US 4,797,981 AGrant
Process for the Production of Salt
Issue Date:1989-01-17
•9 Claims
Abstract
Process for the production of salt in which sodium chloride is crystallized in the form of spheres by evaporation of a sodium chloride brine and the spheres obtained are then broken up. The salt produced by the process is particularly suitable for the food industry.
Metadata
Assignee
- Solvay & Cie (Societe Anonyme)
Inventors
- Leon Ninane
- Claude Breton
Application Information
Application Number:US 9402209
Filing Date:1986-12-08
Priority Date:1984-04-16
Art Unit:113
Classifications
IPC:
B01D 900C01D 306
Field of Search:
42323267;499303;313 FB;313 P
Patent Drawings
This patent does not have any drawings.
Description
Background of the Invention
1. Field of the Invention
The present invention relates to a process for the production of salt. More particularly, it concerns a process according to which sodium chloride is crystallised by evaporation of a sodium chloride brine.
2. Background of the Art
A process which has been in use for a long time for manufacturing food-grade salt consists in heating a sodium chloride brine below its boiling point, in open basins or pans, of a low height, which have a large evaporation area ("Sodium Chloride", Kaufmann, Reinhold Publishing Corp., 1960, p. 262).
The salt obtained by this known process, usually called "pan salt", is generally in the form of coarse, non-uniform particles, translucent and glassy in appearance, which is easy to use and which is, consequently, valued by certain users, for example for salt-preserving methods.
However, this salt manufacturing process has the disadvantage of being too costly, since the efficiency of heating brines in the pans is, in fact, very low. It has the additional disadvantage of requiring plant which occupies a very large ground area.
To overcome the above-mentioned disadvantages of this known process it has also been proposed to process sodium chloride brines in multistage evaporators (op. cit., p. 205).
Compared to the process for manufacturing pan salt described earlier, the use of multistage evaporators, which generally operate at a reduced pressure, permits a considerable fuel saving and is, moreover, adaptable to plant which occupies a smaller ground area.
However, the salt obtained by this known process is completely different from pan salt in appearance; it is usually in the form of fine particles, matt and opaque in appearance, the uses of which do not generally correspond to those of pan salt.
Summary of the Invention
The invention is aimed at providing a process which permits the production, at a low cost, of a salt having properties which are similar to those of pan salt.
To this end, the invention relates to a process for the production of salt, according to which sodium chloride is crystallised by evaporation of a sodium chloride brine. According to the invention, sodium chloride is crystallised in the form of spheres which are subsequently broken up.
In the process according to the invention, the crystallisation can be carried out by any suitable means capable of producing salt in the form of spheres by evaporation of a brine. According to the invention, it is advantageous that the salt spheres produced have a diameter which is greater than 3 mm. In practice, it is not desirable for the diameter of the spheres to exceed 15 mm. Diameters which are particularly suitable are those between 4 and 10 mm, and especially those of at least 5 mm.
A means which is particularly suitable for crystallising sodium chloride spheres is that described in Chem. Ing. Techn. 52 (1980) No. 11, pages 872 and 873. According to this means, the sodium chloride brine is first evaporated in a controlled manner to supersaturate it with sodium chloride , and it is then circulated through a fluid bed of sodium chloride particles.
The purpose of breaking up the spheres is to produce salt particles having the required particle size distribution. This may be carried out by any suitable means.
According to a preferred embodiment of the invention, the breaking up is controlled so that the particle size is at most 4 mm. As a general rule, it is not desirable for the salt produced by the breakingup to contain a considerable fraction of fine particles the size of which is below 0.25 mm. In practice, it is desirable that the fraction of particles below 0.25 mm in size does not exceed 2.5% by weight of the salt.
To avoid excessive formation of fine salt particles, it is advantageous, according to a particular embodiment of the invention, to break up the spheres in a moist state. In this embodiment of the invention, it is generally appropriate to employ a quantity of water which is at least 2 g, preferably 10 g, per kg of dry solids. It is not desirable for the quantity of water employed to exceed 75 g per kg of dry solids, quantities below 50 g being preferred. Quantities of water of between 5 and 20 g per kg of dry solids are generally suitable.
The temperature at which the breaking up is carried out is not critical. It can usually be carried out at the temperature at which the sodium chloride spheres are produced, for example between 50.degree. and 90.degree. C., in the case where the evaporation of the sodium chloride brine is carried out between 90.degree. and 110.degree. C.
The invention also relates to the salt obtained by means of a process according to the invention, as described above.
The salt according to the invention is in the form of particles of various sizes over a wide range of particle size distribution. It has a variety of uses, particularly in the processing of hides, in the food industry, for example, in the preparation of salt-preserves, and in the culinary industry.
Description of the Preferred Embodiments
According to a particular embodiment, the salt according to the invention is in the form of particles below 4 mm in size, having a particle size distribution defined by a mean diameter of between 1.00 and 2.50 mm and a standard deviation of between 0.50 and 1.50 mm, the mean diameter of d and the standard deviation .sigma. being defined by the following relationships (G. Herdan "Small particle staticstics" 2nd edition, 1960, Butterworths, pages 10 and 11): ##EQU1## where n.sub.i denotes the frequency (for example the weight) of particles of size d.sub.i. This type of salt is especially suitable for the food industry. In a preferred embodiment, the mean diameter is between 1.8 and 2.2 mm and the standard deviation is between 0.8 and 1.2 mm.
The salt according to the invention has physical properties which are substantially identical to those of pan salt. It has good pourability and excellent suitablility for salt-preserving methods. It has a translucent and glassy appearance similar to that of pan salt and its use for salting foodstuffs is at least as easy as that of pan salt.
To improve the pourability of the salt obtained by the process according to the invention still further and to facilitate its use still further, an anticaking substance generally employed in the production of foodgrade salt (Gmelins Handbuch der anorganischen Chemie, 8. Auflage, Natrium, Lief. 1, No. 21, 1964, p. 144 to 146) may be mixed therewith, in an alternative embodiment. A preferred anticaking substance is potassium ferrocyanide.
Detailed features of the invention will become apparent from the following description of an embodiment of the process according to the invention.
Sodium chloride spheres approximately 5 mm in diameter were crystallised by evaporation of a sodium chloride brine using the fluid bed method described in Chem.-Ing.-Techn. 52 (1980) No. 11, pages 872 and 873. A suspension of spheres in a saturated brine at approximately 100.degree. C. was drawn off from the bottom of the fluid bed. The suspension, which contained 500 g of spheres per kg. was filtered on a cloth in order that the spheres collected have a moisture content of approximately 9.7 g H.sub.2 O/kg.
One kg of moist spheres obtained in this way was ground by a pass between a pair of smooth rolls 200 mm in diameter, 200 mm in length, rotating at a speed of 374 revolutions per minute. Roll separation was fixed at 2.5 mm. The salt collected at the end of the grinding conformed to the invention and had the following cumulative particle size distribution:
This partical size distribution is characterised by a mean diameter of 1.93 mm and a standard deviation of 1 mm.
Claims
We claim:
1. Process for the production of salt, comprising: subjecting a sodium chloride brine to crystallization by evaporation under conditions which result in the formation of sodium chloride having the form of spheres; and breaking up the spheres to provide said salt, which salt has a translucent and glassy appearance, a particle shape of broken spheres, a non-uniform particle size, and a mean diameter ranging from 1.00 to 2.50 mm.
2. Process according to claim 1, wherein the spheres have a diameter which is greater than 3 mm.
3. Process according to claim 2, wherein the spheres have a diameter of at least 5 mm and the breaking up provides salt having a particle size of at most 4 mm.
4. Process according to claim 1, wherein the evaporation is carried out at a temperature of between 90.degree. and 100.degree. C. and the breaking up is carried out at a temperature of between 50.degree. and 90.degree. C.
5. Process according to claim 1, wherein the crystallisation of the sodium chloride brine is accomplished by subjecting same to evaporation to provide a supersaturated sodium chloride brine which is supersaturated with sodium chloride, and circulating the supersaturated sodium chloride brine through a fluid bed of sodium chloride particles.
6. Process according to claim 1, wherein the spheres are broken up while in a moist state.
7. Process according to claim 6, wherein the moisture content of the spheres subjected to the breakingup is controlled so that the spheres contain between 5 and 20 g of water per kg of dry solids.
8. The process according to claim 5, wherein the spheres are broken up while in a moist state.
9. The process according to claim 8, wherein the moisture content of the spheres subjected to the breaking up is controlled so that the spheres contain between 5 and 20 g of water per kg of dry solids.
Patent Citations (5)
| Patent | Date | Inventor | Cited By |
|---|---|---|---|
| US475577 | 1892-05-01 | Lawton et al. | |
| US2947603 | 1960-08-01 | Miller | |
| SUX688432 | 1979-09-01 | ||
| GBX1142046 | 1969-02-01 | ||
| GBX1163888 | 1969-09-01 |
Non-Patent Literature (11)
- Sodium Chloride, Kaufmann, Ed. Reinhold Publ. Corp. 1960, pp. 16, 206-207, 218.
- Grainer Salt, R. B. Richards, pp. 262-263.
- Bavarten von Kristallisatoren, Wohlk et al., Chem.-Ing.-Tech. 57 (1985) Nr. 4, pp. 318, 323-327.
- Chemical Engineers' Handbook, 5th Ed., Ed. by Perry & Chilton McGraw-Hill Book Co. 1973, pp. 8-8, 12.
- "Principles of Size Reduction" by John H. Perry in Chemical Engineers' Handbook, pp. 8-2-8-12.
- "La Valorisation Des Minerais" by Pierre Blazy in Manuel of Mineralurgie, 1970, p. 51.
- Svanoe, H., "Krystal" Classifying Crystallizer, Industrial and Engineering Chemistry, vol. 32, No. 5, May 1940, pp. 636-639.
- Messing et al., Theodor, "Industrielle Kristallisation-Moderne grosstechnische Anlagen und Fallstudien," Chem.-Ing.-Tech. 52 (1980) Nr. 11.S., pp. 872-873, (English Translation).
- Gmelins Handbuch der Anorganischen Chemie, 8th Edition, Natrium, Lief. 1, No. 21, 1964, Verlag Chemie GmbH Weinheim/Bergstr., pp. 144-146, (No ranslation).
- Herdan, G. et al., Small Particle Statistics, First Edition, 1953, Elsevier Publishing Company, pp. 10-15.
- Kaufmann, Dale W., Sodium Chloride, The Production and Properties of Salt and Brine, Reinhold Publishing Corporation, New York, 1960, pp. 205 and 262.