US 4,748,072 AGrant
Rigid Shaped Body Comprising a Plurality of Superposed and/or Adjacently Laminated and Commonly Pressed Oriented Thermoplastic Carriers and a Method for Producing the Same
Issue Date:1988-05-31
•9 Claims
Abstract
With a rigid shaped body of a plurality of oriented, i.e., stretched thermoplastic carriers in film, ribbon, monofil or fiber form, the plastic carriers are superposed and/or adjacently laminated and commonly pressed. In order to prevent a decrease in the favorable properties obtained by stretching of an individual plastic carrier during pressing, the stretched plastic carriers are coated with thermoplastic material on the sides getting into contact when superposed and/or adjacently laminated. The coating material has a crystallite melting temperature or a glass temperature lower than the plastic carriers. The thickness of two adjacent coating materials each is smaller than the thickness of a plastic carrier.
Metadata
Inventor
- Harald Schobermayr
Application Information
Application Number:US 8207127
Filing Date:1986-01-17
Priority Date:1985-01-25
Art Unit:158
Classifications
IPC:
B32B 702
Field of Search:
428212;213;516;910;461
Patent Drawings
This patent does not have any drawings.
Description
The invention relates to a rigid shaped body, such as a plate or a pipe, comprised of a plurality of superposed and/or adjacently laminated, commonly pressed, oriented, i.e., stretched thermoplastic carriers in film, ribbon, monofil or fiber form.
By orienting thermoplastics, it is possible to change their physical properties. In particular, partially crystalline materials will exhibit elevated yield stress, resistance to tearing, puncture resistance, low-temperature resistance and transparency as well as a reduced breaking elongation. Big-scale drawing processes are primarily employed, normal to the running direction, for the production of products having small geometric dimensions, such as, for instance, films, film ribbons, monofils and fibers.
For the production of shaped bodies having larger geometric dimensions, it is known (European patent application No. 0,031,157) to commonly press stretched partially crystalline thermoplastic films of equal material upon pressure and temperature exposure. In doing so, the pressing temperature must be raised close to the temperature of the crystallite melting end of the film in order to obtain a sufficient motility of the molecule chains of the plastic films, because it is only then that a sufficient bonding adhesion will be provided. Such a high pressing temperature involves a relaxation of the orientation of the film, thus reducing the favorable properties attained by the drawing process. By the known method, it is, therefore, not possible to produce shaped bodies of larger dimensions that exhibit similarly good properties as the stretched carrier films.
The invention aims at avoiding these disadvantages and difficulties and has as its object to provide a shaped body of the initially defined kind, with which pressing at elevated temperatures does not lead to a remarkable decrease in the favorable properties attained by stretching an individual plastic carrier so that the shaped body, despite its larger geometric dimensions substantially exceeding the dimensions of the individual plastic carrier, approximately exhibits the mechanical and technological properties of an individual stretched plastic carrier.
This object is achieved according to the invention in that the stretched plastic carriers, on the sides getting into contact when superposed and/or adjacently laminated, are coated with thermoplastic material, the coating material having a crystallite melting temperature or a glass temperature lower than the plastic carrier and the thickness of two adjacent coating materials each being smaller than the thickness of a plastic carrier.
The adhesion of the commonly pressed plastic carriers, according to the invention, is ensured by the coating material of the same: When superposing and/or adjacently laminating the coated plastic carriers, the coating materials of neighboring plastic carriers come to lie at each other. Since the crystallite melting temperature in the case of partially crystalline coating material, or the glass temperature of amorphous coating material, lies below the crystallite melting temperature of the stretched, partially crystalline plastic carriers to be connected, or below the glass temperature of amorphous plastic carriers, respectively, it will do to choose as the pressing temperature a temperature at which the coating material melts to such an extent that a sufficient bonding adhesion between the coating materials of neighboring plastic carriers is effected.
Since the pressing temperature can be kept to below the crystallite melting temperature or the glass temperature, respectively, of the plastic carriers, the advantageous properties of the stretched plastic carriers are changed by the pressing temperature only very slightly, if at all.
Since the coating material, due to heating to the crystallite melting temperature or the glass temperature, or therebeyond, reduces the favorable properties of the shaped body as compared to the favorable properties of an individual stretched plastic carrier, the volume portion of the coating material in the shaped body is to be as low as possible, the volume of the coating material preferably amounting to 20 percent at most of the volume of the shaped body.
A preferred embodiment is characterized in that the plastic carriers consist of polypropylene and the coating material consists of polyethylene, polypropylene or of a copolymer thereof.
According to a further preferred embodiment, the ultimate tensile strength and the modulus of elasticity of the pressed shaped body formed of equally oriented laminated plastic carriers amounts to at least 80 percent of the ultimate tensile strength and of the modulus of elasticity of a stretched plastic carrier, wherein, with a shaped body of bi-stretched plastic carriers, the ultimate tensile strength perpendicular to the running direction amounts to at least 170 N/mm.sup.2 according to DIN 53455, the modulus of elasticity perpendicular to the running direction is at least 3,800 N/mm.sup.2 according to DIN 53457 and the impact energy, measured at a 1.5 mm thick plate, is at least 60 J according to DIN 53453.
Another preferred embodiment is characterized in that the ultimate tensile strength and the modulus of elasticity of the shaped body formed by angularly laminated plastic carriers and pressed, amount to at least 40 percent of the maximum ultimate tensile strength and of the maximum modulus of elasticity, respectively, of a stretched plastic carrier, wherein, for a shaped body of bi-stretched plastic carriers, the ultimate tensile strength is at least 100 N/mm.sup.2 according to DIN 53455, the modulus of elasticity is at least 2,200 N/mm.sup.2 according to DIN 53457 and the impact energy, measured at a 1.5 mm thick plate, is at least 60 J according to DIN 53453.
Preferably, the shaped body has a minimum thickness of 3/10 mm, because from this thickness the good technological properties of the shaped body are particularly effective. This thickness results when using about at least ten plastic carriers of common thickness.
According to a preferred embodiment, at least one plastic carrier lying between the lowermost and the uppermost film-shaped plastic carriers is formed by a printed film-shaped plastic carrier or, preferably, a plastic carrier disposed between the lowermost and the uppermost film-shaped plastic carriers is replaced by a metal foil provided with an imprint, if desired. Thereby, labels and signboards or opaque shaped bodies may be produced in a simple manner, the opaque layer or the layer provided with an imprint lying well-protected within the shaped body.
According to a further preferred embodiment, the lowermost and/or uppermost plastic carrier is formed by a film of increased resistance to mechanical abrasion and/or to chemical attacks, the shaped body thus being usable, for instance, as panes or screens for vehicles.
A method for the production of a shaped body according to the invention, by connecting superposed and/or adjacently laminated stretched carriers of thermoplastics under thermal and pressure influence is characterized in that a plurality of plastic carriers coated with thermoplastic material on their mutual contact surfaces are commonly pressed at a temperature in the range of, or above, the crystallite melting temperature or the glass temperature of the coating material and below the crystallite melting temperature or the glass temperature of the stretched plastic carriers.
A sufficient adhesion between the pressed plastic carriers and the coating material suitably is obtained by using stretched plastic carriers to which the coating material has been applied by coextrusion.
According to another preferred embodiment, stretched plastic carriers to which the coating material has been applied with the help of adhesion mediators are used to obtain a sufficient adhesion between the plastic carriers and the coating material.
An advantageous embodiment of the method is characterized by using bi-stretched plastic carriers stretched by 1:3 to 1:6 in the running direction and by 1:8 to 1:12 perpendicular thereto and made of isotactic polypropylene, which have an ultimate tensile strength of about 200 N/mm.sup.2 perpendicular to the running direction and a modulus of elasticity of about 4,200 N/mm.sup.2 perpendicular to the running direction, after having been coated with a layer of copolymer polypropylene/polyethylene with a thickness of about 6 percent of the thickness of the plastic carrier in the extrusion process, wherein pressing suitably takes place at a pressure of at least 10 bar and at a temperature in the range of from 130.degree. C. to 150.degree. C., preferably at about 140.degree. C., for a period of at least 5 s, whereupon cooling under pressure to a temperature at which the coating material is substantially solidified, or therebelow, is effected.
Preferably, the shaped body is formed by winding a coated plastic carrier about a mandrel, and pressing takes place merely by heating the shaped body to a temperature above the crystallite melting temperature or the glass temperature of the coating material and to below the crystallite melting temperature or the glass temperature of the stretched plastic carrier.
With a method of this type, the winding body is formed by bi-stretched plastic carriers stretched by 1:3 to 1:6 in the running direction and by 1:8 to 1:12 perpendicular thereto and made of isotactic polypropylene, and is heated to a temperature in the range of from 130.degree. C. to 150.degree. C., preferably to a temperature of about 140.degree. C., and subsequently is cooled to room temperature.
The invention will now be explained in more detail by way of exemplary embodiments.
As the starting material for the production of a plate-shaped body having a plate thickness of 1.5 mm, a bi-stretched polypropylene film coated on both sides with an ethylene/propylene copolymer by the coextrusion method was chosen. The stretching ratio of the polypropylene film was 4 to 5 in the longitudinal direction and 8 to 12 perpendicular thereto. The thickness of the polypropylene film including the coatings on both sides amounted to 0.03 mm, the thickness of the coating on either side was 0.0015 mm.
50 of such polypropylene films were superposed to a stack, i.e., were stacked one above the other with the same orientation. This stack was pressed at a specific pressing power of 25 bar and at a pressing temperature of 140.degree. C. for a period of 10 s. Subsequently, cooling under pressure to about 60.degree. C. was effected. The shaped body pressed in this way had a thickness of 1.5 mm.
In the following Table 3, the characteristic data of an isotropic shaped body produced by pressing in the conventional manner, also of polypropylene, and having a thickness of 1.5 mm are indicated.
A comparison of the Tables shows that the modulus of elasticity, the ultimate tensile strength and the elongation at break, of the pressed shaped body are only slightly lower than the corresponding values of the stretched polypropylene film. There are remarkable differences as to the ultimate tensile strength, the elongation at break and the impact energy, between the pressed shaped body and the isotropic shaped body. For instance, the impact energy of the pressed shaped body is higher than the impact energy of the isotropic shaped body by the factor 40. Also are the luminous values of the pressed shaped body with regard to transparency considerably better than the luminous values of the isotropic shaped body.
In the following Table 4, the mechanical-technological values are indicated for a shaped body produced of the same starting material and substantially in the same manner as the previously described shaped body, yet composed of films laminated in cross bond. By cross bond, an angular bond is meant, in which the individual layers of the plastic carrier are torsionally stacked by 90.degree. each relative to the layer arranged therebelow, with respect to their orientation obtained by stretching.
The invention is not limited to the exemplary embodiments explained in detail, but may be modified in various aspects. Thus, it is possible to produce shaped bodies not only by pressing large-area foils, but also by winding film ribbons, fibers or monofils around mandrels. The thermal shrinkage of the stretched plastic carriers, which depends on the degree of stretching of the same, under certain conditions suffices to produce the pressing power necessary to bring about the bonding adhesion between the plastic carriers so that a separate pressure action from outside can be obviated. An example for this is the folowing
A film according to Table 1 was cut in the longitudinal direction into ribbons of 10 mm width and the ribbons were wound about a mandrel of 30 mm diameter. Subsequently, tempering took place at 140.degree. C. with a subsequent cooling to removal temperature (room temperature). To achieve bonding of the ribbons, no additional external pressure was required; the thermal shrinkage occurring during tempering in this case was enough to press the individual layers of the ribbons sufficiently firm at each other.
Furthermore, it is possible, by special arrangement of the individual layers of the plastic carriers, to effect an anisotropy aimed at offering dimensions of shaped parts in accordance with special demands.
A shaped body according to the invention need not be built up of identical plastic carriers, but it is possible to use plastic carriers of different materials and different dimensions (such as, e.g., thicknesses), thereby producing a shaped body that meets the demands set on it.
Furthermore, it is possible to substitute a metal foil or a plastic carrier with an imprint for a plastic carrier, thus obtaining a graphic design of the shaped body in a simple manner and preventing damage to the metal foil or the imprinted plastic carrier, because they are arranged within the shaped body. For the production of shaped bodies being of interest as panes or screens, for instance, the lowermost and/or the uppermost plastic carrier is formed by a film exhibiting an elevated scratch resistance, such as a polyester film. Also in this case, it is possible to provide films with an increased resistance to chemical attacks, the applicability of the shaped body according to the invention thus being even further increased.
Claims
What I claim is:
1. A rigid shaped body obtained by uniting highly biaxially oriented polypropylene carriers having ethylene/propylene copolymer coatings on their contacting surfaces under the influence of heat and pressure, which comprises: a plurality of zones of high molecular orientation comprising said propylene carriers, alternating with zones without molecular orientation comprising said ethylene/propylene copolymer coatings; said propylene carriers having a crystallite melting temperature on the order of about 160.degree. to 180.degree. C. and the ethylene/propylene copolymer coatings having a crystallite melting temperature on the order of about 110.degree. to 140.degree. C.; and, said zones without molecular orientation having a volume of up to 20 percent of the volume of the rigid shaped body, with the tensile strength and the modulus of elasticity of the rigid shaped body being less than 10 percent lower than that of a highly biaxially oriented polypropylene carrier and the impact energy of the rigid shaped body being at least 20 times as high as that of an isotropic material of the same thickness.
2. The rigid shaped body of claim 1, wherein one of said polypropylene carriers lying between a lowermost and an uppermost of said polypropylene carriers is replaced by a metal foil.
3. The rigid shaped body of claim 1, wherein the thermoplastic material of the carrires is biaxially oriented, and the shaped body has a tensile strength perpendicular to a running direction of at least 170 N/mm.sup.2 according to DIN 53455, a modulus of elasticity perpendicular to the running direction of at least 3800 N/mm.sup.2 according to DIN 53457, and an impact energy, measured at a 1.5 mm thick plate, of at least 60 J according to DIN 53453.
4. The rigid shaped body of claim 1, wherein the thermoplastic material of the carriers is biaxially oriented, and the shaped body has a tensile strength of at least 100 N/mm.sup.2 according to DIN 53455, a modulus of elasticity of at least 2200 N/mm.sup.2 according to DIN 53457, and an impact energy, measured at a 1.5 mm thick plate, of at least 60 J according to DIN 53453.
5. The rigid shaped body of claim 1, wherein the thermoplastic material of the carriers is equally oriented and the shaped body has a tensile strength and a modulus of elasticity amounting to at least 80% of that of each one of the carriers.
6. The rigid shaped body of claim 1, wherein the carriers extend at an angle to each other and said shaped body has a tensile strength amounting to at least 40% of that of each one of the carriers and a modulus of elasticity amounting to the maximum modulus of elasticity of each one of the carriers.
7. The rigid shaped body of claim 1, having a minimum thickness of 0.3 mm.
8. The rigid shaped body of claim 1, wherein said carriers are film-shaped and at least one of the film-shaped carriers between a lowermost and an uppermost film-shaped carrier carries printing.
9. The rigid shaped body of claim 1, comprising a lowermost and an uppermost film-shaped carrier, at least one of the film-shaped carriers being abrasion- and corrosion-resistant.