US 5,604,146 AGrant
Method to Fabricate a Semiconductor Memory Device Having an E-Shaped Storage Node
Issue Date:1997-02-18
•35 Claims
•7 Drawing Sheets
Abstract
A method is described for forming a dynamic random access memory cell with an increased capacitance capacitor. Device structures, including a capacitor node contact region, are formed in and on the semiconductor substrate. A dielectric layer and a thick insulating layer are deposited over the device structures and planarized. A contact is opened to the capacitor node contact region. A first layer of polysilicon is deposited filling the contact opening. The portion contacting the node contact region forms the bottom electrode of the capacitor. A portion of the polysilicon layer is etched away to form a well above the contact opening. A layer of silicon oxide is deposited within the well and is etched back to leave spacers on the sidewalls of the well. A second layer of polysilicon is deposited over the first polysilicon layer and within the well. The second polysilicon layer is removed except where it forms a plug within the well. The spacers are removed leaving gaps on either side of the plug. The first polysilicon layer is patterned so that an E-shaped storage node structure having three prongs pointing upward is formed. The plug forms the central prong and the outer two prongs are formed by the patterned first polysilicon layer. A capacitor dielectric layer is deposited over all surfaces of the E-shaped structure. A third polysilicon layer is deposited over the capacitor dielectric covering and filling the gaps of the E-shaped structure and forming the top capacitor electrode.
Metadata
Assignee
- Vanguard International Semiconductor Corporation
Inventor
- Horng-Huei Tseng
Application Information
Application Number:US 6612458
Filing Date:1996-06-10
Priority Date:1996-06-10
Art Unit:117
Classifications
IPC:
H01L 2170H01L 2700
Field of Search:
43714852;60;919DIG. 14
Patent Drawings (7 sheets)
Description
Background of the Invention
(1) Field of the Invention
The present invention relates to a method of fabricating a dynamic random access memory having an increased capacitance capacitor having an E-shaped storage node.
(2) Description of the Prior Art
In recent years there has been a dramatic increase in the packing density of DRAMs. Large DRAM devices are normally silicon based, and each cell typically embodies a single MOS field effect transistor with its source connected to a storage capacitor. This large integration of DRAMs has been accomplished by a reduction in individual cell size. However, the reduction in cell size results in a decrease in storage capacitance leading to reliability drawbacks, such as a lowering of source/drain ratio and undesirable signal problems. In order to achieve the desired higher level of integration, the technology must keep almost the same storage capacitance on a greatly reduced cell area.
Efforts to maintain or increase the storage capacitance in memory cells with greater packing densities have included the use of a stacked cylindrical capacitor design in which the capacitor cell uses the space over the device area for the capacitor plates. In U.S. Pat. No. 5,389,568 to Yun, the inventor describes a method of forming a cylindrical capacitor with a central pillar including a hole. U.S. Pat. 5,438,013 to Kim et al teaches a method of forming a double cylindrical capacitor. U.S. Pat. No. 5,364,809 to Kwon et al teaches a method of fabricating a multi-chamber type capacitor.
Summary of the Invention
Accordingly, it is a primary object of the invention to provide an improved and very manufacturable process for producing a memory cell capacitor with increased capacitance.
A method is described for forming a dynamic random access memory cell with an increased capacitance capacitor. Relatively thick field oxide areas are formed on the surface of a semiconductor substrate while leaving device areas for fabrication of semiconductor devices. Device structures are formed within the device areas of the semiconductor substrate wherein the device structures include a capacitor node contact region within the silicon substrate. The capacitors are formed by the following steps. A dielectric layer is deposited overlying the semiconductor device structures. An insulating layer is deposited overlying the dielectric layer and is planarized. A contact is opened through the insulating layer and the dielectric layer to the capacitor node contact region. A first layer of polysilicon is deposited overlying the insulating layer and filling the contact opening wherein the portion of the first polysilicon layer contacting the node contact region forms the bottom electrode of the capacitor. A portion of the first polysilicon layer is etched away wherein a well opening is formed above the contact opening. A layer of silicon oxide is deposited overlying the first polysilicon layer and conformally within the well opening. The silicon oxide layer is etched back to leave spacers on the sidewalls of the well opening. A second layer of polysilicon is deposited overlying the first polysilicon layer and within the well opening. The second polysilicon layer is removed except where the second polysilicon layer forms a plug within the well opening. The spacers on the walls of the well opening are removed wherein gaps are left on either side of the plug. The first polysilicon layer is patterned so that an E-shaped structure having three prongs is formed wherein the prongs of the E-shaped structure point upward and wherein the plug forms the central prong and wherein the outer two prongs are formed by the patterned first polysilicon layer and wherein the E-shaped structure forms the storage node of the capacitor. A capacitor dielectric layer is deposited over all surfaces of the substrate wherein the capacitor dielectric layer covers the surfaces of the E-shaped structure. A third polysilicon layer is deposited overlying the capacitor dielectric layer wherein the third polysilicon layer covers and fills the gaps of the E-shaped structure and wherein the third polysilicon layer forms the top electrode of the capacitor to complete formation of the DRAM with capacitor.
According to another aspect of the present invention, a dynamic random access memory having a high capacitance capacitor is described. Field oxide areas on the surface of a semiconductor substrate surround device areas for fabrication of field effect devices, gate dielectric and electrode structures on the substrate in the device areas. Source/drain structures associated with the gate structures lie within the device areas of the semiconductor substrate. A capacitor structure comprises a bottom electrode formed by the central cylindrical portion of a polysilicon layer which electrically contacts the source/drain structures, a storage node having an E-shape with three prongs wherein the prongs point upward from the central cylindrical portion of the polysilicon layer, a capacitor dielectric layer overlying all surfaces of the storage node, and a top plate electrode layer overlying the capacitor dielectric layer on all surfaces of the storage node to complete the capacitor.
Brief Description of the Drawings
In the following drawings forming a material part of this description, there is shown:
FIGS. 1-8 and 10-12 are schematic cross-sectional representations of a preferred embodiment of the present invention.
FIGS. 9A and 9B schematically illustrate in cross-sectional representation two alternative methods in the process of the present invention.
Description of the Preferred Embodiments
Referring now more particularly to FIG. 1, the first series of steps involve the formation of the dielectric isolation regions for isolating semiconductor surface regions from other such regions in the semiconductor substrate 10. The semiconductor substrate is preferably composed of silicon having a (100) crystallographic orientation. In an effort to simplify the description and the drawings the dielectric isolation between devices has been only partially shown and will not be described in detail, because they are conventional. Field oxide regions 12 are formed in and on the semiconductor substrate.
The surface of the silicon substrate 10 is thermally oxidized to form the desired gate oxide 14 thickness. The preferred thickness is between about 80 to 200 Angstroms. The polysilicon layer 16 is blanket deposited by low pressure chemical vapor deposition (LPCVD) to a preferred thickness of between about 1500 to 3500 Angstroms. A layer 18 of silicon oxide is chemically vapor deposited over the surface of the polysilicon to a thickness of between about 600 to 1200 Angstroms. The layers 14, 16, and 18 are patterned by lithography and anisotropic etching techniques as are conventional in the art to provide a desired pattern of gate electrodes and word lines 20 as seen in FIG. 1.
The source/drain structure of the MOS FET may now be formed by the following steps. FIGS. 1 through 12 illustrate the formation of an N channel FET integrated circuit device. However, it is well understood by those skilled in the art that a P channel FET integrated circuit device could also be formed by simply substituting opposite polarities to those given for the N channel embodiment. Also, a CMOS FET could in a similar way be formed by making both N channel and P channel devices upon the same substrate. As is understood in the art, the DRAM cell is composed of a combination device structure of an N channel FET and a stacked capacitor while the peripheral circuits are often composed of CMOS devices.
FIG. 1, for example shows the ion implantations of N- dopants. Lithographic masks may be required to protect the areas not to be subjected to that particular N- ion implantation. The formation of the lithographic masks is done by conventional lithography and etching techniques. The N- lightly doped drain implantation 22 is done with, for example, P.sub.31 at a dosage of between about 1 E 13 to 1 E 14 atoms/cm.sup.2 and an energy of between about 20 to 40 Kev.
The dielectric spacer 24 is now to be formed followed by the completion of the lightly doped drain source/drain structures. A tetraethyloxysilane (TEOS) LPCVD deposition is preferred to a thickness of between about 1000 to 2000 Angstroms.
An anisotropic etching of this layer produces the dielectric spacer layer 24 on the sidewalls of the layer structures 20.
The heavily doped source and drain regions 26 are formed by implantation with, for example, arsenic at a dosage of between about 1 E 15 to 1 E 16 atoms/cm.sup.2 and an energy of between about 20 to 80 Kev.
Referring now to FIG. 2, a layer of silicon oxide or nitride 28 is formed over the field oxide and device areas to a thickness of between about 800 to 2000 Angstroms. Next, a thick insulating layer, such as chemically vapor deposited (CVD) oxide or borophosphosilicate glass (BPSG) 30 is deposited to a thickness of between about 5000 to 10,000 Angstroms and then planarized, for example by chemical mechanical polishing (CMP), to obtain a flat surface.
Referring now to FIG. 3, using conventional lithographic and etching techniques, contact openings are made through the CVD oxide or BPSG layer 30 and silicon nitride layer 28 to the silicon substrate. Opening 31 is made to the node contact region for the capacitor structure.
Referring now to FIG. 4, a first thick polysilicon layer 32 is deposited over CVD oxide or BPSG layer 30 by LPCVD either in situ doped or doped after deposition by ion implantation. The thickness of this layer is between about 2000 to 6000 Angstroms.
The thick polysilicon layer 32 is anisotropically etched into to form a well 34, as shown in FIG. 5. This may be a Magnetic Enhanced Reactive Ion Etching (MERIE). The width of the well 34 can be of the minimum dimension on the chip. The depth of the well 34 must be less than the thickness of layer 32.
A layer of silicon oxide 36 is deposited over layer 32 and within the well 34 by CVD to a thickness of between about 2000 to 6000 Angstroms, as illustrated in FIG. 6.
Referring now to FIG. 7, the silicon oxide layer 36 is etched back, using MERIE, to form spacers on the sidewalls of the well 34.
Referring now to FIG. 8, a second layer of polysilicon 38 is deposited over the first polysilicon layer 32, spacers 36, and within the well 34. The in-situ doped polysilicon layer 38 is deposited by LPCVD. This layer has a thickness of between about 500 to 1500 Angstroms.
The polysilicon layer 38 is thermally oxidized to form polyoxide layer 40, shown in FIG. 9A.
Referring now to FIG. 10, the polyoxide layer 40 and oxide spacers 36 are removed, using, for example, a hydrofluoric acid solution, to leave polysilicon plug 42.
Alternatively, instead of oxidizing polysilicon layer 38, as shown in FIG. 9A, the polysilicon layer 38 can be etched back to leave the polysilicon plug 42, as shown in FIG. 9B. Then the oxide spacers 36 can be removed using, for example, a hydrofluoric acid solution, resulting also in FIG. 10.
Referring now to FIG. 11, the polysilicon layer 32 is patterned to form the storage node of the capacitor. The portion of layer 32 contacting the node contact region forms the bottom electrode of the capacitor. Layer 32 and plug 42 together form the E-shaped storage node of the capacitor where the three prongs of the E-shape point upward.
Referring now to FIG. 12, the capacitor dielectric layer 44 is now deposited conformally over the polysilicon 32 and 42 and insulating layer 30 surfaces. This layer is typically either composed of layers of silicon nitride and silicon oxide (NO) or layers of silicon oxide, silicon nitride and silicon oxide (ONO). In making the ONO dielectric, the first or bottom silicon oxide, 0 layer is usually a native oxide grown to a thickness of about 15 Angstroms. The silicon nitride, N layer is formed by LPCVD to give a resulting thickness of between about 80 to 200 Angstroms. The top silicon oxide, 0 layer may be formed in an oxidation furnace. The total ONO thickness is in the order of between about 100 to 250 Angstroms.
The top plate electrode is formed by depositing a third in-situ doped polysilicon layer 46 by LPCVD. The thickness of this layer 46 is between about 1000 to 2000 Angstroms.
The process of the invention results in an increased capacitance DRAM capacitor having an E-shaped storage node. Since the insulating layer 30 is planarized using CMP, the etchback to form the plug 42, which forms the middle prong of the E-shape, leaves no residue.
The DRAM integrated circuit with increased capacitance capacitor of the present invention is described with reference to FIG. 12. MOS devices, such as gate electrodes and word lines 20 lie on a semiconductor substrate 10. Source and drain regions 26 lie within the semiconductor substrate not covered by the MOS devices. A stacked capacitor 32 contacts one of the source and drain regions 26. The storage node of the capacitor comprises a cylindrical polysilicon structure 32 at the top of which is an E-shaped polysilicon structure 32,42 having the prongs of the E pointing upward. The capacitor dielectric 44 comprises NO or ONO covering all surfaces of the storage node 32 and 42. The top electrode 46 comprises polysilicon overlying the capacitor dielectric.
While the invention has been particularly shown and described with reference to the preferred embodiments thereof, it will be understood by those skilled in the art that various changes in form and details may be made without departing from the spirit and scope of the invention.
Claims
What is claimed is:
1. A method for fabricating a dynamic random access memory (DRAM) having a capacitor comprising: forming field oxide regions in and on a semiconductor substrate; forming a gate silicon oxide layer over the surface of said semiconductor substrate; depositing a gate polysilicon layer overlying said gate silicon oxide layer and patterning said gate polysilicon to form gate electrodes; forming lightly doped drain regions within said semiconductor substrate; depositing and etching a spacer silicon oxide to form spacers on the sidewalls of said gate electrodes; forming source and drain regions within said semiconductor substrate; depositing a dielectric layer overlying said gate electrodes and the surfaces of said semiconductor substrate; depositing an insulating layer overlying said dielectric layer and planarizing said insulating layer; opening a contact through said insulating layer and said dielectric layer to one of said source and drain regions within said semiconductor substrate which will form a node of said capacitor; depositing a first layer of polysilicon overlying said insulating layer and filling said contact opening wherein a portion of said first polysilicon layer contacting one of said source and drain regions which forms said node will be the bottom electrode of said capacitor; etching away a portion of said first polysilicon layer wherein a well opening is formed above said contact opening; depositing a layer of silicon oxide overlying said first polysilicon layer and conformally within said well opening; etching back said silicon oxide layer to leave spacers on the sidewalls of said well opening; depositing a second layer of polysilicon overlying said first polysilicon layer and within said well opening; removing said second polysilicon layer except where said second polysilicon layer forms a plug within said well opening; removing said spacers on the walls of said well opening wherein gaps are left on either side of said plug; patterning said first polysilicon layer so that an E-shaped structure having three prongs is formed wherein the prongs of said E-shaped structure point upward and wherein said plug forms the central prong and wherein the outer two prongs are formed by said patterned first polysilicon layer and wherein said E-shaped structure forms the storage node of said capacitor; depositing a capacitor dielectric layer over all surfaces of said substrate wherein said capacitor dielectric layer covers the surfaces of said E-shaped structure; and depositing a third polysilicon layer overlying said capacitor dielectric layer wherein said third polysilicon layer covers and fills gaps of said E-shaped structure and wherein said third polysilicon layer forms the top electrode of said capacitor to complete formation of said DRAM with capacitor.
2. The method according to claim 1 wherein said dielectric layer comprises silicon nitride having a thickness of between about 800 to 2000 Angstroms.
3. The method according to claim 1 wherein said dielectric layer comprises silicon oxide having a thickness of between about 800 to 2000 Angstroms.
4. The method according to claim 1 wherein said insulating layer comprises chemically vapor deposited oxide and has a thickness of between about 5000 to 10,000 Angstroms.
5. The method according to claim 1 wherein said insulating layer comprises borophosphosilicate glass and has a thickness of between about 5000 to 10,000 Angstroms.
6. The method according to claim 1 wherein said insulating layer is planarized by chemical mechanical polishing.
7. The method according to claim 1 wherein said first polysilicon layer has a thickness of between about 2000 to 6000 Angstroms.
8. The method according to claim 1 wherein said first polysilicon layer is etched using Magnetic Enhanced Reactive Ion Etching (MERIE).
9. The method according to claim 1 wherein said silicon oxide layer has a thickness of between about 2000 to 6000 Angstroms.
10. The method according to claim 1 wherein said etching back of said silicon oxide layer is done using MERIE.
11. The method according to claim 1 wherein said second polysilicon layer has a thickness of between about 500 to 1500 Angstroms.
12. The method according to claim 1 wherein said removing said second polysilicon layer except where said second polysilicon layer forms a plug within said well opening is done by etching back said second polysilicon layer to said first polysilicon layer surface leaving said plug within said well opening.
13. The method according to claim 1 wherein said removing said second polysilicon layer except where said second polysilicon layer forms a plug within said well opening comprises the steps of: thermally oxidizing said second polysilicon layer to transform said layer on the surface of said first polysilicon layer into a polyoxide wherein said second polysilicon layer within said well opening is not transformed; and stripping said polyoxide using a hydrofluoric acid solution leaving said plug within said well opening.
14. The method according to claim 13 wherein said removing said spacers on the sidewalls of said well opening is done at the same time as said stripping of said polyoxide.
15. The method according to claim 1 wherein said removing said spacers on the sidewalls of said well opening is done using a hydrofluoric acid solution.
16. The method according to claim 1 wherein said capacitor dielectric layer is composed of layers of silicon oxide, silicon nitride, and silicon oxide having a thickness of between about 100 to 250 Angstroms.
17. The method according to claim 1 wherein said capacitor dielectric layer is composed of layers of silicon nitride and silicon oxide having a thickness of between about 100 to 250 Angstroms.
18. The method according to claim 1 wherein said third polysilicon layer has a thickness of between about 1000 and 2000 Angstroms.
19. A method for fabricating a dynamic random access memory (DRAM) having a capacitor comprising: selectively forming field oxide areas on the surface of a semiconductor substrate while leaving device areas for fabrication of semiconductor devices; forming device structures within said device areas of said semiconductor substrate wherein said device structures include a capacitor node contact region within said semiconductor substrate; and forming said capacitors by: depositing a dielectric layer overlying said semiconductor device structures; depositing an insulating layer overlying said dielectric layer and planarizing said insulating layer; opening a contact through said insulating layer and said dielectric layer to said capacitor node contact region; depositing a first layer of polysilicon overlying said insulating layer and filling said contact opening; etching away a portion of said first polysilicon layer wherein a well opening is formed above said contact opening; depositing a layer of silicon oxide overlying said first polysilicon layer and conformally within said well opening; etching back said silicon oxide layer to leave spacers on the sidewalls of said well opening; depositing a second layer of polysilicon overlying said first polysilicon layer and within said well opening; removing said second polysilicon layer except where said second polysilicon layer forms a plug within said well opening; removing said spacers on the walls of said well opening wherein gaps are left on either side of said plug; patterning said first polysilicon layer so that an E-shaped structure having three prongs is formed wherein the prongs of said E-shaped structure point upward and wherein said plug forms the central prong and wherein the outer two prongs are formed by said patterned first polysilicon layer; depositing a capacitor dielectric layer over all surfaces of said substrate wherein said capacitor dielectric layer covers the surfaces of said E-shaped structure; and depositing a third polysilicon layer overlying said capacitor dielectric layer wherein said third polysilicon layer covers and fills the gaps of said E-shaped structure to complete formation of said DRAM with capacitor.
20. The method according to claim 19 wherein said device structures in said device areas include source/drain and gate field effect transistor structures which form a dynamic random access memory cell together with said capacitor.
21. The method according to claim 19 wherein a portion of said first polysilicon layer contacting said capacitor node contact region forms the bottom node of said electrode, said first and second polysilicon layers remaining form an E-shaped storage node of said capacitor and said third polysilicon layer forms the top electrode of said capacitor.
22. The method according to claim 19 wherein said dielectric layer comprises silicon nitride having a thickness of between about 800 to 2000 Angstroms.
23. The method according to claim 19 wherein said dielectric layer comprises silicon oxide having a thickness of between about 800 to 2000 Angstroms.
24. The method according to claim 19 wherein said insulating layer comprises chemically vapor deposited oxide and has a thickness of between about 5000 to 10,000 Angstroms.
25. The method according to claim 19 wherein said insulating layer comprises borophosphosilicate glass and has a thickness of between about 5000 to 10,000 Angstroms.
26. The method according to claim 19 wherein said insulating layer is planarized by chemical mechanical polishing.
27. The method according to claim 19 wherein said first polysilicon layer has a thickness of between about 2000 to 6000 Angstroms.
28. The method according to claim 19 wherein said silicon oxide layer has a thickness of between about 2000 to 6000 Angstroms.
29. The method according to claim 19 wherein said second polysilicon layer has a thickness of between about 500 to 1500 Angstroms.
30. The method according to claim 19 wherein said removing said second polysilicon layer except where said second polysilicon layer forms a plug within said well opening is done by etching back said second polysilicon layer to said first polysilicon layer surface leaving said plug within said well opening.
31. The method according to claim 19 wherein said removing said second polysilicon layer except where said second polysilicon layer forms a plug within said well opening comprises the steps of: thermally oxidizing said second polysilicon layer to transform said layer on the surface of said first polysilicon layer into a polyoxide wherein said second polysilicon layer within said well opening is not transformed; and stripping said polyoxide using a hydrofluoric acid solution leaving said plug within said well opening.
32. The method according to claim 31 wherein said removing said spacers on the sidewalls of said well opening is done at the same time as said stripping of said polyoxide.
33. The method according to claim 19 wherein said removing said spacers on the sidewall of said well opening is done using a hydrofluoric acid solution.
34. The method according to claim 19, wherein said capacitor dielectric layer is composed of layers of silicon oxide, silicon nitride, and silicon oxide having a thickness of between about 100 to 250 Angstroms.
35. The method according to claim 19 wherein said third polysilicon layer has a thickness of between about 1000 and 2000 Angstroms.