US 4,231,741 AGrant
Mixtures of Optical Brighteners
Issue Date:1980-11-04
•5 Claims
Abstract
Mixture of optical brighteners consisting of from 0.5 to 0.95 part by weight of a brightener of the series of the benzoxazolyl-stilbenes and of from 0.95 to 0.05 part by weight of a brightener of the series of the aryltriazoles.
Metadata
Assignee
- Hoechst Aktiengesellschaft
Inventors
- Dieter Gunther
- Rudiger Erckel
- Gunter Rosch
- Heinz Probst
Application Information
Application Number:US 9717358
Filing Date:1978-12-21
Priority Date:1977-12-31
Art Unit:142
Classifications
IPC:
D06P 1642
Field of Search:
82521 W301.23
Patent Drawings
This patent does not have any drawings.
Description
U.S. Pat. No. 4,169,810 relates to mixtures of optical brighteners consisting of from 0.05 to 0.95 part by weight of a compound of the formula I ##STR1## and of from 0.95 to 0.05 part by weight of a compound of the formulae II or III ##STR2## in which the symbols X, R.sup.1, R.sup.2, A and B are defined as follows:
X is oxygen or sulfur, R.sup.1 and R.sup.2, which may be identical or different, are radicals selected from the group consisting of hydrogen, fluorine or chlorine atoms; phenyl, C.sub.1-9 alkyl, C.sub.1-4 alkoxy, C.sub.1-4 dialkylamino, acylamino groups or optionally functionally modified carboxy or sulfo groups, or two vicinal radicals R.sup.1 and R.sup.2, when taken together, stand for a fused benzo ring, for lower alkylene or 1,3-dioxapropylene; A is cyano, a group of the formula --COOR.sup.3 or CONR.sub.2.sup.3 with R.sup.3 being hydrogen, C.sub.1-18 alkyl, cycloalkyl, aryl, alkylaryl, halogenaryl, aralkyl, alkoxyalkyl, halogenalkyl, hydroxyalkyl, alkylaminoalkyl, carboxyalkyl or carboalkoxyalkyl, or two alkyl or alkylene radicals standing for R.sup.3, when taken together with the nitrogen atom, being morpholino, piperidino or piperazino ring; or A is a group of the formula ##STR3## in which R.sup.4 is straight chain or branched alkyl having from 1 to 18 carbon atoms, preferably 1 to 6 carbon atoms, which may be substituted by hydroxy, halogen, lower alkoxy, dialkylamino, lower alkylmercapto, chloroaryloxy, aryloxy, arylmercapto or aryl radicals both alkyl groups contained in the dialkylaminoalkyl groups, when taken together, standing optionally for a morpholino, piperidino or piperazino ring; or R.sup.4 is a group of the formula --(CH.sub.2 CH.sub.2 O).sub.n --R with n being 1, 2 or 3 and R being hydrogen; lower alkyl, dialkylaminoalkoxyalkyl or alkylthioalkoxyalkyl, the alkyl groups in dialkylaminoalkoxyalkyl, when taken together, forming optionally a piperidino, pyrrolidino, hexamethylenimino, morpholino or piperazino ring; or R.sup.4 is a group of the formula --(CH.sub.2).sub.m --CH.dbd.CH--R with m being an integer of from 0 to 5, or R.sup.4 is a radical of the formula ##STR4## wherein R.sup.5 and R.sup.6, which may be the same or different, are radicals selected from the group consisting of hydrogen, fluorine or chlorine atoms, phenyl, lower alkyl, lower alkoxy, C.sub.1-4 acylamino groups or optionally modified carboxy or sulfo groups, two vicinal radicals R.sup.5 and R.sup.6, when taken together, standing optionally for lower alkylene, a fused benzo ring or 1,3-dioxapropylene and B is a group of the formula ##STR5## wherein R.sup.7 and R.sup.8 independant from each other are hydrogen, fluorine, chlorine or C.sub.1-4 alkyl.
By further modifying this invention it has now been found that mixtures of optical brighteners which are equal in quality to the above described are obtained when the brighteners of the formula I are mixed with the brighteners of the formula IV ##STR6##
The present invention, consequently, relates to mixtures of optical brighteners consisting of from 0.05 to 0.95 part by weight of a compound of the formula I as defined above and of from 0.95 to 0.05 part by weight of a compound of the formula IV, ##STR7## wherein B is a polycyclic aromatic radical having at least three condensed rings optionally carrying non chromophoric substituents; C is amino, substituted by one or two alkyl, hydroxyalkyl, acyl or phenyl groups, the phenyl group containing optionally one or several non chromophoric radicals and two alkyl groups, when taken together with the nitrogen atom of the amino group forming optionally a pyrrolidino or piperidino ring or, when taken together with a further nitrogen or oxygen atom, a piperazino or morpholino ring; or C is alkoxy, hydroxyalkyl, acyloxy, alkylthio or carbalkylmercapto; D independant from C is defined as C and may further stand for a chlorine atom.
Suitable polycyclic aromatic radicals are pyrene, anthracene, acenaphthene and chrysene radicals, preferably pyrene. Examples of alkyl, alkoxy or acyl groups are those which have of from 1 to 4 carbon atoms. As non chromophoric radicals there may be mentioned halogen, alkyl, alkoxy, mono- and di-alkylamino, acylamino, cyano, sulfo, sulfoacid alkyl esters, carboxy, carboalkoxy, sulfonamido, carbonamido and the mono- and di-alkylamides derived therefrom, each alkyl, acyl or alkoxy group having 1-4 C-atoms.
Especially preferred are those compounds of the formula IV in which B is pyrene and C and D independant from each other are C.sub.1-4 alkoxy.
The symbols R.sup.1, R.sup.2, X and A in the formula I are defined as above.
Compounds of the formula I, wherein X, A, R.sup.1 and R.sup.2 are defined as above and R.sup.4 stands for a member of the following group: C.sub.1-6 alkyl, C.sub.1-6 -chloroalkyl, dimethyl- or diethylamino-C.sub.1-4 alkyl, morpholinoethyl, N-.beta.-piperidinoethyl, N-.beta.-(N'-methylpiperazino)-ethyl, benzyl, phenoxy-C.sub.1-4 alkyl, chlorphenoxy-C.sub.1-4 alkyl, C.sub.1-4 alkylmercapto-C.sub.1-4 -alkyl, phenylmercapto-C.sub.1-4 alkyl, phenyl, C.sub.1-6 alkylphenyl, di-C.sub.1-6 -alkylphenyl, chlorphenyl, dichlorophenyl, C.sub.1-6 alkoxyphenyl or .beta.-naphthyl or a group of the formula --(CH.sub.2 CH.sub.2 O).sub.n --R with n being 1, 2 or 3 and R being hydrogen, C.sub.1-7 alkyl, C.sub.1-4 alkylmercapto-C.sub.1-4 alkyl, dimethyl- or diethylamino-C.sub.1-4 alkyl or morpholino-C.sub.1-4 alkyl, are particularly interesting.
Especially preferred are those compounds of the formula I wherein X is O or S, R.sup.1 and R.sup.2 in 6 or 7 position each are hydrogen or chlorine atoms, C.sub.1-4 alkyl, phenyl or, when taken together, a fused benzo ring and R.sup.4 in the group A is C.sub.1-6 alkyl, C.sub.1-6 chloroalkyl, C.sub.1-4 alkoxy-C.sub.1-4 -alkyl, hydroxy-C.sub.1-4 alkyl or a group of the formula --(CH.sub.2 CH.sub.2 O).sub.n --R' with n being 2 or 3 and R' being hydrogen or C.sub.1-4 alkyl.
Particularly interesting as a subgroup are further those compounds of the formula I wherein X is oxygen, R.sup.1 in 5 position is hydrogen or chlorine, methyl or phenyl, R.sup.2 is hydrogen or R.sup.1 and R.sup.2 each are a methyl group in 5,6 or 5,7 position and R.sup.4 in the group A is methyl, ethyl, n- or iso-propyl, n- or isobutyl, pentyl, chloromethyl, .beta.-chloroethyl, .beta.-hydroxyethyl, .beta.-methoxyethyl, .beta.-ethoxyethyl, benzyl, phenyl, o-tolyl, 2,3-dimethylphenyl, o-chlorphenyl-p-chlorophenyl, 2,4-dichlorophenyl or p-methoxyphenyl.
By the term "functionally modified carboxy group" there are to be understood carboxylic acid derivatives in the largest sense, i.e. compounds having one carbon atom, three bonds of which are occupied by hetero atoms, in particular oxygen, nitrogen and sulfur. In a narrow sense these compounds include salts with colorless kations, among which alkali metal or ammonium ions are preferred, and further the cyano group, a carboxylic acid ester group or a carbonamide group. Carboxylic acid ester groups include in particular those of the formula COOQ.sup.1 wherein Q.sup.1 is a phenyl radical or optionally branched C.sub.1-4 alkyl. Carbonamide groups include in particular those of the formula CONQ.sup.2 Q.sup.3 wherein Q.sup.2 and Q.sup.3 each are hydrogen atoms or C.sub.1-4, optionally substituted alkyl groups, which may form a hydroaromatic ring, when taken together with the nitrogen atom.
By the term "funtionally modified sulfo groups" there are to be understood, in analogy to the above statements, radicals with a sulfo group linked to a hetero atom, i.e. salts with colorless kations, preferably alkali metal or ammonium ions, the sulfonic acid ester groups and the sulfonamide group. Sulfonic acid ester groups include in particular a group of the formula SO.sub.2 OQ.sup.1 wherein Q.sup.1 is defined as above and sulfonamide groups include those of the formula SO.sub.2 NQ.sup.2 Q.sup.3 wherein Q.sup.2 and Q.sup.3 are defined as above.
Suitable acyl groups include in particular those of the formula COQ.sup.4 wherein Q.sup.4 is optionally substituted, preferably lower, alkyl or phenyl, in particular unsubstituted C.sub.1-4 alkanoyl or benzoyl. Preferred substituents for R.sup.3 are C.sub.1-4 alkyl, halogenalkyl or alkoxy.
In addition to the above subgroups any other subgroups may be formed from the definitions for X, R.sup.1, R.sup.2, A, B, C and D. It is quite natural that it is not intended to introduce new matter according to 35 U.S.C. 132 by the formation of such new sub-groups.
Unless stated otherwise, alkyl groups and other groups derived therefrom, each have of from 1 to 4 carbon atoms.
The following radicals may stand for R.sup.1 and R.sup.2 : methyl, ethyl, n- or isopropyl, n- or iso-butyl, pentyl, hexyl, methoxy, ethoxy, propoxy, butoxy, pentoxy, hexoxy, dimethylamino, diethylamino, trimethylammonium, triethylammonium, acetylamino, cyano, --SO.sub.3 H, carboxyl, carbomethoxy, -ethoxy-, -propoxy, -butoxy and the corresponding groups of the class of sulfonic acid alkyl esters, methyl-, ethyl-, propyl-, butyl-carbonamide, and the corresponding groups of the class of alkylsulfonamides and the corresponding dialkylcarbonamide groups or -sulfonamide groups. Two vicinal groups R.sup.1 and R.sup.2 may form thogether a fused benzo or cyclohexyl ring. Those compounds are preferred that contain the benzoxazolyl group (X=O).
R.sup.4 may stand for the following groups: methyl, ethyl, n- or isopropyl, n- or iso-butyl, pentyl, hexyl or the chloroalkyl, hydroxyalkyl, dimethylaminoalkyl, diethylaminoalkyl, methoxyalkyl, ethoxyalkyl, propoxyalkyl, butoxyalkyl, methylenmercaptoalkyl, ethylmercaptoalkyl, chlorophenoxyalkyl, phenoxyalkyl, phenylmercaptoalkyl, phenylalkyl and naphthylalkyl groups which derive therefrom; R.sup.4 may further stand for groups of the formula (CH.sub.2 CH.sub.2 O).sub.n R with n being 1, 2 or 3 and R being hydrogen, methyl, ethyl, propyl or butyl, dimethyl- or diethylaminoalkoxyalkyl having from 1 to 4 carbon atoms in the alkyl or alkoxy moiety or those alkylthioalkoxyalkyl groups which have likewise of from 1 to 4 carbon atoms in the alkyl or alkoxy moieties. Examples of these radicals are those of the formulae
--CH.sub.2 CH.sub.2 OCH.sub.3, --CH.sub.2 CH.sub.2 OC.sub.2 H.sub.5, --CH.sub.2 CH.sub.2 OC.sub.3 H.sub.7, --CH.sub.2 CH.sub.2 OC.sub.4 H.sub.9,
--CH.sub.2 CH.sub.2 OC.sub.6 H.sub.13, ##STR8## --CH.sub.2 CH.sub.2 OC.sub.6 H.sub.11, --(CH.sub.2 CH.sub.2 O).sub.2 CH.sub.3, --(CH.sub.2 CH.sub.2 O).sub.2 C.sub.2 H.sub.5, --(CH.sub.2 CH.sub.2 O).sub.2 C.sub.4 H.sub.9,
--(CH.sub.2 CH.sub.2 O).sub.3 C.sub.2 H.sub.5, --CH.sub.2 CH.sub.2 OCH.sub.2 CH.sub.2 SC.sub.2 H.sub.5, --CH.sub.2 CH.sub.2 OCH.sub.2 CH.sub.2 --N(CH.sub.2).sub.2,
--CH.sub.2 CH.sub.2 OCH.sub.2 CH.sub.2 --N(C.sub.2 H.sub.5).sub.2 ##STR9##
Alternatively R.sup.4 may be unsubstituted phenyl or phenyl substituted once or twice, in which case the alkyl, alkoxy, acyl, carboalkoxy, alkylcarbonamido, alkylsulfonamido and sulfonic acid alkyl ester groups may have of from 1 to 4 carbon atoms. Two substituents R.sup.5 and R.sup.6 may also form together a fused benzo ring.
The compounds of the formula I wherein A is an oxadiazole ring, may be prepared according to U.S. Pat. No. 4,142,044 by reacting a compound of the formula V ##STR10## with a compound of the formula VI
wherein R.sup.1, R.sup.2, X and R.sup.4 are defined as above and Y is a group of the formula VII ##STR11## and Z is simultaneously a group of the formula VIII
or Y is a group of the formula VII and Z is simultaneously a group of the formula VII.
In the first case there are obtained compounds of the formula I which contain a 1,2,4-oxadiazolyl-3 group and in the second case the compounds obtained contain the 1,2,4-oxadiazolyl-5 group. The reaction occurs preferably in the presence of an acid binding agent in an inert solvent, at a temperature of from 20.degree. to 200.degree. C.
The starting compounds of the formula VI wherein Z is a group of the formula VII, may be prepared according to the process disclosed in Chem. Rev. 62 (1962), pages 155 et seq. The starting compounds of the formula V wherein Y is a group of the formula VII may likewise be prepared in analogous manner according to this process.
The compounds of the formula IV are known from German Auslegeschrift No. 1,273,479 and may be prepared according to the process disclosed in this publication.
The reaction products obtained in the aforesaid processes may be subjected to further known conversions, for example those in which sulfo- or carboxy groups are funtionally modified or those in which sulfo- or carboxy groups are converted to provide other groups of this type or the free acids. Furthermore chloromethyl groups may be incorporated in known manner or methyl groups may be oxidized. In addition, the incorporated halogen atoms may be halogenated or subjected to further reactions, for example chlorine or bromine may be exchanged for the amine function.
The mixing ratio of the individual components ranges between 0.05 and 0.95 part by weight of the compound I and the corresponding quantity (0.95 to 0.05 part by weight) of the mixture of the compound IV. The optimum mixing ratio depends in each case of the nature of the individual compounds of the formulae I and IV and may be readily determined by preliminary tests.
As is customary for optical brighteners, the individual components are brought into a commercial form by dispersion in a solvent, for example by dispersing them separately and by combining the dispersions. Alternatively the individual components can be mixed in substance and be dispersed together. Dispersing is effected in usual manner in ball mills, colloid mills, bead mills, or dispersion kneaders. The mixtures according to the invention are especially useful for brightening linear polyesters, polyamides and acetyl cellulose. However, they can likewise be used with the same good result in blended fabrics consisting of linear polyesters and other synthetic or natural fibers, especially hydroxyl groups-containing fibers, in particular cotton. These mixtures are applied onto the fibers under conditions that are customary for the application of optical brighteners, for example according to the exhaust process, at a temperature of from 90.degree. to 130.degree. C. with or without the addition of accelerators (carriers) or according to the thermosol process.
Brighteners that are unsoluble in water and the mixtures according to the invention can alternatively be dissolved in organic solvents such as perchloroethylene prior to being used. In this operation the textile material may be treated with the solvent liquor that contains the optical brightener in a dissolved state according to the exhaust process. Another way consists in impregnating, padding or spraying the textile material with the solvent liquor that contains the brighteners and then drying the textile material at a temperature of from 120.degree. to 220.degree. C. to fix all optical brightener in the fiber.
An advantage of the use of the mixtures as described above resides in the fact that an unexpected synergistic effect as regards the degree of whiteness is achieved, i.e. a mixture of compounds of the formulae I and IV gives a higher degree of whiteness than an identical quantity of only one of the compounds of the formulae I or IV. The same applies to the brillance of the brightening effect obtained. In addition, the textile material brightened with the mixtures according to the invention exhibits a violet-bluish shade, which is generally more pleasant to the human eye than reddish shades, by way of example, that are obtained when the compounds of the formula I are used alone or than greenish shades achieved with compounds of the formula IV alone.
The following examples illustrate the invention. Parts and percentages are by weight unless otherwise stated. The degrees of whiteness have been measured according to the formulae of Stensby (Soap and Chemicals Specialities, April 1967, pages 41 et seq.) and Berger (Die Farbe, 8 (2959), pages 187 et seq.). The temperature is indicated in degrees Celsius.
Example 1
Tissue sections consisting of polyester staple fibers were washed and dried in usual manner before being impregnated on a padding mangle with aqueous dispersions containing 0.5 g/l of a mixture of the optical brighteners of the formula I ##STR12## and of the formula II ##STR13## in the mixing ratio indicated below. The material was squeezed with a padding mangle between rollers to an 80% liquor take-up which corresponds to a take-up of optical brightener on the material of 0.04%. The padded material was then dried on a tenter frame for 30 seconds at 120.degree. C. and thermosoled for a further 30 seconds at 190.degree. C. to provide the degree of whiteness listed hereinafter. It is evident that the mixtures gave higher degrees of whiteness than the individual components.
Example 2
Polyester curtains having a raschelle tulle binding were washed in usual manner in a continuous washing machine, then dried on a tender frame at 120.degree. C. and impregnated on a padding mangle with aqueous dispersions containing 0.5 g/l of mixtures of optical brighteners of the formulae I and II with the mixing ratios shown below. The material was then squeezed between rollers to yield a liquor absorption of 80%, which corresponds to a take-up of optical brightener on the material of 0.04%. The padded material was dried on a tenter frame for 20 seconds at 120.degree. C. and thermofixed for a further 20 seconds at 190.degree. C. To obtain an optimum degree of whiteness for the intended application, the material was subjected to bleaching using 2 g/l of sodium chlorite, 50%, 1 g/l of ammonium sulfate, 1 ml/l of hydrogen peroxide, 35 weight %. The pH of the liquor was adjusted at 3.5 with formic acid. Bleaching was carried out for 60 minutes, at 95.degree. C. with a goods-to-liquor ratio of 1:20.
The following degrees of whiteness were obtained after rinsing and drying at 120.degree. C. for 30 seconds. It becomes evident that the degrees of whiteness obtained with mixtures are distinctly higher than that obtained with the individual components.
Claims
What is claimed is:
1. Mixtures of optical brighteners consisting of from 0.05 to 0.95 part by weight of a compound of the formula I ##STR29## and of from 0.95 to 0.05 part by weight of a compound of the formula IV ##STR30## in which the symbols X, R.sup.1, R.sup.2, A and B are defined as follows: X is oxygen or sulfur, R.sup.1 and R.sup.2, which may be identical or different, are hydrogen, fluorine, chlorine, phenyl, C.sub.1-9 alkyl, C.sub.1-4 alkoxy, C.sub.1-4 dialkylamino, acylamino, carboxy, cyano, carbonamido, mono- or di-alkylcarbonamido, carboalkoxy, sulfo, sulfonamido, mono- or di-alkyl-sulfonamido, alkyloxysulfonyl, two vicinal radicals R.sup.1 and R.sup.2, when taken together, are a fused benzo ring, lower alkylene or 1, 3-dioxapropylene; A is cyano, a group of the formula --COOR.sup.3, CONR.sub.2.sup.3 with R.sup.3 being hydrogen, C.sub.1-18 alkyl, cycloalkyl, aryl, alkylaryl, halogenaryl, aralkyl, alkoxyalkyl, halogenalkyl, hydroxyalkyl, alkylaminoalkyl, carboxyalkyl, carboalkoxyalkyl, two alkyl or alkylene, when taken together with the nitrogen atom, being a morpholino, piperidino or piperazino ring; or A is a group of the formula ##STR31## in which R.sup.4 is straight chain or branched alkyl having from 1 to 18 carbon atoms, preferably 1 to 6 carbon atoms, which may be substituted by hydroxy, halogen, lower alkoxy, dialkylamino, lower alkylmercapto, chloroaryloxy, aryloxy, arylmercapto or aryl radicals both alkyl groups contained in the dialkylaminoalkyl groups, when taken together, may form a morpholino, piperidino or piperazino ring; or R.sup.4 is a group of the formula --(CH.sub.2 CH.sub.2 O).sub.n --R with n being 1, 2 or 3 and R being hydrogen; lower alkyl, dialkylaminoalkoxyalkyl or alkylthioalkoxyalkyl, the alkyl groups in dialkylaminoalkoxyalkyl, when taken together, may form a piperidino, pyrrolidino, hexamethylenimino, morpholino or piperazino ring; or R.sup.4 is a group of the formula --(CH.sub.2).sub.m --CH.dbd.CH--R with m being an integer of from 0 to 5, or R.sup.4 is a radical of the formula ##STR32## wherein R.sup.5 and R.sup.6, which may be the same or different, are hydrogen, fluorine, chlorine, phenyl, lower alkyl, lower alkoxy, C.sub.1-4 acylamino, carboxy, cyano, carbonamido, mono- or di-alkylcarbonamido, carboalkoxy, sulfo, sulfonamido, mono- or di-alkyl-sulfonamido, alkyloxysulfonyl, two vicinal radicals R.sup.5 and R.sup.6, when taken together, may form lower alkylene, a fused benzo ring or 1,3-dioxapropylene; B is a polycyclic aromatic radical having at least three condensed rings; C is amino, substituted by one or two alkyl, hydroxyalkyl, acyl or phenyl groups, and two alkyl groups, when taken together with the nitrogen atom of the amino group may form a pyrrolidino or piperidino ring or, when taken together with a further nitrogen or oxygen atom, a piperazino or morpholino ring; or C is alkoxy, hydroxyalkyl, acyloxy, alkylthio or carbalkylmercapto; D independent from C is defined as C and may further stand for a chlorine atom.
2. Mixtures according to claim 1, containing a compound of the formula I, wherein X, A, R.sup.1 and R.sup.2 are defined as in claim 1 and R.sup.4 stands for a member of the following group; C.sub.1-6 alkyl, C.sub.1-6 chloroalkyl, dimethyl- or diethylamino-C.sub.1-4 alkyl, morpholinoethyl, N-.beta.-piperidinoethyl, N-.beta.-(N'-methylpiperazino)-ethyl, benzyl, phenoxy-C.sub.1-4 alkyl, chlorphenoxy-C.sub.1-4 alkyl, C.sub.1-4 alkylmercapto-C.sub.1-4 -alkyl, phenylmercapto-C.sub.1-4 alkyl, phenyl, C.sub.1-6 -alkylphenyl, di-C.sub.1-6 alkylphenyl, chlorphenyl, dichlorophenyl, C.sub.1-6 alkoxyphenyl or .beta.-naphthyl or a group of the formula --(CH.sub.2 CH.sub.2 O).sub.n --R with n being 1, 2 or 3 and R being hydrogen, C.sub.1-7 alkyl, C.sub.1-4 alkylmercapto-C.sub.1-4 -alkyl, dimethyl- or diethylamino-C.sub.1-4 alkyl or morpholino-C.sub.1-4 alkyl, and a compound of the formula IV wherein B is a pyrene ring and C and D independent from each other each are C.sub.1-4 alkoxy.
3. Mixtures according to claim 1, containing a compound of the formula I wherein X is O or S, R.sup.1 and R.sup.2 in 5-, 6- or 7-position each are hydrogen or chlorine atoms, C.sub.1-4 alkyl, phenyl or, when taken together, a fused benzo ring and R.sup.4 in the group A is C.sub.1-6 alkyl, C.sub.1-6 -chloroalkyl, C.sub.1-4 alkoxy-C.sub.1-4 -alkyl, hydroxy-C.sub.1-4 alkyl or a group of the formula --(CH.sub.2 CH.sub.2 O).sub.n --R' when n being 2 or 3 and R' being hydrogen or C.sub.1-4 alkyl, and a compound of the formula IV wherein B is a pyrene ring and C and D independent from each other are C.sub.1-4 alkoxy.
4. Mixtures as claimed in claim 1 containing a compound of the formula I wherein X is oxygen, R.sup.1 in 5 position is hydrogen or chlorine, methyl or phenyl, R.sup.2 is hydrogen or R.sup.1 and R.sup.2, when taken together, are methyl in 5,6- or 5,7-position and R.sup.4 in the group A is methyl, ethyl, n- or iso-propyl, n- or isobutyl, pentyl, chloromethyl, .beta.-chloroethyl, .beta.-hydroxyethyl, .beta.-methoxyethyl, .beta.-ethoxyethyl, benzyl, phenyl, o-tolyl, p-tolyl, 2,4-dimethylphenyl, o-chlorphenyl, p-chlorophenyl, 2,4-dichlorophenyl or p-methoxyphenyl and a compound of the formula IV wherein B is a pyrene ring and C and D independent from each other each are C.sub.1-4 alkoxy.
5. Process of using mixtures as claimed in any one of claim 1 to 4 for the optical brightening.
Patent Citations (1)
| Patent | Date | Inventor | Cited By |
|---|---|---|---|
| US4129412 | 1978-12-01 | Gunther et al. |