive buffer layer, and therefore have smaller contact resistance.

[0030] The lower confinement layer 130 is formed on the buffer layer 120, and includes gallium nitride-based compound semiconductor, such as N-type Al_xIn_yGa_l−x−yN (x, y≧0; 0≦x+y<1; x>c, where c is the Al content for the buffer layer 120). Dopants for N-type can be chosen by skilled artisans, and are not described here.

[0031] An active layer 140 is formed on the lower confinement layer 130. The active layer is a light emitting layer. The active layer includes, for example, the indium gallium nitride based multiple quantum well. In this example, the active layer 140 can be either doped or undoped Al_aIn_bGa_l−a−bN/Al_xIn_yGa_l−x−yN (a, b≧0; 0≦a+b<1; x, y≧0; 0≦x+y<1; x>c>a, where c is the index for the buffer layer 120 ) with a quantum well structure. The doping conductive type can be N-type or P-type. The dopants used to form the N-type doping or the P-type doping are well known by skilled artisans

[0032] An upper confinement layer 132 is formed on the active layer 140. The upper confinement layer 132 can include gallium nitride-based compound semiconductors, such as P-type doped Al_xIn_yGa_l−x−yN (x, y ≦0; 0≧x+y<1; x>c). The P-type dopants can select from the conventional material known by skilled artisans. The active layer 140 with either N-type or P-type is confined by the lower confinement layer 130 and the upper confinement layer 132. In the foregoing, materials of the gallium nitride-based compound semiconductors, content weight, dopant type, and so on can vary according to the actual design. The above embodiment is only an example for description.

[0033] Then, a contact layer 150 is formed over the upper confinement layer 132. The contact layer 150 is one the main features in the invention. According to the 15 present invention, the contact layer includes the material of gallium nitride-based compound semiconductors with high carrier concentration, such as an SLS layer 150. The SLS layer 150 includes, for example, gallium nitride-based compound semiconductors, such as Al_uIn_yGa_l−x−yN/Al_xIn_yGa_l−x−yN (u, v≧0; 0≦u+v<1; x,y ≧0; 0≦x+y<1; x>u). The SLS layer 150 is doped by a mechanism of modulation doped. Moreover, the SLS layer can be doped with N-type dopants or P-type dopants.

[0034] A transparent electrode 160 is formed on the contact layer 150. The transparent electrode includes, for example, Ni/Au, TiN, Pd/Au/Pt/Au, and so on. The transparent electrode can also, for example, include N-type transparent conductive oxide layer (TCO), such as ITO, CTO, ZnO:Al, ZnGa₂O₄, SnO₂:Sb, Ga₂O₃:Sn, AgInO₂:Sn, In₂O₃:Zn, and so on or P-type TCO, such as CuAlO₂, LaCuOS, NiO, CuGaO₂, SrCu₂O₂, and so on. The transparent electrode cal also includes a metal layer of Ni/Au, Ni/Pt, Ni/Pd, Ni/Co, Pd/Au, Pt/Au, Ti/Au, Cr/Au, Sn/Au, Ta/Au, TiN, TiWN_x, WSi_x. Generally, the transparent electrode 160 includes a metal layer with a single-layer structure or a multi-layer structure, which structures are common in semiconductor technologies. However, the total thickness of the transparent electrode is preferably about equal to or less than 0.1 microns.

[0035] According to the conventional manner, the contact layer usually has the same conductive type with the gallium nitride-based compound semiconductor material. Generally, since the contact layer has contact with the transparent electrode that is formed subsequently, the carrier concentration for the contact layer usually needs a rather high level, such as 1×10¹⁸/cm³or higher. However, it is very difficult to grow a P-type contact layer with the carrier concentration level of 1×10¹⁸/cm³or higher for the semiconductor bulk of the P-type gallium nitride-based compound, such as p-GaN. In the conventional semiconductor fabrication technologies, if the carrier concentration in the semiconductor material is insufficient, it would have a large contact resistance with the metal electrode. It is even more severe for the P-type semiconductor material.

[0036] Therefore, the present invention introduces the SLS layer with modulation doping property. Using the properties of the strained-layer superlattices structure, the P-type gallium nitride-based contact layer with high carrier concentration level can be easily grown thereon. The band structure between the gallium nitride-based material in the SLS structure is affected by the strain, so that the Fermi level is closer to the valence band. Therefore, the dopants can be easily activated, so as to increase the carrier concentration level, which can achieve the level of 1×10¹⁸/cm³. It can even achieve to 1×10¹⁹/cm³or higher for the P-type gallium nitride-based material. The SLS structure has sufficient advantage for choice as the contact layer. In addition, as the carrier concentration is sufficiently high, the carriers can directly transport through the energy barrier due to the tunneling effect. The contact layer therefore can be having different conductive type from the upper confinement layer. The P-N junction is prevented from occurring. For example, if the upper confinement layer is P-type, the contact layer can be either N-type or P-type. The mechanism for energy band for conduction is shown in FIG. 5.

[0037] Since the SLS layer is used as the contact layer 150 with the transparent electrode 160, the ohmic contact between them has good quality. Moreover, the transparent electrode layer can be formed with an area about equal to the area of the contact layer. Therefore, the structure of the present invention can even increase the current, which flows through the whole active layer 140 and the area of transparent electrode layer. In FIG. 4, when the anode 160, that is, the transparent electrode of the light emitting diode and the cathode 162 are applied with a forward bias, all light generate by the whole active layer 140 emits through the transparent electrode, and extracts outwardly. This means that the structure of the invention has larger light emitting area than the conventional light emitting area. Since the invention uses the SLS layer to serve as the contact layer associating with the transparent electrode, the light emitting efficiency for the light emitting device is greatly improved.

[0038] Further still, due to use of the properties of strained-layer superlattices, the transparent electrode 160 and the contact layer 150 of strained-layer superlattices can include materials with the same conductive type. For example in the embodiment, the contact layer 150 of strained-layer superlattices includes the P-type material of Al_uIn_vGa_l−u−vN/Al_xIn_yGa_l−x−yN, and the transparent electrode 160 includes P-type material of CuAlO₂, LaCuOS, CuGaO₂, SrCu₂O₂, and so on. The contact layer 150 of strained-layer superlattices can also includes the N-type material of Al_uIn_vGa_l−u−vN/Al_xIn_yGa_l−x−yN, and the transparent electrode 160 includes N-type material of ITO, CTO, AgInO₂or In₂O₃:Zn. In this situation, since the transparent electrode 160 and the contact layer 150 has the same conduction type, there is no rectified junction occurring. As comparing with the convention method, the conventional method restricts that the contact layer should use the P-type material of gallium nitride-based compound semiconductor, while the transparent electrode is N-type material, such as ITO or CTO. Due to the different conduction type between the transparent electrode and the contact layer, the P-N junction might occur in the conventional method, and affects the operation of the device. This is particularly due to the insufficient carrier concentration of contact layer.

[0039] In summary, the structure of the light emitting diode in the present invention at least has advantages as follows:

[0040] The structure of the light emitting diode in the present invention uses the modulated doped process associating with the properties of strained layer superlattices material to form contact layer of the gallium nitride-based light emitting diode. The carrier concentration of the contact layer can be effectively and easily increased up to 1×10¹⁸atoms/cm³or even higher.

[0041] The structure of the light emitting diode in the present invention uses the doped strained-layer superlattices to serve as the contact layer of the gallium nitride-based light emitting diode. The transparent electrode has better quality of ohmic contact, and the area of the transparent electrode can be about the same as the area of the contact layer. This features improve the area of the active layer where current can flow through. The effective light emitting area of the active layer is increased, and thereby the light emitting efficiency is greatly improved and the operation voltage for the device is reduced.

[0042] The structure of the light emitting diode in the present invention uses the doped strained-layer superlattices to serve as the contact layer of the light emitting diode. The conductive type of the contact layer can be freely chosen depending on the actual design. That is, the transparent electrode and the contact layer can be having the same conductive type or different conductive type. If the option of taking same conductive type, the P-N junction between the contact layer and the transparent electrode, which occurring in the conventional manner, can be avoided.

[0043] It will be apparent to those skilled in the art that various modifications and variations can be made to the structure of the present invention without departing from the scope or spirit of the invention. In view of the foregoing, it is intended that the present invention covers modifications and variations of this invention provided they fall within the scope of the following claims and their equivalents.