US 4,995,723 AGrant
Method and Apparatus for Optically Coupling an Element Analysis System and a Laser to Liquid Metal in a Melting Vessel
Issue Date:1991-02-26
•7 Claims
•1 Drawing Sheets
Abstract
A method of analyzing elements of a metal melt contained in a melting vessel comprises the following steps: introducing an inert gas at a temperature in excess of 300.degree. C. laterally into a tube passing through a lateral wall of the melting vessel and opening thereinto; generating a laser beam; passing the laser beam through an adjustable first lens system; reflecting the laser beam by a mirror into the tube; guiding the laser beam through a quartz window which closes the tube; generating a plasma in the tube by focusing the laser beam by the adjustable first lens system onto the surface of the metal melt in the tube; guiding the light generated by the plasma through the quartz window to an adjustable second lens system; coupling the light by the adjustable second lens system with an optical waveguide; and introducing the light by the optical waveguide into a spectrometer.
Metadata
Assignee
- Fried. Krupp Gesellschaft Mit Beschrankter Haftung
Inventors
- Christoph Carlhoff
- Claus-Jurgen Lorenzen
- Klaus-Peter Nick
Application Information
Application Number:US 4143876
Filing Date:1989-09-29
Priority Date:1988-10-03
Art Unit:255
Classifications
IPC:
G01J 3443G01N 2163
Field of Search:
356317;318
Patent Drawings (1 sheets)
Description
Brief Description of the Drawing
The sole FIGURE is a schematic elevational view of a preferred embodiment of the invention.
Description of the Preferred Embodiments
A vessel 1 provided with a refractory lining 2 and serving for the production of steel has a bore 2a below the slag level 3. A tube 4 equipped with a gas inlet nipple 5 and a quartz window 6 is received in the bore 2a and terminates at the inner wall face 2b of the lining 2. The tube section 4a extending in the lining 2 from the wall face 2b has an inner diameter of 6 mm and is composed of ceramic. The subsequent tube section 4b connected with a housing 7 is made of high-grade steel. The ceramic tube section 4a is affixed to the lining 2 and the tube section 4b by an adhesive.
Argon at a temperature of more than 500.degree. C. is introduced into the tube 4 through the nipple 5. In the housing 7 a solid state laser beam generator 8 and optical components for guiding the laser and plasma light beams are disposed. The light of the pulsed solid state laser beam generator 8 is focused by means of a lens system 9 and mirror 10 onto the free surface 12 of the melting bath. The metal vapor plasma 11 is produced in the focal point of the laser beam.
The major part of the light emitted by the hot plasma travels past the mirror 10--which blocks only about 20% of the light exit surface--and impinges on a lens system consisting of lenses 13a and 13b which couples the light beam to an optical waveguide 14 made of quartz with cross-sectional conversion of a circular into a rectangular cross-section.
The plasma light travels through the optical waveguide 14 into a spectrograph 15 through an entrance slit 16 thereof. The spectrograph 15 is furnished with a detector system (not shown).
The detectorsystem is connected to a computer that analyses the iron line intensities Fe.sub.I and Fe.sub.II, calculates the relation Fe.sub.I /Fe.sub.II and energieses the drives 17 and 18 which move the supports of the lenses 9 and 13a synchronously the same distance until Fe.sub.I /Fe.sub.II is a minimum. Then the laser light is focused at the metal surface in the bore and at the same time the plasma is focused at the input of the wave guide. The plasma is at the focal plane of lens 13a.
It will be understood that the above description of the present invention is susceptible to various modifications, changes and adaptations, and the same are intended to be comprehended within the meaning and range of equivalents of the appended claims.
Claims
What is claimed is:
1. A method of analyzing elements of a metal melt contained in a melting vessel, comprising the following steps: (a) introducing an inert gas at a temperature in excess of 300.degree. C. laterally into a tube passing through a lateral wall of the melting vessel and opening thereinto; (b) generating a laser beam; (c) passing the laser beam through an adjustable first lens system; (d) reflecting the laser beam by a mirror into said tube through a quartz window closing said tube; (e) generating a plasma in said tube by focusing the laser beam by said adjustable first lens system onto the surface of the metal melt in said tube by the condition that the relation of the intensities Me.sub.I /Me.sub.II is a minimum; (f) guiding the light generated by the plasma through said quartz window to an adjustable second lens system; (g) coupling the light by said second lens system with an optical waveguide so that the plasma is focused on the input end of the waveguide; and (h) introducing the light by the optical waveguide into a spectrometer.
2. A method as defined in claim 1, wherein said inert gas is argon.
3. A method as defined in claim 2, wherein said temperature is in excess of 500.degree. C.
4. A method as defined in claim 1, further comprising the step of varying said adjustable first and second lens systems upon changes of wall thickness of the melting vessel, such that the laser beam continues to be focused on said surface of the metal melt and the generated plasma is focused continuously on the input end of the waveguide.
5. An apparatus for the emission spectrum analysis of a metal melt contained in a melting vessel, comprising (a) a housing; (b) a tube connected to said housing and extending therefrom and being adapted to pass through a wall of the melting vessel; the tube having an open end for communicating with the metal melt, whereby a surface of the metal melt is exposed in the tube; (c) a quartz window closing said tube at a distance from said open end; (d) a gas intake nipple provided in said tube between said open end and said quartz window for introducing an inert gas into the tube; (e) a laser beam generator accommodated in the housing; (f) a mirror supported in said housing and oriented for reflecting a laser beam, emitted by the laser beam generator, into said tube through said quartz window; (g) an adjustable first lens system arranged in the path of the laser beam for focusing the laser beam on the surface of the metal melt to generate a plasma thereon; (h) a spectrometer situated externally of said housing; (i) an optical waveguide extending from the housing to the spectrometer; and (j) an adjustable second lens system for directing light, emitted by the plasma and passing through the quartz window, into the optical waveguide for introduction therefrom into said spectrometer.
6. An apparatus as defined in claim 5, wherein said tube has two consecutive length portions of unlike diameter; the length portion closer to the housing having the greater diameter.
7. An apparatus as defined in claim 6, wherein the length portion of smaller diameter is ceramic and the length portion of greater diameter is metal.
Patent Citations (2)
| Patent | Date | Inventor | Cited By |
|---|---|---|---|
| US4818106 | 1989-04-01 | Koch et al. | |
| DEX3413589 | 1985-10-01 |