Hydroxylic Acrylate Copolymer, Process for Its Preparation, and Coating Agent Based on the Acrylate

The invention relates to a hydroxylic acrylate copolymer produced by copolymerization of acrylates having at least 2 olefinically unsaturated (sic) double bonds, hydroxylic monomers and further olefinically unsaturated monomers.

EP-A 103,199 has disclosed an acrylate copolymer of the abovementioned type. EP-A 103,199 has also disclosed the processing of the copolymer of the abovementioned type with a suitable crosslinking agent to give a coating agent. An etherified amine/formaldehyde resin is mentioned inter alia as a crosslinking agent.

Moreover, EP-A 64,338 has disclosed an acid-curable coating agent based on an acrylate copolymer and a melamine/formaldehyde resin.

It is the object of the present invention to provide a crosslinkable acrylate copolymer and coating agents which are based on the crosslinkable acrylate copolymer and have an improved fastness to gasoline and an improved resistance to long-term exposure to water or steam.

The object is achieved by a hydroxylic acrylate copolymer of the abovementioned type, which has been obtained from

a.sub.1) 10 to 60% by weight, preferably 15 to 60% by weight, of hydroxylic esters of acrylic/methacrylic acid, having 2 to 14 carbon atoms in the alkyl radical,

a.sub.2) 3 to 25% by weight, preferably 5 to 20% by weight, of monomers having at least 2 polymerizable olefinically unsaturated double bonds, and

a.sub.3) 15 to 82% by weight, preferable 40 to 70% by weight, of further polymerizable monomers having one olefinically unsaturated (sic) double bond, the sum of components a.sub.1, a.sub.2 and a.sub.3 being 100% by weight.

Compounds of the general formula ##STR1## where

R=H or CH.sub.3,

X=0, N or S

n=2 to 8,

can advantageously be used as the component a.sub.2.

Examples of such compounds are hexanediol diacrylate, hexanediol dimethacrylate, glycol diacrylate, glycol dimethacrylate, butanediol diacrylate, butanediol dimethacrylate and similar compounds.

The component a.sub.2 can advantageously also be a reaction product of a carboxylic acid having a polymerizable olefinically unsaturated double bond and glycidyl acrylate and/or glycidylmethacrylate, or a polycarboxylic acid or unsaturated monocarboxylic acid esterified with an unsaturated alcohol.

Moreover, the component a.sub.2 can advantageously be a reaction product of a polyisocyanate and an unsaturated alcohol or amine. The reaction product of one mol of hexamethylene diisocyanate and 2 mol of allyl alcohol may be mentioned as an example.

Another advantageous component a.sub.2 is a diester of polyethylene glycol and/or polypropylene glycol of a mean molecular weight of less than 1500, preferably less than 1000, and acrylic and/or methacrylic acid. According to the invention, acrylates having more than 2 ethylenically unsaturated double bonds, for example trimethylolpropane triacrylates or trimethylolpropane trimethacrylate, can also be used as the component a.sub.2. Of course, combinations of these polyunsaturated monomers can also be used.

The component a.sub.1 can especially be a hydroxyalkyl ester of acrylic and/or methacrylic acid, having a primary hydroxyl group, for example hydroxyethyl acrylate, hydroxypropyl acrylate, hydroxybutyl acrylate, hydroxyamyl acrylate, hydroxyhexyl acrylate, hydroxyoctyl acrylate and the corresponding methacrylates.

Advantageously, the component a.sub.1 can at least partially be a reaction product of one mol of hydroxyethyl acrylate and/or hydroxyethyl methacrylate and, on average, 2 mol of .epsilon.-caprolactone.

Advantageously, up to 75% by weight, and particularly preferably up to 50% by weight, of the component a.sub.1 can also be a hydroxylic acrylic and/or methacrylic acid ester with a secondary hydroxyl group, in particular a reaction product of acrylic and/or methacrylic acid and the glycidyl ester of a carboxylic acid having a tertiary .alpha.-carbon atom. 2-Hydroxypropyl acrylate, 2-hydroxybutyl acrylate, 3-hydroxybutyl acrylate and the corresponding methacrylates may be mentioned as examples.

The choice of the further polymerizable monomers of component a.sub.3 is not particularly critical. These can be chosen from the group comprising styrene, vinyltoluene, acrylic acid, methacrylic acid, alkyl esters of acrylic and methacrylic acid, alkoxyethyl acrylates and aryloxyethyl acrylates and the corresponding methacrylates, and the esters of maleic and fumaric acids. Examples of these are methyl acrylate, ethyl acrylate, propyl acrylate, butyl acrylate, isopropyl acrylate, isobutyl acrylate, pentyl acrylate, isoamyl acrylate, hexyl acrylate, 2-ethylhexyl acrylate, octyl acrylate, 3,5,5-trimethylhexyl acrylate, decyl acrylate, dodecyl acrylate, hexadecyl acrylate, octadecyl acrylate, octadecenyl acrylate, pentyl methacrylate, isoamyl methacrylate, hexyl methacrylate, 2-ethylbutyl methacrylate, octyl methacrylate, 3,5,5-trimethylhexyl methacrylate, decyl methacrylate, dodecyl methacrylate, hexadecyl methacrylate, octadecyl methacrylate, alkoxyethyl acrylates or methacrylates, such as butoxyethyl acrylate or butoxyethyl methacrylate, methyl methacrylate, ethyl methacrylate, propyl methacrylate, isopropyl methacrylate, butyl methacrylate, cyclohexyl acrylate, cyclohexyl methacrylate, acrylonitrile, methacrylonitrile, vinyl acetate, vinyl chloride and phenoxyethyl acrylate. Other monomers can be used, unless they cause undesirable properties of the copolymer.

The invention also relates to a process for the preparation of an acrylate copolymer, which comprises copolymerizing, for its preparation,

a.sub.1) 10 to 60% by weight, preferably 15 to 60% by weight, of hydroxylic esters of acrylic and/or methacrylic acid, having 2 to 14 carbon atoms in the alkyl radical,

a.sub.2) 3 to 25% by weight, preferably 5 to 20% by weight, of monomers having at least 2 polymerizable olefinically unsaturated double bonds and

a.sub.3) 15 to 82% by weight, preferably 40 to 70% by weight, of further polymerizable monomers having one olefinically unsaturated double bond, in an organic solvent with the addition of polymerization initiators and polymerization regulators to give a precrosslinked, ungelled product, the sum of the components a.sub.1, a.sub.2 and a.sub.3 being 100% by weight.

Care must be taken in order to obtain a precrosslinked, but ungelled copolymer. Surprisingly, a clear, transparent, ungelled solution of a branched copolymer can be prepared by means of suitable polymerization conditions. The use of monomers having at least 2 ethylenically unsaturated groups causes precrosslinking of the copolymer molecules, but due to the special reaction conditions according to the invention this nevertheless does not lead to gelled products. These special reaction conditions comprise carrying out the polymerization at temperatures from 80.degree. to 130.degree. C., preferably 90.degree. to 120.degree. C., at a relatively low polymerized solids content of about 50% by weight. Furthermore, it is necessary to use suitable initiators and, depending on the proportion of difunctional monomer, at least 0.5% by weight, but preferably at least 2.5% by weight, of a polymerization regulator (chain stopper), for example mercapto compounds. The choice of the initiator depends on the proportion of the difunctional monomers used. In the case of a low proportion, the initiators conventional for such temperatures, for example peroxy esters, can be used. In the case of a higher proportion of difunctional monomer, initiators such as azo compounds are preferably employed. After the polymerization, the polymer solution is concentrated to the desired solids content, preferably solids contents of 60% by weight, by distilling off the solvent. When adjusted to a solids content of 50% by weight, the clear copolymer solutions thus obtained have a viscosity of 0.4 to 10 dPas.

Surprisingly, measurements on the acrylate copolymer solutions by means of photon-correlation spectroscopy do not indicate any microgel content.

The invention also relates to a coating agent which contains a binder, organic solvents, if appropriate pigments, fillers and conventional assistants and additives and, if appropriate, is curable by means of a catalyst and which, as the essential binder, contains the acrylate copolymer according to the invention and a binder suitable for cross-linking the former.

The invention relates to a coating agent which is curable by means of acid and, as the essential binder, contains

A) 55 to 90% by weight, preferably 70 to 80% by weight, of the acrylate copolymer according to the invention and

B) 10 to 45% by weight, preferably 20 to 30% by weight, of a melamine/formaldehyde resin having a mean molecular weight from 250 to 1000 and a degree of a methylolation of at least 0.65, preferably 0.9 to 1, which resin is etherified with monoalcohols having 1 to 4 carbon atoms and/or monoethers of diols having 2 to 7 carbon atoms in total, to an extent of at least 80 mol %, preferably 90 to 100 mol %, based on the maximum possible etherification, the sum of the binders A) and B) being 100% by weight.

Preferably, 25 to 40% by weight of the component a.sub.1 is used, the sum of components a.sub.1, a.sub.2 and a.sub.3 being 100% by weight.

The melamine/formaldehyde resin used as the binder B) can have been etherified with, for example, methanol, ethanol, propanol and butanol. Hexakis-(methoxy)-methylmelamine is very suitable. Of course, the component B can also consist of urea/formaldehyde and benzoguanamine formaldehyde resins.

Before they are used, the coating agents according to the invention are mixed with an acid catalyst, in order to reduce the curing temperature and to accelerate curing. The catalyst is used in a quantity of 1 to 5% by weight, preferably 1.5 to 3.5% by weight, based on the solids content of binders A) and B). Sulfonic acid compounds, in particular p-toluene sulfonic acid, are particularly suitable. Mixtures of catalysts can also be employed.

To extend the pot life to 6 to 24 hours after the addition of the catalyst, the coating agent advantageously contains a quantity of a nitrogen-containing compound, equivalent to the quantity of acid, or a part of this quantity, depending on the desired extension of the pot life.

An extension of the pot life can advantageously also be obtained by an addition of 5 to 35% by weight, based on the solids content of binder, of one or more alcohols, of which ethanol, butanol and mixtures thereof are preferred.

The invention also relates to a process for the preparation of an acid-curable coating agent, which comprises copolymerizing, for the preparation of an hydroxylic acrylate copolymer,

A) a.sub.1) 10 to 60% by weight, preferably 15 to 60% by weight, of hydroxylic esters of acrylic and/or methacrylic acid, having 2 to 14 carbon atoms in the alkyl radical,

a.sub.2) 3 to 25% by weight, preferably 5 to 20% by weight, of monomers having at least 2 polymerizable olefinically unsaturated (sic) double bonds and

a.sub.3) 15 to 82% by weight, preferably 40 to 70% by weight, of further polymerizable monomers having one olefinically unsaturated (sic) double bond, in an organic solvent with the addition of polymerization initiators and polymerization regulators to give a precross-linked, ungelled product, the sum of the components a.sub.1, a.sub.2 and a.sub.3 being 100% by weight, and processing this copolymer A) in a proportion of 55 to 90% by weight, preferably 70 to 80% by weight, with

B) 10 to 45% by weight, preferably 20 to 30% by weight, of a melamine/formaldehyde resin having a molecular weight from 250 to 1000 and a degree of methylolation of at least 0.65, preferably 0.9 to 1, which resin is etherified with monoalcohols of 1 to 4 carbon atoms and/or monoethers of diols having 2 to 7 carbon atoms in total, to an extent of at least 80 mol %, preferably 90 to 100 mol %, based on the maximum possible etherification, and with organic solvents and, if appropriate, pigments and conventional assistants and additives, by mixing and, if necessary, dispersing to give a coating composition, the sum of binders A) and B) being 100% by weight.

The invention also relates to a coating agent which, as the essential binder, contains the acrylate copolymer

A) according to the invention and

B) one or more different polyfunctional isocyanates, with the proviso that the ratio of the isocyanate groups and hydroxyl groups is within the range from 0.3:1 to 3.5:1.

Examples of polyfunctional isocyanates, which can be used for crosslinking the hydroxylic copolymers, are 2,4-toluylene diisocyanate, 2,6-toluylene diisocyanate, 4,4'-diphenylmethane diisocyanate, hexamethylene diisocyanate, 3,5,5-trimethyl-1-diocyanato-3-isocyanatomethylcyclohexane, m-xylylene diisocyanate, p-xylylene diisocyanate, tetramethylene diisocyanate, cyclohexane-1,4-diisocyanate, 4,4'-diisocyanatodiphenyl ether, 2,4,6-triisocyanatotoluene and 4,4',4"-triisocyanatotriphenylmethane. The polyisocyanates can be linked to give propolymers of higher molecular weight. Adducts of toluylene diisocyanate and trimethylolpropane, a biuret formed from 3 molecules of hexamethylene diisocyanate, and the trimers of hexamethylene diisocyanate and 3,5,5-trimethyl-1-isocyanato-3-isocyanatomethylcyclohexane may be mentioned here.

In the case of the acrylate copolymers crosslinked with isocyanate groups, preferably 15 to 40% by weight of component a.sub.1 are used, the sum of components a.sub.1, a.sub.2 and a.sub.3 being 100% by weight.

The invention also relates to a process for the preparation of the coating agent, which comprises copolymerizing, for the preparation of the acrylate copolymer,

A) a.sub.1) 10 to 60% by weight, preferably 15 to 60% by weight, of hydroxylic esters of acrylic and/or methacrylic acid, having 2 to 14 carbon atoms in the alkyl radical,

a.sub.2) 3 to 25% by weight, preferably 5 to 20% by weight, of monomers having at least 2 polymerizable olefinically unsaturated (sic) double bonds and

a.sub.3) 15 to 82% by weight, preferably 40 to 70% by weight, of further polymerizable monomers having one olefinically unsaturated (sic) double bond, in an organic solvent with the addition of polymerization initiators and polymerization regulators to give a pre-crosslinked, ungelled product, the sum of components a.sub.1, a.sub.2 and a.sub.3 being 100% by weight, and processing this copolymer A) with

B) one or more different polyfunctional isocyanates and with organic solvents and, if appropriate, pigments and conventional assistants and additives, by mixing and, if necessary, dispersing to give a coating composition, with the proviso that the ratio of the isocyanate groups and hydroxyl groups is within the range from 0.3:1 to 3.5:1.

In the process according to the invention, one or more catalysts in a quantity of 0.01 to 1% by weight, based on the solids content of the reacting components, can be used. The preferred catalysts used are amines, for example dimethylethanolamine. When catalysts are added the curing temperature can be reduced and curing can be accelerated. The isocyanate curing according to the invention can be carried out at temperatures as low as room temperature. At very high temperatures, the addition of a catalyst is unnecessary.

The coating agents according to the invention can be cured at low temperatures, for example at 20.degree. to 80.degree. C., and are therefore employed particularly for automobile finish repairs.

The invention also relates to a process for the preparation of a coating, wherein an acid catalyst in a quantity of 1 to 5% by weight, preferably 1.5 to 3.5% by weight, based on the solids content of binders A) and B), is admixed to a coating agent as claimed in claim 18 or 19, the mixture obtained is applied in the form of a film to a substrate by spraying, flooding, dipping, rolling, knife application or brushing and a film is cured at temperatures from 20.degree. to 80.degree. C. to give a firmly adhering coating.

The invention also relates to a process for the preparation of a coating, wherein a coating agent crosslinked in claim 21 or 22, to which a catalyst may have been admixed, is applied in the form of a film to a substrate by spraying, flooding, dipping, rolling, knife application or brushing and the film is cured to give a firmly adhering coating. The invention also relates to substrates coated by a process according to the invention.

The invention is explained in more detail below by reference to illustrative embodiments.

In the examples which follow, all percentage figures relate to parts by weight, unless otherwise stated. The solids content values were determined in a circulating-air oven after 1 hour at 130.degree. C. The viscosities were determined in a cone-and-plate viscometer.

1. Preparation of acrylate resin I

360 parts of butyl acetate and 180 parts of methoxypropyl acetate are introduced into a 3 l kettle.

The solvent mixture is heated to 110.degree. C. Within 3 hours, the following are metered in uniformly:

Solution 1:

300 parts of methyl methacrylate

250 parts of styrene

150 parts of hexanediol diacrylate

250 parts of butanediol monoacrylate

50 parts of n-butyl acrylate

45 parts of mercaptoethanol

Solution 2:

350 parts of butyl acetate

30 parts of azobisisobutyronitrile

175 parts of methoxypropyl acetate

The polymerization is then completed during a further 3 hours at 110.degree. C. A solids content of 50.5% is reached. About 340 parts of solvent are distilled off in vacuo at 60.degree.-70.degree. C. The clear, colorless acrylate resin solution has a solids content of 60.6%, an acid number of 0.1, an OH number of 97 and a viscosity of 2.0 dPas at 23.degree. C. at a solids content adjusted to 50% with ethylglycol acetate.

2. Preparation of acrylate resin II

360 parts of butyl acetate and 180 parts of methoxypropyl acetate are introduced into a 3 l kettle.

The solvent mixture is heated to 110.degree. C. Within 3 hours, the following are metered in uniformly:

Solution 1:

300 parts of methyl methacrylate

150 parts of styrene

150 parts of hexanediol diacrylate

400 parts of hydroxyethyl methacrylate

45 parts of mercaptoethanol

Solution 2:

350 parts of butyl acetate

30 parts of azobisisobutyronitrile

175 parts of methoxypropyl acetate.

The polymerization is then completed during a further 3 hours at 110.degree. C. A solids content of 50.5% is reached. About 340 parts of solvent are distilled off in vacuo at 60.degree.-70.degree. C. The clear, colorless acrylate resin solution has a solids content of 61.4%, an acid number of 0.4, and an OH number of 173 and a viscosity of 6.6 dPas at 23.degree. C. at a solids content adjusted to 50% with ethyl glycol acetate.

3. Preparation of acrylate resin III

360 parts of butyl acetate and 180 parts of methoxypropyl acetate are introduced into a 3 l kettle.

The solvent mixture is heated to 110.degree. C. Within 3 hours, the following are metered in uniformly:

Solution 1:

300 parts of methyl methacrylate

150 parts of styrene

150 parts of hexanediol diacrylate

150 parts of hydroxyethyl methacrylate

250 parts of butanediol monoacrylate

45 parts of mercaptoethanol

Solution 2:

350 parts of butyl acetate

30 parts of azobisisobutyronitrile

175 parts of methoxypropyl acetate.

The polymerization is then completed during a further 3 hours at 110.degree. C. A solids content of 49.8% is reached. About 340 parts of solvent are distilled off in vacuo at 60.degree.-70.degree. C. The clear, colorless acrylate resin solution has a solids content of 60.9%, an acid number of 0.3, and an OH number of 162 and a viscosity of 3.8 dPas at 23.degree. C. at a solids content adjusted to 50% with ethylglycol acetate.

4. Preparation of acrylate resin IV

240 parts of butyl acetate, 120 parts of methoxypropyl acetate and 10 parts of tert.-butylperoxy 2-ethylhexanoate are introduced into a 3 l kettle.

The solvent mixture and a part of the required quantity of initiator are heated to 110.degree. C. Within 3 hours, the following are metered in uniformly:

Solution 1:

300 parts of methyl methacrylate

250 parts of styrene

75 parts of hexanediol diacrylate

75 parts of hydroxyethyl methacrylate

250 parts of butanediol monoacrylate

50 parts of n-butyl acrylate

35 parts of mercaptoethanol

Within 3.5 hours, the following are metered in uniformly:

Solution 2:

240 parts of butyl acetate

35 parts of tert.-butylperoxy 2-ethylhexanoate

120 parts of methoxypropyl acetate.

The polymerization is then completed during a further 3 hours at 110.degree. C. The clear, colorless acrylate resin solution has a solids content of 61.5%, an acid number of 4.1, and an OH number of 130 and a viscosity of 4.8 dPas at 23.degree. C., at a solids content adjusted to 50% with ethylglycol acetate.

5. Preparation of acrylate resin V

360 parts of butyl acetate, 180 parts of methoxypropyl acetate and 10 parts of tert.-butylperoxy 2-ethylhexanoate are introduced into a 3 l kettle.

The solvent mixture is heated to 110.degree. C. Within 3 hours, the following are metered in uniformly:

Solution 1:

300 parts of methyl methacrylate

250 parts of styrene

75 parts of hexamethylene-bis-methacrylamide

75 parts of hydroxyethyl methacrylate

250 parts of butanediol monoacrylate

50 parts of n-butyl acrylate

35 parts of mercaptoethanol

Within 3.5 hours, the following are metered in uniformly:

Solution 2:

350 parts of butyl acetate

35 parts of tert.-butylperoxy 2-ethylhexanoate

175 parts of methoxypropyl acetate

The polymerization is then completed during a further 3 hours at 110.degree. C. The solids content of 50.9% is reached. About 340 parts of solvent are distilled off in vacuo at 60.degree.-70.degree. C. The clear, colorless acrylate resin solution has a solids content of 61.5%, an acid number of 3.1, an OH number of 130 and a viscosity of 3.6 dPas at 23.degree. C. at a solids content adjusted to 50% with ethylglycol acetate.

6. Preparation of acrylate resin VI

361 parts of butyl acetate and 181 parts of ethylglycol acetate are introduced into a 3 l kettle.

The solvent mixture is heated to 110.degree. C. Within 3 hours, the following are metered in uniformly:

Solution 1:

300 parts of methyl methacrylate

250 parts of styrene

150 parts of ethylene glycol dimethacrylate

250 parts of butanediol monoacrylate

50 parts of n-butyl acrylate

45 parts of mercaptoethanol

Solution 2:

350 parts of butyl acetate

30 parts of azobisiobutyronitrile (sic)

175 parts of ethyl glycol acetate.

The polymerization is then completed during a further 3 hours at 110.degree. C. A solids content of 48.9% is reached. About 340 parts of solvent are distilled off in vacuo at 60.degree.-70.degree. C. The clear, colorless acrylate resin solution has a solids content of 59.1%, an acid number of 1.6, an OH number of 97 and a viscosity of 6.5 dPas at 23.degree. C. at a solids content adjusted to 50% with ethylglycol acetate.

7. Preparation of acrylate resin VII

361 parts of butyl acetate and 181 parts of ethyl glycol acetate are introduced into a 3 l kettle. The solvent mixture is heated to 110.degree. C. Within 3 hours, the following are metered in uniformly:

Solution 1:

300 parts of methyl methacrylate

150 parts of styrene

150 parts of hexanediol diacrylate

250 parts of butanediol monoacrylate

150 parts of a 1:2 reaction product of 2-hydroxyethyl acrylate and caprolactone, as described below

45 parts of mercaptoethanol

Solution 2:

350 parts of butyl acetate

30 parts of ethylglycol acetate

175 parts of ethylglycol acetate

The polymerization is then completed during a further 3 hours at 110.degree. C. A solids content of 50.3% is reached. About 340 parts of solvent are distilled off in vacuo at 60.degree.-70.degree. C. The clear, colorless acrylate resin solution has a solids content of 60.1%, an acid number of 0.7, an OH number of 122 and a viscosity of 7.4 dPas at 23.degree. C. originally and a viscosity of 2.2 dPas at a solids content adjusted to 50% with ethylglycol acetate.

A commercially available reaction product, prepared from one mol of hydroxyethyl acrylate and, on average, 2 mol of .epsilon.-caprolactone, was used.

The items are successively stirred up in a dissolver and then dispersed for 20 minutes in a commercially available laboratory sand mill (10 .mu.m fineness)

The items are stirred up successively in a dissolver and then dispersed for 60 minutes in a commercially available laboratory sand mill (10 .mu.m fineness).

The items are stirred up successively in the dissolver and then dispersed for 20 minutes in a commercially available laboratory sand mill (10 .mu.m fineness).

The items are stirred up successively in a dissolver and then dispersed for 20 minutes in a commercially available laboratory sand mill (10 .mu.m fineness).

The items are stirred up successively in a dissolver and then dispersed for 20 minutes in a commercially available laboratory sand mill (10 .mu.m fineness).

In the examples which follow, testing of the coatings is carried out as follows:

The pendulum hardness is determined by the Konig method.

Resistance to premium gasoline (FAM standard gasoline DIN 51,604) and xylene:

A small cellulose sheet (diameter about 35 mm) impregnated with the particular solvent is placed for the indicated time upon the coating (knife-coated on glass in the viscosity as obtained) and covered. The film is examined for softening and marking.

Damp heat resistance:

A phosphated steel sheet with the conventional structure (cathodic electrocoat primer, epoxy filler, top coat) is exposed for the indicated period to a humidity-saturated atmosphere at 40.degree. C.

After one hour of regeneration time, the test sheet is examined for blisters and loss of gloss.

Sticking test:

One hour after forced drying of the coating, a strip of crepe adhesive tape is stuck on, firmly pressed on and left for one hour. After the adhesive tape has been torn off, the coating is examined for markings.

Adjustment diluent: xylene (18 sec DIN 4)

Adjustment diluent: xylene (18 sec DIN 4)

With forced drying (30 minutes at 60.degree. C.), the following property level is reached (unless otherwise stated, the exposure tests were carried out one hour after removal from the drying oven).

Adjustment diluent: methoxypropyl acetate (18 sec DIN 4)

With forced drying (30 minutes at 60.degree. C.), the following property level is reached (unless otherwise stated, the exposure tests were carried out 1 hour after removal from the drying oven).

With drying at 20.degree. c. (room temperature), the following property level is reached:

Adjustment diluent: methoxypropyl acetate (18 sec DIN 4)

With forced drying (30 minutes at 60.degree. C.), the following property level is reached (unless otherwise stated, the exposure tests were carried out 1 hour after removal from the drying oven).

With drying at 20.degree. C. (room temperature), the following property level is reached:

Adjustment diluent: xylene (18 sec DIN 4)

With forced drying (30 minutes at 60.degree. C.), the following product level is reached (unless otherwise stated, the exposure tests were carried out 1 hour after removal from the drying oven).

Adjustment diluent: xylene (18 sec DIN 4)

With forced drying (30 minutes at 60.degree. C.), the following property level is reached (unless otherwise stated, the exposure tests were carried out 1 hour after removal from the drying oven).

Adjustment diluent: xylene (18 sec DIN 4)

With forced drying (30 minutes at 60.degree. C.), the following property level is reached (unless otherwise stated the exposure tests were carried out 1 hour after removal from the drying oven).

Adjustment diluent: xylene (18 sec DIN 4)

With forced drying (30 minutes at 60.degree. C.), the following property level is reached (unless otherwise stated, the exposure tests were carried out 1 hour after removal from the drying oven):

With forced drying (30 minutes at 60.degree. C.), the following property level is reached:

With forced drying (20 minutes at 120.degree. C.), the following property level is reached:

Pot life in a DIN 4 flow cup, rise from 20 seconds to 52 seconds in 24 hours.

The acrylate resins I and III are examined by photoncorrelation spectroscopy for a content of microgel particles. The result of the examination is that there is no analytical indication of a microgel content. The resin solutions were examined by means of a Coulter Model N 4 sub-micron particle analyzer of Curtin Matheson Scientific Inc., Detroit, Mich., USA.