US 4,228,043 AGrant
Liquid Detergent Composition
Issue Date:1980-10-14
•2 Claims
Abstract
In a process for making an aqueous built liquid detergent composition comprising sodium tripolyphosphate and alkalimetal orthophosphate, the formation of alkalimetal orthophosphate in situ by neutralization may cause some sediment. This sediment formation is significantly reduced by the addition of a small amount of an alkanolamine such as triethanolamine to the liquid detergent composition.
Metadata
Assignee
- Lever Brothers Company
Inventor
- Guido C. van den Brom
Application Information
Application Number:US 9347399
Filing Date:1978-08-21
Priority Date:1977-08-22
Art Unit:166
Classifications
IPC:
C11D 306C11D 330C11D 1104C11D 1708
Field of Search:
252110;111;117;118;173;363.5;529;548;DIG. 14
Patent Drawings
This patent does not have any drawings.
Description
The present invention relates to aqueous built liquid detergent compositions, and more particularly to such compositions comprising a mixture of sodium tripolyphosphate and an alkalimetal orthophosphate as the builder component.
Such formulations are the object of applications Ser. Nos. 799,861 and 798,556 which are herein incorporated by reference. In these applications we have described and claimed compositions, which contain 2-20% by weight of an active detergent, at least 2% by weight of sodium tripolyphosphate, at least 2% by weight of an alkalimetal orthophosphate, the sum of the two phosphate builders being 5-35% by weight, and a hydrotrope or a stabilizing system.
According to these earlier applications, it is possible to prepare the orthophosphate builder salt in situ, by neutralizing orthophosphoric acid, added to the formulation, by a suitable base such as potassium hydroxide.
However, such a procedure might cause some sediment in the liquid composition, which detracts from the otherwise satisfactory properties of these products.
It has now been found that this problem can be overcome by adding a small amount of an alkanolamine to such systems.
The present invention therefore relates to an aqueous built liquid detergent composition of the type as described above, in which the alkalimetal orthophosphate is produced in situ by neutralization of orthophosphoric acid, wherein the improvement consists in adding a small amount of an alkanolamine to said liquid detergent composition.
An additional benefit of the present invention is that it also enables to prepare compositions with a higher level of sodium tripolyphosphate, i.e. above about 12% by weight of the composition, without having to use a particular type of sodium tripolyphophate, i.e. a rapidly hydrating one or one which has a high phase I content, as is advocated in the above-mentioned applications.
The alkanolamine to be used in the present invention is a mono-, di-or trialkanolamine, wherein the alkanol is ethanol, propanol or isopropanol. Particularly preferred is triethanolamine. In general the alkanolamine is used in an amount of from 0.5 to 5% by weight of the composition.
The amount of orthophosphoric acid, neutralized in situ by an appropriate neutralizing agent, such as KOH, is such that it provides an amount of the alkalimetal orthophosphate within the ranges as specified in the above-mentioned applications.
The other ingredients of the composition of the invention are as described and claimed in the above-mentioned applications, which are herein incorporated by reference.
Example I
The following liquid detergent composition was prepared.
This liquid was a clear, stable liquid, pourable at 0.degree. C. It had a pH of 12.5, and a viscosity of 200 cP (Brookfield viscosimeter, spindle nr. 3 at 30 rpm, temperature 22.degree. C.).
Example Ii
The following liquid detergent compositions were prepared.
Product A had a viscosity of 200 cP (Brookfield, spindle 3, 30 rpm, temperature 22.degree. C.) and a pH of 12.5, and was clear and stable on storage down to -5.degree. C.
Product B was clear and stable for several months at room temperature. At 0.degree. C. some thickening occurred, but no solidification. In washing machine experiments, even with clean fabrics, no overfoaming occurred.
Example Iii
The following clear, high-sudsing liquid detergent was prepared.
Claims
I claim:
1. In a process for the preparation of an aqueous built liquid detergent composition containing 2 to 20% by weight of an active detergent, at least about 12% by weight of sodium tripolyphosphate, at least 2% by weight of an alkalimetal orthophosphate in which the alkali metal orthophosphate is produced in situ by neutralizing orthophosphoric acid by a suitable base, the sum of the two phosphate builders being about 14% to about 35% by weight, and a hydrotrope or stabilizing system, the improvement which comprises the step of adding from 0.5% to 5% by weight of a mono-, di- or trialkanolamine, wherein the alkanol constituent is ethanol, propanol or isopropanol.
2. The process of claim 1 wherein the alkanolamine is triethanolamine.
Patent Citations (4)
| Patent | Date | Inventor | Cited By |
|---|---|---|---|
| US2335466 | 1943-11-01 | Volz | |
| US3021284 | 1962-02-01 | Doan | |
| US4018720 | 1977-04-01 | Lengyel | |
| GBX1093935 | 1967-12-01 |