US 5,084,430 AGrant
Sulfur and Nitrogen Containing Hydrocarbons and Process of Using Same in Separating Desired Ions From Solutions Thereof
Issue Date:1992-01-28
•6 Claims
•1 Drawing Sheets
Abstract
Compositions of matter are disclosed comprising nitrogen containing hydrocarbons which are modified with at least one of the elements selected from the group consisting of sulfur, phosphorus an arsenic, with the modified hydrocarbons being covalently bonded to trialkoxysilane. These modified hydrocarbons are further covalently bonded to a solid inorganic support such as silica to form a solid complexing agent. The complexing agents are particularly useful in a process of removing and/or concentrating certain ions, such as noble metal ions and other transition metal ions, from solutions thereof admixed with other ions by forming a complex of the desired ion(s) with the complexing agent. The solution preferably flow through a column packed with the complexing agent to form the complex of the desired ion(s). The desired ion(s) are recovered from the column by subsequently flowing a receiving liquid through the column, wherein the receiving liquid is adapted to break the complex and receive ion(s) in solution in the receiving liquid. The receiving ion(s) can then be separated from the receiving liquid if so desired.
Metadata
Assignee
- Brigham Young University
Inventors
- Bryon J. Tarbet
- Ronald L. Bruening
- Jerald S. Bradshaw
- Reed M. Izatt
Application Information
Application Number:US 542013&
Filing Date:1990-06-22
Priority Date:1988-08-26
Art Unit:116
Classifications
IPC:
B01J 2022
Field of Search:
502401
Patent Drawings (1 sheets)
Description
Brief Description of the Drawing
The drawing shows schematically a reaction sequence illustrating a preferred method for producing hydrocarbon compositions of the present invention which are covalently bonded to an inorganic solid support or matrix.
Description of the Preferred Embodiments of the Invention
The new compositions of the invention are represented by formula (1) as given above. These compositions consist of certain sulfur and nitrogen containing hydrocarbon ligands which are covalently bonded to an inorganic solid support in accordance with the invention.
In producing the novel compositions of formula (1), a glycidoxyalkyltrialkoxysilane is covalently bonded to any inorganic solid support which has surface hydroxylic groups capable of reacting with the alkoxy silane portion of the reactant as shown in the first step of the reaction sequence shown in the drawing. The reaction can take place by first, dissolving the starting silane compound in a low boiling solvent such as dichloromethane, adding the solid support, removing the low boiling solvent, then heating the coated support at about 120.degree. C. for 3 to about 18 hours under vacuum. A second procedure for bonding the alkoxysilane portion of the reactant with the solid support is to heat the solid support with the reactant in a high boiling solvent such as toluene. In a subsequent step or steps ethylenediamine is reacted with the epoxide function, and the intermediate is further reacted with ethylene sulfide to give a material containing both sulfur and nitrogen, such as (CH.sub.3 O).sub.3 Si(CH.sub.2).sub.3 OCH.sub.2 CH(OH)CH.sub.2 NRCH.sub.2 CH.sub.2 NRH, where R is a repeating ethylenethio group.
The following three examples are given to illustrate compounds which have been made in accordance with formula 1 of the present invention. These examples are illustrative only and are not comprehensive of the many different compounds which have or can be made within the scope of the present invention.
Example 1
Silica gel (30 g, 60-22 mesh) was slowly added to 375 mL of toluene and 7.5 g of .gamma.-glycidoxypropyltrimethoxysilane. The mixture was maintained in suspension by mechanical stirring and was heated at reflux overnight. Ethylenediamine (1.25 g) was then added to the suspension and heated an additional 5 hours. The mixture was allowed to cool and 5.2 g of ethylene sulfide was added. The suspension was stirred at room temperature for 6 hours and then heated to 80.degree. C. overnight to effect reaction. The product was isolated by filtration and allowed to air dry.
Example 2
Silica gel was covalently attached to .gamma.-glycidoxypropyltrimethoxysilane in the same manner as given in Example 1. This intermediate was then reacted with pentaethylenehexamine and ethylene sulfide successively as in Example 1 in a mole ratio of 3 to 1 such that there are three ethylenethio groups per nitrogen.
Example 3
Silica gel was covalently attached to .gamma.-glycidoxypropyltrimethoxysilane in the same manner as given in Example 1. This intermediate was then reacted with pentaethylenehexamine, and 5 g of the resulting nitrogen containing intermediate was suspended in toluene at -40.degree. C. in a flask equipped with a mechanical stirrer and a dropping funnel. Into the dropping funnel was placed 2.5 g of chlorodiphenylphosphine. The phosphine was added slowly to the flask and the mixture was allowed to come to room temperature. The amount of phosphine added to the flask was sufficient to put one phosphorus group on each nitrogen atom of the nitrogen containing intermediate. The final product was isolated by filtration and washed extensively with methanol and a solution of sodium bicarbonate in water to remove any trace of acid from the synthesis.
Metal Ion Recovery and Concentration Process
The metal ion recovery and concentration process of the invention relates to the selective recovery of desired metal ions from mixtures thereof with other metal ions using the compounds of formula 1 of the invention as defined above. Effective methods of recovery and/or separation of metal ions, particularly the noble metal ions, from other metal ions in water supplies, waste solutions, deposits and industrial solutions and silver recovery from waste solutions, e.g., from emulsions on photographic and X-ray film, represent a real need in modern technology. These ions are typically present at low concentrations in solutions containing other ions in much greater concentration. Hence, there is a real need for a process to selectively recover and concentrate these metal ions. The present invention accomplishes this separation effectively and efficiently by the use of compounds selected from the families represented by formula (1).
The material of formula (1) is preferably placed in a column. An aqueous solution containing the desired ion(s), in a mixture of other ions, which may be in much greater concentration, is passed through the column. The flow rate may be controlled by applying pressure to the top of the column or by applying vacuum to the receiving vessel at the bottom of the column. After the solution has passed through the column, a volume of a recovery solution, i.e. aqueous sodium thiosulfate, aqueous ammonia, or aqueous sodium cyanide, which forms a stronger complex with the desired noble metal ions, or in their absence other metal ions, as stated above, is passed through the column. This recovery solution contains only the desired metal ions in a more concentrated form.
The following examples of separations of metal ions by the sulfur and nitrogen containing materials of Examples 1, 2 and 3 are given as illustrations. These examples are illustrative only and are not comprehensive of the many separations of noble metal, platinum group metal, and in some cases transition metal ions that are possible using the materials made within the scope of this invention.
Example 4
In this example, 4 g of the sulfur and nitrogen containing hydrocarbon of Example 1 was placed in a column. A 500 mL solution of approximately 10 ppm (parts per million) copper ion in 1M HCl was drawn through the column using a vacuum pump at 600 torr to increase the flow rate. A 25 mL aqueous solution of 2M NH.sub.3, 1M HCl was then passed through the column. Analysis of the recovery solution by atomic absorption spectroscopy (AA) showed greater than 95% of the copper (II) ions originally in the 500 mL solution described above was in the 25 mL recovery solution.
Example 5
The experiment of Example 3 was repeated with 10 g of the silica-bound sulfur and nitrogen-containing hydrocarbon of Example 2. A 100 mL solution of 10 ppm Au (I) in 0.01M KCN was passed through the column. A 10 mL aqueous solution of 5M KCN was then passed through the column. Analysis of the recovery solution by AA showed that about 90% of the Au (I) ions originally present in the 100 mL Au (I) solution was found in the 10 mL recovery solution.
Example 6
In this example, 2 g of the silica gel bonded phosphorus and nitrogen containing hydrocarbon of Example 3 was placed in a column. A 25 mL solution containing approximately 1000 ppm palladium ions in 5M nitric acid was passed through the column. A 25 mL aqueous stripping solution of 1M thiourea and 0.1M acetic acid was then passed through the column. Analysis of the recovered stripping solution by both atomic absorption spectroscopy (AA) and inductively coupled plasma spectroscopy (ICP) showed that over 90% of the palladium in the original loading solution was recovered in the stripping solution.
From the foregoing, it will be appreciated that the sulfur and nitrogen containing hydrocarbon ligands of formula (1) bonded to a solid support in accordance with the present invention provide a material useful for the separation and concentration of the noble metal cations from mixtures of those cations with other metal cations and also in the presence of strong acids or strong complexing agents. The noble metals can then be recovered from the concentrated recovery solution by standard techniques known in the science of these materials. In the absence of noble metal ions, other transition metal ions may be selectively recovered.
Although the invention has been described and illustrated by reference to certain sulfur and nitrogen containing hydrocarbon ligands of formula (1) and the process of using them, analogs of these sulfur and nitrogen containing hydrocarbon ligands are within the scope of the compounds and processes of the invention as defined in the following claims.
Claims
We claim:
1. A compound of the formula ##STR2## wherein A and B are members independently selected from the group consisting of N(R), N(R)CH.sub.2, O, OCH.sub.2, S and SCH.sub.2 ; R is a member selected from the group consisting of H, lower alkyl, aryl and [(CH.sub.2).sub.f E].sub.g R.sup.4 ; D is a member selected from the group consisting of H, SH, OH, NH(R), lower alkyl and N(R)[CH.sub.2 CHR.sup.1 CH.sub.2 O].sub.b (CH.sub.2).sub.a SiXYZ; X, Y and Z are members independently selected from the group consisting of Cl, O-matrix, OCH.sub.3, OC.sub.2 H.sub.5, methyl, ethyl and halogenated substituents thereof; R.sup.1, R.sup.2 and R.sup.3 are members independently selected from the group consisting of H, SH, OH, lower alkyl, aryl, dialkylphosphino, diarylphosphino, dialkylarsino, diarylarsino and [(CH.sub.2).sub.f E].sub.g R.sup.4 ; E is selected from the group consisting of S, Se and Te; R.sup.4 is a member selected from the group consisting of H, lower alkyl and aryl; a is an integer from 2 to about 10; b is an integer of 0 or 1; c is an integer from 1 to about 2000; d is an integer from 0 to about 2000; f is an integer from 2 to about 10; g is an integer from 1 to about 20; matrix is selected from the group consisting of sand, silica gel, glass, glass fibers, alumina, zirconia, titania and nickel oxide; with the following provisos: (1) if A is selected from the group consisting of O, OCH.sub.2, S and SCH.sub.2, then B must be selected from the group consisting of N(R) and N(R)CH.sub.2, (2) that at least one of the groups R, R.sup.1, R.sup.2 and R.sup.3 must be present in the compound as a member independently selected from the group consisting of SH, dialkylphosphino, diarylphosphino, dialkylarsino, diarylarsino and [(CH.sub.2).sub.f E].sub.g R.sup.4, and (3) d can be the integer 0 only if A is selected from the group consisting of N(R) and N(R)CH.sub.2.
2. A compound as defined in claim 1, wherein R.sup.1 is OH.
3. A compound as defined in claim 1, wherein a is 3, b is 1, c is 1, d is 1, R.sup.1 is OH, R.sup.2 and R.sup.3 are both H, A is N(R), B is NH and D is SH.
4. A compound as defined in claim 1, wherein a is 3, b is 1, c is 1, d is 0, R.sup.1 is OH, R.sup.2 and R.sup.3 are both H, A contains nitrogen, d is 0, and D is ##STR3##
5. A compound as defined in claim 1, wherein a is 3, b is 1, c is 4, d is 1, R.sup.1 is OH, R.sup.2 and R.sup.3 are both H, A contains nitrogen, B contains nitrogen, ##STR4##
6. A compound as defined in claim 1, wherein X, Y and Z are (O-matrix).
Patent Citations (2)
| Patent | Date | Inventor | Cited By |
|---|---|---|---|
| US4767670 | 1988-08-01 | Cox et al. | |
| EPX276138 | 1988-07-01 |