US 5,369,956 AGrant
Exhaust Gas Aftertreatment Device for Internal Combustion Engines
Issue Date:1994-12-06
•4 Claims
•1 Drawing Sheets
Abstract
An exhaust gas aftertreatment device for internal combustion engines having a catalyzer for the selective catalytic reduction of oxides of nitrogen from exhaust gases of motor vehicle diesel engines, provides overstoichiometric supply of NH.sub.3 or materials releasing NH.sub.3. A first sensor records the NH.sub.3 concentration contained in the exhaust gas and interrupts the supply of the NH.sub.3 quantity when a specified upper threshold value is reached. A second sensor records the NH.sub.3 adsorbed in the catalyzer, by way of which the NH.sub.3 supply is resumed on reaching a specified lower threshold value. Alternatively, only one NH.sub.3 sensor is provided in the exhaust gas aftertreatment device. The NH.sub.3 concentration determined by this single sensor is compared, as the actual value, with a required value corresponding to a specified NH.sub.3 concentration in order to form a correction signal which is used for triggering the metering appliance continuously connected into the gas phase.
Metadata
Assignee
- Mercedes-Benz AG
Inventors
- Helmut Daudel
- Klaus-Jurgen Marquardt
- Uwe Gartner
Application Information
Application Number:US 0530093
Filing Date:1993-04-27
Priority Date:1992-05-27
Art Unit:346
Classifications
IPC:
F01N 320
Field of Search:
60274;276;277;286
Patent Drawings (1 sheets)
Description
Background and Summary of the Invention
The present invention relates to an exhaust gas aftertreatment device for internal combustion engines having a catalyzer for selective catalytic reduction of oxides of nitrogen from exhaust gases, especially from exhaust gases of motor vehicle diesel engines. More particularly, the present invention relates to a device comprising a metering appliance for an overstoichiometric supply of one of NH.sub.3 and materials releasing NH.sub.3, at least two sensors, one of which is an NH.sub.3 sensor configured to interrupt the supply when a quantity of NH.sub.3 quantity exceeds a specified upper threshold value, and to resume the supply when, in the catalyzer, a stored NH.sub.3 quantity reaches a specified lower threshold value, and also to a device comprising a metering appliance for supply of one of NH.sub.3 and of materials releasing NH.sub.3, and a single sensor for determining the NH.sub.3 concentration in the exhaust gas.
As is well known, the oxides of nitrogen contained in the exhaust gases are reduced to nitrogen and water on a catalyzer when a reducing agent, namely ammonia (NH.sub.3) or compounds forming ammonia, is added.
Measures are disclosed in DE 3,825,206 to provide a pulsed overstoichiometric metered addition of the reducing agent NH.sub.3 and, specifically, by measuring the NO.sub.x concentration before and after the catalyzer, because the charge condition of the catalyzer is not defined in this mode of operation.
Furthermore, measures for the selective catalytic reduction of oxides of nitrogen from exhaust gases are described in German Patent Application P 41 17 143.8-43, by way of which the high NH.sub.3 concentration occurring in the metering phase is recorded by a sensor placed in the catalyzer. The sensor interrupts the NH.sub.3 supply after detection of the specified NH.sub.3 concentration. As soon as the NH.sub.3 stored in the catalyzer is substantially used up by the reaction, the renewed employment of the NH.sub.3 supply is determined by approximate calculation, from the engine characteristic diagram and the operating period, of the NO.sub.x produced by the engine over the period since the beginning of metering or the end of metering, taking account of the average degree of separation.
An object of the present invention is to provide simple measures In an exhaust gas aftertreatment device provided for non-stationary internal combustion engines to further improve the reduction of the oxides of nitrogen contained in the exhaust gas.
The foregoing object has been achieved in accordance with the present invention by providing a further sensor as an NH.sub.3 sensor recognizing the lower threshold value of the stored NH.sub.3 quantity, or by supplying NH.sub.3 in the gas phase without metering pauses so that the NH.sub.3 concentration recorded by the sensor is compared, as the actual value, with a required value corresponding to a specified NH.sub.3 concentration to form a correction signal usable for triggering the metering appliance continuously connected into the gas phase.
Due to the advantageous measures according to the present invention, it is not necessary to calculate the charge level in the catalyzer during the metering pause or NH.sub.3 interruption phase on the basis of the characteristic diagram. The matching of the NH.sub.3 supply to the various engine types with very different exhaust gas emissions becomes superfluous and it is not necessary to take account of the unavoidable component scatter within a type in the selection of the level limits. A second ammonia (NH.sub.3) sensor, which detects the ammonia adsorbed in the catalyzer, undertakes the recognition of the lower charge level whereas the first ammonia sensor detects gaseous ammonia.
This first NH.sub.3 sensor can be placed either downstream of the catalyzer or in the catalyzer itself. Although the arrangement of the sensor within the catalyzer does not permit an optimum utilization of the catalyzer volume, it does ensure that the NO.sub.x emissions do not exceed the permissible limiting values. The arrangement of the sensor after the catalyzer permits, however, full utilization of the catalyzer volume for the maximum adsorption capacity, but a brief minimum unallowable NH.sub.3 break-out cannot always be excluded.
Although a special embodiment with a second sensor is generally described in the aforementioned German Patent application P 41 17 143.8-43, this special configuration is subjected to exhaust gas upstream of the catalyzer in contrast to the present invention.
Continuous control of a slight, but constant NH.sub.3 slip within permissible limiting values is possible by measures in which the NH.sub.3 is supplied in the gas phase without metering pauses so that the NH.sub.3 concentration recorded by the sensor is compared, as the actual value, with a required value corresponding to a specified NH.sub.3 concentration to form a correction signal usable for triggering the metering appliance continuously connected into the gas phase. The advantage of this arrangement lies in avoiding the need for any type of characteristic diagram and in the compensation for any changes to the engine and the catalyzer within the control range.
Brief Description of the Drawing
These and other objects, features and advantages of the present invention will become more readily apparent from the following detailed description thereof when taken in conjunction with the accompanying sole figure which is a schematic diagram of an internal combustion engine and catalyzer utilizing the present invention.
Detailed Description of the Drawing
An internal combustion engine is designated generally by numeral 1, an exhaust gas conduit by numeral 2, a catalyzer by numeral 3 and a metering appliance by numeral 4. The metering appliance 4 comprises a reducing agent tank 5 and a supply conduit 6 with a delivery pump 7 and a shut-off valve 8. The supply conduit 6 opens into the exhaust gas conduit 2 upstream of the catalyzer 3. The system also includes an air filter 14 and a compressed air valve 15. The reducing agent tank 5 contains ammonia (NH.sub.3) or materials releasing ammonia, which are supplied in a controlled manner to the exhaust gas flow in the exhaust gas conduit 2.
The catalyzer 3 is arranged in a casing 9 in which a first NH.sub.3 sensor 10 is provided in one embodiment downstream of the catalyzer 3. This NH.sub.3 sensor 10 measures the NH.sub.3 concentration in the exhaust gas and feeds a switching signal into a control unit 11 at a time when the gaseous NH.sub.3 quantity has reached a fixed upper threshold value. The control unit 11 controls the delivery pump 7 in the sense of switching it off so that the NH.sub.3 supply is interrupted.
A second NH.sub.3 sensor 12 is arranged in, for example, carrier material of the catalyzer 3 to detect adsorbed NH.sub.3. As soon as the lower level limit is reached in the catalyzer 3 and the NH.sub.3 stored in the catalyzer has been substantially consumed by reaction, a switch signal corresponding to the fixed lower NH.sub.3 threshold value is supplied to the control unit 11. The control unit 11 controls the delivery pump 7 in the sense of switching it on again and metered addition of NH.sub.3 is resumed and, in fact, as a function of operating parameters such as engine rotational speed n, control distance CD, exhaust gas temperature T.sub.exhaust upstream of the NH.sub.3 supply and exhaust gas temperatures at inlet, T.sub.cat.in and outlet, T.sub.cat.out of the catalyzer 3. During the metering pause, the shut-off valve 8 triggered by the control unit 11 shuts off the supply conduit 6, into which no exhaust gas can flow.
The first NH.sub.3 sensor 10 can, however, also be placed in the catalyzer 3 as indicated by the numeral 10' to measure, in contrast to the second NH.sub.3 sensor 12 which measures lower charge level, gaseous NH.sub.3.
A further embodiment of the present invention provides for continuous control of the metering appliance 4 by the arrangement of a single NH.sub.3 sensor 13 downstream of the catalyzer 3. It is also possible to place this NH.sub.3 sensor 13 in the catalyzer 3 itself. The sensor 13 determines the respective NH.sub.3 concentration in the gas phase. The instantaneously present NH.sub.3 concentration is compared, as the actual value, with a required value corresponding to a specified NH.sub.3 concentration and a correction signal formed from this is used for triggering the metering appliance 4. The continuous control provides an ammonia slip, within the permissible limiting values, which is as small as possible and constant.
Although the invention has been described and illustrated in detail, it is to be clearly understood that the same is by way of illustration and example, and is not to be taken by way of limitation. The spirit and scope of the present invention are to be limited only by the terms of the appended claims.
Claims
We claim:
1. An exhaust gas aftertreatment device for an internal combustion engine having a catalyzer for selective catalytic reduction of oxides of nitrogen from exhaust gas, comprising a metering appliance for an overstoichiometric supply of one of NH.sub.3 and materials releasing NH.sub.3, and at least one NH.sub.3 sensor configured to interrupt the supply when an NH.sub.3 quantity exceeds a specified upper threshold value, and an NH.sub.3 sensor configured to recognize a specific lower threshold value of a stored NH.sub.3 quantity and to resume the supply when, in the catalyzer, the stored NH.sub.3 quantity reaches the specified lower threshold value.
2. The device according to claim 1, where the exhaust gas is an diesel engine exhaust gas.
3. The device according to claim 1, wherein the first NH.sub.3 sensor and the another NH.sub.3 sensor are operatively arranged in the catalyzer such that the first NH.sub.3 sensor measures the NH.sub.3 concentration in the exhaust gas and the another NH.sub.3 sensor measures the NH.sub.3 adsorbed in the catalyzer.
4. The device according to claim 1, wherein the another NH.sub.3 sensor is operatively arranged in the catalyzer and the first NH.sub.3 sensor is operatively arranged downstream of the catalyzer such that the first NH.sub.3 sensor measures the NH.sub.3 concentration in the exhaust gas and the another NH.sub.3 sensor measures the NH.sub.3 adsorbed in the catalyzer.