In the accompanying drawings which illustrate, by way of example, embodiments of the present invention,
FIG. 1 is a plan view of a partially made form depicting, optical interference authenticating device for depicting a stylized maple leaf,
FIGS. 2 and 3 are diagrammatic, section, exploded end views along II--II, FIG. 1 of two different embodiments of FIG. 1,
FIGS. 4 to 6 are similar, sectional end views to that shown in FIG. 2 in that they are for depicting the same stylized maple leaf outline shown in FIG. 1, but which show fully made authenticating devices to that shown in FIGS. 1 and 2,
FIGS. 7 to 9 show diagrammatic, sectional, exploded end views along II--II, FIG. 1 of different, optical interference coatings,
FIGS. 10 to 12 are plan views of form depicting, optical interference authenticating devices having different stylized maple leaves and using the optical interference coatings shown in FIGS. 8 and 9,
FIG. 13 is a diagrammatic, section, exploded end view along XIII--XIII, FIG. 14, of a different, optical interference coating to those shown in FIGS. 7 to 9,
FIG. 14 is a plan view of a form depicting, optical interference authenticating device using the topical interference coating shown in FIG. 13,
FIG. 15 is an enlarged, plan view of a portion of the device shown in FIG. 14,
FIG. 16 is a plan view of another form depicting, optical interference authenticating device,
FIG. 17 is a diagrammatic, exploded end view of the device shown in FIG. 16,
FIG. 18 is a plan view of yet another form depicting, optical interference authenticating device,
FIG. 19 is a diagrammatic, sectional, exploded end view along XIX--XIX, FIG. 18 and
FIG. 20 is a diagrammatic, sectional, exploded end view along II--II, FIG. 1, but of a different, optical interference authenticating device.
Referring now to FIGS. 1 and 2 there is shown a partially made optical interference authenticating device comprising, a substrate 1, and a stylized leaf form depicting, optical interference coating 2 on the substrate 1, the form depicting coating 2 partially covering one side of the substrate 1 and being shaped so that a distinctive form is provided thereon which may be discerned, the form depicting coating 2 comprising at least one optical interference layer, the material and thickness of which have been selected for the form depicting coating 2 to have particular, known spectral reflectance and spectral transmittance characteristics when viewed at a particular angle, whereby the distinctive form is made visible by reflected or transmitted light of a particular colouration when viewed at a particular angle.
The substrate 1 may be a polyester film. The form depicting coating 2 has an outer boundary 4 for, as will be described later, depicting the stylized maple leaf. Thus the optical interference coating 2 covers only the portion of the surface area of the substrate 1 over which the form will be discernable. The form depicting coating 2 may comprise at least one optical interference layer selected from the group consisting of commonly used non-absorbing optical coating materials such as, for example, cryolite, MgF.sub.2, SiO, SiO.sub.2, ThF.sub.4, TiO.sub.2. ZnS and ZrO.sub.2, and absorbing materials such as, for example, Ag, Al, Au, Cu, Cr, Ge, Ni, NiCr and Si. The thickness of the or each layer of the optical interference layer will normally be within one or two orders of magnitude of 0.1 .mu.m.
In FIG. 3, an optical interference form depicting coating 6 is provided on the substrate 1. The form depicting coating 6 has an inner boundary 8 delineating a stylized maple leaf similar to that shown in FIG. 1. Thus the form depicting coating 6 covers the portion of the surface area of the substrate 1 around the profile 4, as shown in FIG. 1.
In FIGS. 4 to 6, similar parts to those shown in any of FIGS. 1 to 3 are designated by the same reference numerals and the previous description is relied upon to describe them. In each of the FIGS. 4 to 6 the fully made device has at least one additional, optical interference, contrast coating, the materials and thicknesses of which are selected so that these coatings have different known spectral transmission and spectral reflectance to the other coatings.
In FIG. 4, the embodiment shown in FIG. 2 is provided with an optical interference, contrast coating 12 on the side of the same side of the substrate 1 as the coating 2 and completely covering the substrate 1.
As with any of the following embodiments, any contrast coating, such as optical interference, contrast coating 12, comprises at least one optical interference layer, the materials and thicknesses of which are selected so that the coating 12, in combination with the form depicting coating 2, has different, known, spectral reflectance and spectral transmittance characteristics to that portion o the coating 12 which does not overly the coating 2, due at least in part to optical interference of light partially reflected or transmitted at the interfacial contact.
If the substrate 1 is transparent or semi-transparent then the spectral reflectance or spectral transmittance characteristics of the coatings 2 and 12 may be viewed from either side. However, if the spectral reflectance characteristics of the coatings 2 and 12 are viewed through the substrate 1 then the substrate 1 may form an outer, protective covering for the coatings 2 and 12.
If the substrate 1 is substantially opaque then the spectral reflectance characteristics of the coatings 2 and 12 are viewed only from the exposed side face of the coating 12.
In FIG. 5 the embodiment shown in FIG. 3 is provided with an optical interference, contrast coating 14 between the substrate 1 and the coating 6 and completely covering the substrate 1.
If the substrate 1 is transparent or semi-transparent, and the coating 14 is transparent or semi-transparent at a particular angle, then the combined effect of the coatings 2 and 14 may be viewed through the substrate 1 in the same manner as the coatings 2 and 12 (FIG. 4). Similarly, if the substrate 1 is substantially opaque then the spectral reflectance characteristics of the coatings 2 and 14 can only be viewed from the exposed side face of the coating 14.
In FIG. 6 the substrate 1 is provided with a first optical interference contrast coating 16 then a form depicting coating 2, then a second optical interference contrast coating 18 then another, form depicting coating 2. In this embodiment, if the substrate 1 is opaque then the coating 18 and the coatings 2 are transparent or translucent at a particular angle in order that the reflectance characteristic of the coating 16 may be seen as a part of the resulting reflectance characteristic of all of the coatings 2, 16 and 18. If the substrate 1 is transparent or semi-transparent then the coatings 16 and 18 and the inner coating 2 must be transparent or semi-transparent at a particular angle if the combined reflectance characteristic of all the coatings 16 and 18 and coatings 2 is to be viewed through the substrate 1.
FIG. 7 shows a diagrammatic sectional side view of one of the coatings 2, 6, 12, 14, 16 or 18 shown in FIGS. 1 to 6, wherein all of the layers 20 to 23 are of uniform thickness and the spectral transmission and reflectance characteristics of each layer is determined by the material from which that layer is made and the thickness of that layer, and the colouration depends at least in part by optical interference of light partially reflected or transmitted at the interfacial contacts between the layers 20 to 23.
Examples of the different ways in which the embodiments shown in FIGS. 1 to 7 may function is given in the following table which illustrates, as far as the examples are concerned, what may be seen when these devices are viewed at normal incidence thereto and what may be seen when these devices are viewed at an oblique angle of incidence thereto.
In FIG. 8 similar parts to those shown in FIG. 7 are designated by the same reference numerals and the previous description is relied upon to describe them.
In FIG. 8 there is an optical interference coating having a layer 24 which gradually increases in thickness from one edge to another one so that the spectral reflectance and transmittance characteristics will vary from one edge to another one. This can be used to vary the spectral reflectance and transmittance characteristics across the from or the area around the form or both
In FIG. 9 a more complex variation of the spectral reflectance and transmittance characteristics of an optical interference coating is obtained by all of the layers 26 to 29 gradually increasing in thickness from one edge to another one.
As shown in FIG. 10 to 12, the optical interference coatings shown in FIG. 8 or 9 may be used to vary the spectral reflectance characteristics across a stylized maple leaf form 30, the area 32 around the stylized maple leaf form 30, or both, respectively.
In FIG. 13 to 15 there is shown a form depicting, optical interference coating comprising three layers 34 to 36. The layers 34 to 35 each have marginal edge portions 38 to 40 therearound which decrease in thickness in outward directions.
As shown in FIGS. 14 and 15, the optical interference coating shown in this embodiment is used to provide a stylized maple leaf 38 with a multi-coloured aureole 40 therearound against a contrast 42 when viewed at an angle.
FIGS. 16 and 17 show a substrate 4 having form depicting, optical interference coatings 46 to 48, and optical interference, contrast coatings 50 to 52 covering the whole of the substrate 44.
As shown in FIG. 16, the form depicting coatings 46 to 48 partially overlie one another and in so doing produce a more complex geometric pattern of areas having different spectral reflectance and transmittance characteristics. It will be appreciated that the materials and thicknesses of all of the coatings 46 to 48 and 50 to 52 are chosen so that these coatings have suitable spectral reflectance and transmittance characteristics for the complex geometric pattern to be visible in reflected light or, if the substrate 44 is transparent or semi-transparent, for the complex geometric pattern to be visible in transmitted light, due at least in part to optical interference of light partially reflected or transmitted at each interfacial contact.
FIGS. 18 to 19 show a substrate 54 having form depicting, optical interference coatings 56 to 59, and optical interference coatings 60 to 61 covering the whole of the substrate 54.
As shown in FIG. 18, the form depicting coatings provide a device having very complex areas of different reflectance and transmittance characteristics.
FIG. 20 shows a transparent or semi-transparent substrate 64 sandwiched between form depicting, optical interference coatings 2 and 2, and optical interference coatings 12 and 12 which completely cover the substrate 64.
The device shown in FIG. 20 will exhibit a complex, geometric pattern by spectral transmission, due at least in part to optical interference of light partially reflected or transmitted at each interfacial contact.
The form depicting coatings can be created in a number of different ways:
1. by evaporation through suitable masks,
2. by laser excavation (see co-pending Canadian patent) application No.
3. by selective laser activated chemical vapour deposition,
4. by transfer from a substrate selectively treated with a release coating, or by
other methods known to these skilled in the art.