US 4,251,622 AGrant
Photo-Sensitive Composition for Dry Formation of Image
Issue Date:1981-02-17
•7 Claims
Abstract
A photo-sensitive composition for dry formation of image comprising a dyestuff having a photo-fading property, a ketonic sensitizing agent and a high molecular polymer as a binding agent, which can provide a visible image by the irradiation of light and maintain the image without any fixing treatment.
Metadata
Assignee
- Nippon Paint Co., Ltd.
Inventors
- Koichi Kimoto
- Yasusi Umeda
- Shin Saito
- Kunsei Tanabe
- Yasuyuki Takimoto
Application Information
Application Number:US 8828946
Filing Date:1978-03-01
Priority Date:1973-05-25
Art Unit:166
Classifications
IPC:
G03C 152
Field of Search:
9643089;90 R;48 QP332;339
Patent Drawings
This patent does not have any drawings.
Description
Practical and presently preferred embodiments of the invention are illustratively shown in the following Examples wherein parts and % are by weight.
Example 1
A 10% aqueous methanol solution (10 parts) of 50% saponified polyvinyl acetate resin ("Corponyl PK-40" manufactured by Nihon Sosen Kagaku Industry Co., Ltd.; number average polymerization degree, 1700) and benzophenone (0.5 part) are admixed and dissolved each other, and a 1% methanol solution (1.5 parts) of Solar Cyanine 6B (a triphenylmethane dye manufactured by Sumitomo Chemical Company, Limited; color index, 42660) is added thereto to make a uniform mixed solution. The thus obtained mixed solution is applied on an aluminum plate by the aid of a bar coater and dried at 45.degree..+-.5.degree. C. in a hot air drier for 2 minutes to obtain a photo-sensitive material (thickness of film, 20.mu.), which is subjected to the irradiation of light through Kodak Step Tablet No. 2 by the aid of a carbon arc lamp (30 A) from a distance of 40 cm for 3 seconds. The thus irradiated photosensitive material possesses as such the ability to show a continuous tone. The sensitivity amounts to 9 steps. When the continuous tone is stored without fixing for a week, any appreciable change is not observed.
The thus stored image is then subjected to the irradiation of light on the surface under the same condition as above whereby the original image disappears clearly, and the whole surface is completely faded.
When the image of the photo-sensitive material before the storage is subjected to the irradiation of light through the test chart No. 1 of the electrophotography society under the same condition as above, the reproduction is satisfactorily executed up to a resolving power of 16 lines/mm.
Example 2
The preparation of a photo-sensitive material is executed as in Example 1 using the 10% aqueous methanol solution (10 parts) of 50% saponified polyvinyl acetate resin, benzophenone (0.4 part), the 1% methanol solution (1.5 parts) of Solar Cyanine 6B and thiocyanamine (0.2 part). The thus prepared photo-sensitive material is subjected to the irradiation of light as in Example 1. The sensitivity and the resolving power are shown in Table 1.
Example 3
The preparation of a photo-sensitive material is executed as in Example 1 using the 10% aqueous methanol solution (10 parts) of 50% saponified polyvinyl acetate resin, benzophenone (0.2 part), a 1% methanol solution (2 parts) of Sunchromine Blue FBG (a triphenylmethane dye manufactured by Sumitomo Chemical Company, Limited; color index, 43855), o-anisaldehyde (0.2 part) and benzanilide (0.2 part). The thus prepared photo-sensitive material is subjected to the irradiation of light as in Example 1. The sensitivity and the resolving power are shown in Table 1.
Example 4
The preparation of a photo-sensitive material is executed as in Example 1 using the 10% aqueous methanol solution (10 parts) of 50% saponified polyvinyl acetate resin, acetophenone (0.4 part), a 1% methanol solution (2.2 parts) of Aizen Rose bengal B (a xanthene dyestuff manufactured by Aizen Corp.; color index, 45440) and a phenylacetaldehyde (0.2 part). The thus prepared photo-sensitive material is subjected to the irradiation of light as in Example 1. The sensitivity and the resolving power are shown in Table 1.
Example 5
The preparation of a photo-sensitive material is executed as in Example 1 using the 10% aqueous methanol solution (10 parts) of 50% saponified polyvinyl acetate resin, benzyl (0.2 part), butyroin (0.2 part), the 1% methanol solution of Aizen Rose bengal B (2.2 parts) as in Example 4 and N-n-propylbenzamide (0.2 part). The thus prepared photo-sensitive material is subjected to the irradiation of light as in Example 1. The sensitivity and the resolving power are shown in Table 1.
Example 6
The preparation of a photo-sensitive material is executed as in Example 1 using a 10% isopropanol-acetone (1:1) solution (10 parts) of nitrocellulose (nitration degree, L; viscosity, 1/2), benzophenone (0.4 part) and the 1% methanol solution of Solar Cyanine 6B (1.5 parts) as in Example 1. The thus prepared photo-sensitive material is subjected to the irradiation of light as in Example 1. The sensitivity and the resolving power are shown in Table 1.
Example 7
The preparation of a photo-sensitive material is executed as in Example 1 using a 10% aqueous methanol solution (10 parts) of 40% saponified ethylene-vinyl acetate copolymer (vinyl acetate, 80 mol %), 4-chlorobenzophenone (0.4 part) and the 1% methanol solution of Solar Cyanine 6B (1.5 parts) as in Example 1. The thus prepared photo-sensitive material is subjected to the irradiation of light as in Example 1. The sensitivity and the resolving power are shown in Table 1.
Example 8
The preparation of a photo-sensitive material is executed as in Example 1 using a 10% ethanol-acetone (1:1) solution (10 parts) of a copolymer mainly consisting of 2-hydroxypropyl methacrylate and n-butyl acrylate (molecular weight, 48000), benzophenone (0.2 part), benzoin ethyl ether (0.2 part) and the 1% methanol solution of Solar Cyanine 6B (1.5 parts) as in Example 1. The thus prepared photosensitive material is subjected to the irradiation of light as in Example 1. The sensitivity and the resolving power are shown in Table 1.
Example 9
The preparation of a photo-sensitive material is executed as in Example 1 using a 10% methanol-chloroform (7:3) solution (10 parts) of copolymerized nylon resin ("CM 8000" manufactured by Toyo Rayon Co., Ltd.; specific gravity, 1.12, melting point, 128.degree. C.), acetophenone (0.5 part) and the 1% methanol solution of Solar Cyanine 6B (1.3 parts) as in Example 1. The thus prepared photo-sensitive material is subjected to the irradiation of light as in Example 1. The sensitivity and the resolving power are shown in Table 1.
Example 10
The preparation of a photo-sensitive material is executed as in Example 1 using a 10% methanol-chloroform-water (7:2:1) solution (10 parts) of N-methoxymethylnylon 6 ("Type 8 nylon" manufactured by Unichika Co.,; N-methoxymethylation degree, 28-30%), benzophenone (0.3 part) and the 1% methanol solution of Solar Cyanine 6B (1.5 parts) as in Example 1. The thus prepared photo-sensitive material is subjected to the irradiation of light as in Example 1. The sensitivity and the resolving power are shown in Table 1.
Example 11
The preparation of a photo-sensitive material is executed as in Example 1 using a 10% ethanol-chloroform (8:2) solution (10 parts) of N-n-butylnylon 66 (number average molecular weight, 3200; N-n-butylation degree, 22-25%), benzophenone (0.3 part) and a 1% methanol solution (1.5 parts) of Acid Violet 5B (a triphenylmethane dyestuff manufactured by Sumitomo Chemical Company, Limited; color index, 42640). The thus prepared photo-sensitive material is subjected to the irradiation of light as in Example 1. The sensitivity and the resolving power are shown in Table 1.
Example 12
The preparation of a photo-sensitive material is executed as in Example 1 using a 10% ethanol-acetone (3:7) solution (10 parts) of copolymer mainly consisting of p-chloromethylstyrene and n-butyl acrylate (number average molecular weight, 35000), benzophenone (0.4 part) and the 1% methanol solution of Solar Cyanine 6B (1.5 parts) as in Example 1. The thus prepared photo-sensitive material is subjected to the irradiation of light as in Example 1. The sensitivity and the resolving power are shown in Table 1.
Example 13
The uniform mixed solution obtained as in Example 2 is applied on a sheet of paper coated with polystyrene to make a photo-sensitive material as in Example 1. The thus obtained material is subjected to the irradiation of light through Kodak Step Tablet No. 2 by the aid of a high pressure mercury lamp (3 KW) from a distance of 40 cm for 3 seconds. The sensitivity amounts to 9 steps. When the test for the resolving power is executed as in Example 1 under the same irradiation condition as above, the reproduction is satisfactorily performed up to 16 lines/mm.
Example 14
The uniform mixed solution obtained as in Example 1 is applied on a sheet of paper coated with polystyrene to make a photo-sensitive material as in Example 1. The thus obtained material is subjected to the irradiation of light through Kodak Step Tablet No. 2 by the aid of a xenone lamp (2 KW) from a distance of 30 cm for 5 seconds. The sensitivity amounts to 10 steps. When the test for the resolving power is executed as in Example 1 under the same irradiation condition as above, the reproduction is satisfactorily performed up to 16 lines/mm.
Example 15
The uniform mixed solution obtained as in Example 10 is applied on a sheet of paper coated with polystyrene to make a photo-sensitive material as in Example 1. The thus obtained material is subjected to the irradiation of light through Kodak Step Tablet No. 2 by the aid of a high pressure mercury lamp (3 KW) from a distance of 40 cm for 3 seconds. The sensitivity amounts to 10 steps. When the test for the resolving power is executed as in Example 1 under the same irradiation condition as above, the reproduction is satisfactorily performed up to 16 lines/mm.
Reference Example 1
The preparation of a photo-sensitive material is executed as in example 1 using a 20% methanol-acetone (1:4) solution (10 parts) of poly-n-butyl acrylate (molecular weight, 63000), benzophenone (0.2 part), the 1% methanol solution of Solar Cyanine 6B (1.5 parts) as in Example 1 and o-anisaldehyde (0.2 part). The thus prepared photo-sensitive material is subjected to the irradiation of light as in Example 1. The sensitivity and the resolving power are shown in Table 1.
Reference Example 2
The preparation of a photo-sensitive material is executed as in Example 1 using the 10% aqueous methanol solution (10 parts) of 50% saponified polyvinyl acetate resin as in Example 1, 5-nitroacetonaphthene (0.2 part) and the 1% methanol solution of Solar Cyanine 6B (1.5 parts) as in Example 1. The thus prepared photo-sensitive material is subjected to the irradiation of light as in Example 1. The sensitivity and the resolving power are shown in Table 1.
Reference Example 3
A sheet of commercially available diazo copying paper is subjected to the irradiation of light as in Example 1. The sensitivity and the resolving power are shown in Table 1.
Example 16
A 40% solution of partially saponified polyvinyl acetate (saponification degree, 30-50%; number average polymerization degree, 1700; viscosity, 30000 cps at 25.degree. C. on a 40% methanol solution) in aqueous methanol is diluted to make a 10% aqueous methanol solution. The thus prepared dilution (10 parts) and benzophenone (0.5 part) are admixed and dissolved each other, and a 1% methanol solution (4.0 parts) of C.I. acid blue 83 (color index, 42660) is added thereto to make a uniform solution. The obtained solution is applied on a triacetyl cellulose film (thickness, 80.mu.) by the aid of a bar coater (No. 36), and the film is dried in a hot air drier at 45.degree..+-.5.degree. C. for 2 minutes to make a material for blue-proof, which is subjected to the irradiation of light by a high pressure mercury lamp (3 KW) through Kodak Step Tablet No. 2 from a distance of 70 cm for 60 seconds whereby a clear blue image having 10 continuous steps of tone is obtained.
The above procedure is repeated but using C.I. acid yellow 29 (color index, 18900) in place of C.I. acid blue 83 whereby a yellow image having 8 continuous steps of tone is obtained.
Similarly, when C.I. acid red 32 (color index, 17065) is employed, a red image having 10 steps is obtained.
Further, similarly, the use of C.I. acid black 2 (color index, 15711) affords a black image having 6 steps.
Reference Example 4
Each of the materials for color-proof prepared in Example 16 is closely contacted with an original color decomposition plate for offset and subjected to the irradiation of light by a carbon arc lamp (2 KW) from a distance of 70 cm for 80 seconds. The reproduction of the original color decomposition plate is executed satisfactorily on every color. When the thus obtained color image sheets of each color are piled up each other with conjectural estimation, and the piled product is compared with the original plate under a transmission light source, they prove to be quite identical each other.
Reference Example 5
On the surface of the photosensitive layer of each material for color-proof prepared in Example 16, a transparent thin film of vinylidene chloride resin (thickness, 13.mu.) is piled, and the piled product is subjected to the irradiation of light in the absence of air for 30 seconds as in Example 16 whereby a color image corresponding to the one obtained in Example 16 is prepared. After the irradiation, the transparent thin film is removed off, and the material is allowed to stand in a room under the scattering light for 15 days. The color image is stable and not changed.
Reference Example 6
One of the color image sheets obtained in Reference Example 4 is closely contacted with a sheet of art paper previously applied an adhesive agent (an acryl resin). After pressed by the aid of a gum roller, the sheet is peeled off whereby the whole color image is transcribed on the art paper. On the thus transcribed color image, the adhesive agent is applied, and another color image sheet is closely contacted therewith. After pressed by the aid of a gum roller, the sheet is peeled off whereby the second color image is removed from the supporter to give a two-colored image. Similarly, the third and the fourth color images are transcribed to give a product consisting of the color images obtained from the original plates for color decomposition of yellow, cyan, magenta and black. The thus obtained product reproduces satisfactorily the original plate and corresponds to the color image obtained by the proof sheet.
Reference Example 7
As in Reference Example 6, the color image obtained in Example 16 are closely contacted with a white plastic sheet (polyethylene containing 10% of titanium oxide; thickness, 300.mu.) previously applied the adhesive agent and subjected to pressing by the aid of a gum roller and peeling off whereby the whole color images are well transcribed on the white plastic sheet.
Example 17
The preparation of materials for color-proof is executed in the same manner as in Example 16 but using, as the supporter, a polypropylene film (stretched at two axes; thickness, 60.mu.) in place of the triacetyl cellulose film, and from the thus prepared materials, color image sheets are obtained as in Reference Example 4. Each of the sheets is closely contacted with a sheet of white thick paper, heated in a hot air drier at 100.degree..+-.5.degree. C., pressed by the aid of a gum roller and, after cooling, peeled off whereby the whole color image is transcribed on the white plastic sheet.
Example 18
The preparation of materials for color-proof is executed in the same manner as in Example 16 but using, as the binding agent of high polymer, a 10% solution of N-methoxymethylnylon 6 (degree of N-methoxymethylation, 28 to 30%; viscosity, 500 to 800 cps at 20.degree. C. on a 20% methanol solution) in a mixture of methanol, chloroform and water (7:2:1) in place of the 10% aqueous methanol solution of partially saponified polyvinyl acetate. Each of the thus prepared materials is subjected to the irradiation of light for 40 seconds under the same condition as in Example 16. The formed color image corresponds to the one obtained in Example 16.
Example 19
The preparation of materials for color-proof is executed in the same manner as in Example 16 but using the 10% solution of N-methoxymethylnylon 6 in a mixture of methanol, chloroform and water (7:2:1) as in Example 18 (10 parts), benzophenone (0.4 part) and a 1% methanol solution (4.0 parts) of a dye as shown in Table 2. The thus prepared materials are subjected to the irradiation of light under the same condition as in Example 16. The results are shown in Table 2.
Example 20
A 10% solution (10 parts) of polyvinylbutyral resin (tripolymer of vinylbutyral, vinyl acetate and vinyl alcohol; degree of butyralation, 65.+-.2 mol %; number average polymerization degree, 1000 to 2000) in a mixture of methanol and acetone (7:3), benzophenone (0.5 part) and a 1% methanol solution (4.0 parts) of C.I. acid red 249 (color index, 18134) are admixed as in Example 16 to prepare a uniform solution. The thus obtained solution is applied on a polyester film (polyethylene terephthalate; thickness, 100.mu.) to prepare a material for red color-proof as in Example 16.
Example 21
A material for yellow color-proof is prepared as in Example 16 using a 10% methanol solution (10 parts) of hydroxypropylmethylcellulose phthalate (content of carboxybenzoyl group, 20 to 35%, content of hydroxypropyl group, 6 to 12%; content of methoxy group, 20 to 25%; viscosity, 250.+-.50 cps at 20.degree. C. on a 15% methylene chloride-methanol solution), benzophenone (0.5 part) and a 1% methanol solution (4.0 parts) of C.I. disperse yellow 3 (color index, 11855).
Example 22
A meterial for blue color-proof is prepared in the same manner as in Example 16 but using C.I. acid blue 9 (color index, 42090) in place of C.I. acid blue 83.
Reference Example 8
Each of the material for black color-proof obtained in Example 16 and the materials for color-proof prepared in Examples 20, 21 and 22 is closely contacted with an original color decomposition plate for offset and subjected to the irradiation of light by the aid of a carbon arc lamp (2 KW) from a distanece of 70 cm for 80 seconds whereby the reproduction of the original color decomposition plate is executed satisfactorily. When the thus obtained color image sheets are subjected to the pile printing as in Example 20, there can be formed a color image almost identical to the one obtained by a proof sheet.
Example 23
The preparation of materials for color-proof is executed in the same manner as in Example 16 but using, as the binding agent of high polymer, a 10% solution of vinyl chloride-vinyl acetate-maleic acid copolymer (proportion of the monomers, vinyl chloride:vinyl acetate:maleic acid=86:13:1 (% by weight); number average polymerization degree, 400) in a mixture of acetone and methanol (7:3) in place of the 10% aqueous methanol solution of partially saponified polyvinyl acetate. Each of the thus prepared materials is subjected to the irradiation of light through Kodak Step Tablet No. 2 by the aid of a high pressure mercury lamp (3 KW) from a distance of 70 cm for 50 seconds whereby a good color image can be obtained.
Example 24
A material for yellow color-proof is prepared in the same manner as in Example 16 but using C.I. acid yellow of acryl resin (copolymer mainly containing methacryl moiety; viscosity, 600 to 800 cps at 25.degree. C. on a 40% toluene solution) in a mixture of toluene and methanol in place of the 10% aqueous methanol solution of partially saponified polyvinyl acetate.
Example 25
A material for blue color proof is prepared as in Example 24 but using C.I. acid blue 9 (color index, 42090) and a 10% methanol solution of diethylaminoethyl methacrylate-methyl methacrylate copolymer as the binding agent of high polymer.
Reference Example 9
Each of the material for black color-proof obtained in Example 16 and the materials for color-proof prepared in Examples 20, 24 and 25 is closely contacted with an original color decomposition plate for offset and subjected to the irradiation of light by the aid of a high pressure mercury lamp (3 KW) from a distance of 70 cm for 90 seconds whereby the reproduction of the original color decomposition plate is executed satisfactorily. When the thus prepared color image sheets are subjected to the pile-printing as in Reference Example 6, there can be obtained a color image almost identical to the one obtained by a proof sheet.
Example 26
A material for yellow color-proof is prepared as in Example 16 but using C.I. disperse yellow 3 and, as the binding agent of high polymer, a 10% solution of butylated urea resin (acid value, 3.0; Gardner viscosity, N-0.2) in a mixture of methanol and butanol (4:6) in place of the 10% aqueous methanol solution of partially saponified polyvinyl acetate.
Example 27
A material for the blue color-proof is prepared as in Example 26 but using C.I. acid blue 9 and, as the binding agent of high polymer, a 10% methanol solution of polyvinyl acetate (number average polymerization degree, 1000; viscosity, 16000 cps at 25.degree. C. on a 50% methanol solution).
Example 28
A material for red color-proof is prepared as in Example 26 but using C.I. acid red 249 (color index, 18134) and, as the binding agent of high polymer, a 10% methanol solution of vinylacetal butyral copolymer (acetal group, 37-41% by weight; butyral group, 37-41% by weight; hydroxyl group, 17-23% by weight).
Reference Example 10
Each of the material for black color-proof obtained in Example 16 and the materials for color-proof prepared in Examples 26, 27 and 28 is closely contacted with an original color decomposition plate for offset and subjected to the irradiation of light by the aid of a high pressure mercury lamp (3 KW) from a distance of 70 cm for 90 seconds whereby the reproduction of the original color decomposition plate is executed satisfactorily. When the thus prepared color image sheets are subjected to the pile-printing as in Reference Example 6, there can be obtained a color image almost identical to the one obtained by a proof sheet.
Example 29
The preparation of materials for yellow color-proof is executed as in Example 16 using a 10% dilute solution (10 parts) of a binding agent of high polymer as shown in Table 2, benzophenone (0.5 part) and a 1% methanol solution (4.0 parts) of C.I. disperse yellow 3. The thus prepared materials are subjected to the irradiation of light as in Example 16. The results are shown in Table 3.
Example 30
The preparation of materials for red color-proof is executed as in Example 16 using the 10% aqueous methanol solution (10 parts) of partially saponified polyvinyl acetate as in Example 16, a photo-sensitizing agent as shown in Table 4 (0.5 part) and a 10% methanol solution of C.I. acid red 32 (4.0 parts). The thus prepared materials are subjected to the irradiation of light as in Example 16. The results are shown in Table 4.
As understood from the above embodiments, specific examples of the presently preferred combinations of the dyestuff, the sensitizer and the binder include: a triphenylmethane dyestuff, benzophenone and a partially saponified vinyl acetate polymer; a xanthene dyestuff, acetophenone and a partially saponified vinyl acetate polymer; a triphenylmethane dyestuff, 4-chlorobenzophenone and a partially saponified vinyl acetate polymer; a triphenylmethane dyestuff, acetophenone and an N-substituted polyamide resin; a triphenylmethane dyestuff, benzophenone and an N-substituted polyamide resin, etc.
Claims
What is claimed is:
1. A photo-sensitive composition used for the dry formation of an image without requiring any fixing operation consisting essentially of a dyestuff having photofading properties selected from the group consisting of an azo dyestuff, a triphenylmethane dyestuff, a xanthene dyestuff, and an oxazine dyestuff; an aryl ketone sensitizing agent selected from the group consisting of benzophenone, 4-methylbenzophenone, 4-chlorobenzophenone, 4-ethylbenzophenone, 4,4'-dimethoxybenzophenone, acetophenone, 4-methylacetophenone, propiophenone, benzalacetophenone and .omega.-bromoacetophenone; and a high molecular polymer binding agent selected from the group consisting of an N-substituted polyamide resin and a vinyl acetate polymer or its partially saponified product, wherein the proportions of the dyestuff, the ketonic sensitizing agent and the high molecular polymer are 0.05 to 20:0.2 to 200:100 parts by weight.
2. A material for the dry formation of an image prepared by incorporating the photo-sensitive composition according to claim 1 into a plastic material and molding the resulting product.
3. A material for the dry formation of an image prepared by applying the photo-sensitive composition according to claim 1 on a supporter to form a layer of the photo-sensitive composition.
4. A material for color-proof prepared by applying a solution of the photo-sensitive composition according to claim 1 in an appropriate solvent on a supporter to form a layer of the photo-sensitive composition.
5. The photo-sensitizing composition according to claim 1, wherein the proportions of the dyestuff, the ketonic sensitizing agent and the high molecular polymer are 0.2 to 5:1 to 100:100 parts by weight.
6. A method for production of an image which comprises applying a light to a material for dry formation of an image through an original picture corresponding to the image, the said material being one prepared by incorporating a photo-sensitive composition comprising a dyestuff having photo-fading properties selected from the group consisting of an azo dyestuff, a triphenylmethane dyestuff, a xanthene dyestuff and an axazine dyestuff; an aryl ketone sensitizing agent selected from the group consisting of benzophenone, 4-methylbenzophenone, 4-chlorobenzophenone, 4-ethylbenzophenone, 4,4'-dimethoxybenzophenone, acetophenone, 4-methylacetophenone, propiophenone, benzalacetophenone and .omega.-bromoacetophenone; and a high molecular polymer binding agent selected from the group consisting of an N-substituted polyamide resin and a vinyl acetate polymer or its partially saponified product into a plastic material and molding the resulting product, wherein the proportions of the dyestuff, the ketonic sensitizing agent and the high molecular polymer are 0.05 to 20:0.2 to 200:100 parts by weight.
7. A method for production of an image which comprises applying a light to a material for dry formation of an image through an original picture corresponding to the image, the said material being one prepared by applying a photo-sensitive composition comprising a dyestuff having photo-fading properties selected from the group consisting of an azo dyestuff, a triphenylmethane dyestuff, a xanthene dyestuff, and an oxazine dyestuff; an aryl ketone sensitizing agent selected from the group consisting of benzophenone, 4-methylbenzophenone, 4-chlorobenzophenone, 4-ethylbenzophenone, 4,4'-dimethoxybenzophenone, acetophenone, 4-methylacetophenone, propiophenone, benzalacetophenone and .omega.-bromoacetophenone; and a high molecular polymer binding agent selected from the group consisting of an N-substituted polyamide resin and a vinyl acetate polymer or its partially saponified product, or its solution in an appropriate solvent on a supporter to form a layer of the photo-sensitive composition, wherein the proportions of the dyestuff, the ketonic sensitizing agent and the high molecular polymer are 0.05 to 20:0.2 to 200:100 parts by weight.
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