US 4,089,692 AGrant
Settable Composition Containing Aluminum Phosphate and Method for Preparing Same
Issue Date:1978-05-16
•34 Claims
Abstract
Settable composition comprising aluminum phosphate, solid organic carboxylic acid, water, and material containing an alkaline earth metal and an oxide, and being obtained by providing an admixture of the above constituents whereby the solid organic carboxylic acid and alkaline earth material are not precontacted with each other prior to contact of the material containing an alkaline earth material with the aluminum phosphate, and process for preparing same are provided.
Metadata
Assignee
- Ashland Oil, Inc.
Inventors
- Richard H. Toeniskoetter
- John J. Spiwak
Application Information
Application Number:US 5881218
Filing Date:1975-06-18
Priority Date:1974-03-27
Art Unit:143
Classifications
IPC:
B28B 734
Field of Search:
10638.3;38.35;286;38.9;85
Patent Drawings
This patent does not have any drawings.
Description
Example 1
To a round bottom, 3 liter, 3-necked reaction flask fitted with a heating mantle, mechanical stirrer, reflux condenser and thermometer are added 1650 parts of 85% phosphoric acid. Under mild agitation, 50 parts of granular boric acid are charged to yield a boric acid-phosphoric acid dispersion. The boric acid is added as a smooth steady "stream", as opposed to dumping in bulk, to avoid clumping. To the agitated dispersion are added 310 parts of hydrated alumina (Alcoa, C-33 grade) as a smooth steady stream to give a milky-white slurry.
The reaction mass is heated to a temperature of about 110.degree.-120.degree. F in about 1/2 hour at which time external heat is removed. The reaction is continued for about another 20 to 30 minutes with the temperature rising to a maximum of about 220.degree.-230.degree. F due to the reaction exotherm. Then external heat is applied and reaction temperature rises to a maximum of about 245.degree.-250.degree. F at which point refluxing occurs. The reaction mass is held at about 245.degree.-250.degree. F for about 1.5-2 hours to ensure complete reaction. The reaction mass is cooled to about 200.degree. F in about 45 minutes at which time about 260 parts of water are slowly added with agitation. The temperature of the reaction mass then drops to about 150.degree.-160.degree. F. About 2270 parts of product are then collected in glass-line polypropylene containers. The product is a boronated aluminum phosphate product having a solids content of 66.6%, a viscosity of 700-750 centipoises, mole ratio of phosphorus to total moles of aluminum and boron of 3:1, and about 20 mole % boron based upon the moles of aluminum; a pH of 1.5-2.0 and Gardner color of 2.
5000 parts of Port Crescent sand and about 25 parts of a mixture of magnesium oxide having a surface area of about 2.3 m.sup.2 /gram (Magmaster 1-A) and Calcium Aluminate (Refcon) in a ratio of 5 parts of magnesium oxide to 1 part of calcium aluminate are admixed for about 2 minutes. To this mixture are added a mixture of about 158 parts of the boronated aluminum phosphate product prepared above and about 7 parts of gluconic acid. The mixture is then agitated for 2 minutes.
The resulting foundry mix is formed by hand ramming into standard AFS tensile strength samples using the standard procedure. The tensile strength of the test bars and core hardness are set forth in Table I below. The composition has a work time of about 19 minutes and a strip time of about 62 minutes.
Example 2
Example 1 is repeated except that about 10.3 parts of gluconic acid and about 154.7 parts of the boronated aluminum phosphate are employed. The resulting foundry mix is formed into standard AFS tensile strength samples using the standard procedure. The tensile strength of the test bars and core hardness are set forth below in Table I. The composition has a work time of about 23 minutes and a strip time of about 58 minutes.
Example 3
Example 1 is repeated except that about 16.5 parts of gluconic acid and about 148.5 parts of the boronated aluminum phosphate are employed. The resulting foundry mix is formed into standard AFS tensile strength samples using the standard procedure. The tensile strength of the test bars and core hardness are set forth below in Table I. The composition has a work time of about 18 minutes and a strip time of about 55 minutes.
Example 4
Example 1 is repeated except that 165 parts of the boronated aluminum phosphate without any gluconic acid are employed. The resulting foundry mix is formed into standard AFS tensile strength samples using the standard procedure. The tensile strength of the test bars and core hardness are set forth in Table I below. The composition has a work time of about 14 minutes and a strip time of about 40 minutes.
Example 5
5000 parts of Port Crescent Lake sand and about 25 parts of a mixture of magnesium oxide having a surface area of about 2.3 m.sup.2 /gram (Magmaster 1-A) and calcium aluminate (Refcon) in a ratio of 5 parts of magnesium oxide to 1 part of calcium aluminate are admixed for about 2 minutes. To this mixture are added a mixture of about 156.65 parts of an aluminum phosphate prepared along the lines of the procedure in Example 1 and having a solids content of 66.6%, viscosity of 700-750 centipoises, mole ratio of phosphorus to total moles of aluminum and boron of 3:1, about 20 mole % boron based upon the moles of aluminum, pH of 1.5-2.0 and Gardner color of 2, and about 8.35 parts of d-tartaric acid. The mixture is then agitated for 2 minutes.
The resulting foundry mix is formed into standard AFS tensile strength samples using the standard procedure. The tensile strength of the test bars and core hardness are set forth below in Table II. The composition has a work time of about 16 minutes and a strip time of about 52 minutes.
Example 6
Example 5 is repeated except that about 13.5 parts of d-tartaric acid and about 151.5 parts of the boronated aluminum phosphate are employed. The resulting foundry mix is formed into standard AFS tensile strength samples using the standard procedure. The tensile strength of the test bars and core hardness are set forth below in Table II. The composition has a work time of about 15 minutes and a strip time of about 51 minutes.
Example 7
Example 5 is repeated escept that about 2 parts of d-tartaric acid and about 163 parts of the boronated aluminum phosphate are employed. The resulting foundry mix is formed into standard AFS tensile strength samples using the standard procedure. The tensile strength of the test bars and core hardness are set forth below in Table II. The composition has a work time of about 16 minutes and a strip time of about 58 minutes.
Example 8
Example 5 is repeated except that about 4 parts of d-tartaric acid and about 161 parts of the boronated aluminum phosphate are employed. The resulting foundry mix is formed into standard AFS tensile strength samples using the standard procedure. The tensile strength of the test bars and core hardness are set forth below in Table II. The composition has a work time of about 15 minutes and a strip time of about 42 minutes.
Example 9
Example 5 is repeated except that 165 parts of the boronated aluminum phosphate without any d-tartaric acid are employed. The resulting foundry mix is formed into standard AFS tensile strength samples using the standard procedure. The tensile strength of the test bars and core hardness are set forth below in Table II. The composition has a work time of about 14 minutes and a strip time of about 40 minutes.
Example 10
5000 parts of Port Crescent Lake sand and about 35 parts of a mixture of magnesium oxide having a surface area of about 2.3 m.sup.2 /gm (Magmaster 1-A) and calcium aluminate (Refcon) in a ratio of 5 parts of magnesium oxide to 1 part of calcium aluminate are admixed for about 2 minutes. To this mixture are added a mixture of about 156.65 parts of an aluminum phosphate prepared along the lines of the procedure in Example 1 and having a solids content of 66.6%, viscosity of 700-750 centipoises, mole ratio of phosphorus to total moles of aluminum and boron of 3:1, about 20 mole % boron based upon the moles of aluminum, pH of 1.5-2.0 and Gardner color of 2, and about 8.35 parts of malonic acid. The mixture is then agitated for 2 minutes.
The resulting foundry mix is formed into standard AFS tensile strength samples using the standard procedure. The tensile strength of the text bars and core hardness are set forth below in Table III. The composition has a work time of about 18 minutes and a strip time of about 58 minutes.
Example 11
Example 10 is repeated except that about 16.3 parts of malonic acid and about 148.7 parts of the boronated aluminum phosphate are employed. The resulting foundry mix is formed into standard AFS tensile strength samples using the standard procedure. The tensile strength of the test bars and core hardness are set forth below in Table III. The composition has a work time of about 23 minutes and a strip time of about 77 minutes.
Example 12
Example 10 is repeated except that about 2 parts of malonic acid and about 163 parts of the boronated aluminum phosphate are employed. The resulting foundary mix is formed into standard AFS tensile strength samples using the standard procedure. The tensile strength of the text bars and core hardness are set forth below in Table III. The composition has a work time of about 15 minutes and a strip time of about 46 minutes.
Example 13
Example 10 is repeated except that about 4 parts of malonic acid and about 161 parts of the boronated aluminum phosphate are employed. The resulting foundry mix is formed into standard AFS tensile strength samples using the standard procedure. The tensile strength of the test bars and core hardness are set forth below in Table III. The composition has a work time of about 17 minutes and a strip time of about 54 minutes.
Example 14
Example 10 is repeated except that 165 parts of the boronated aluminum phosphate without any malonic acid are employed. The resulting foundry mix is formed into standard AFS tensile strength samples using the standard procedure. The tensile strength of the test bars and core hardness are set forth below in Table III. The composition has a work time of about 14 minutes and a strip time of about 40 minutes.
Example 15
5000 parts of Port Crescent Lake sand and about 35 parts of a mixture of magnesium oxide having a surface area of about 2.3 m.sup.2 /gm (Magmaster 1-A) and calcium aluminate (Refcon) in a ratio of 5 parts of magnesium oxide to 1 part of calcium aluminate are admixed for about 2 minutes. To this mixture are added a mixture of about 156.65 parts of an aluminum phosphate prepared along the lines of the procedure in Example 1 and having a solids content of 66.6%, viscosity of 700-750 centipoises, mole ratio of phosphorus to total moles of aluminum and boron of 3:1, about 20 mole % boron based upon the moles of aluminum, pH of 1.5-2.0 and Gardner color of 2, and about 8.35 parts of citric acid. The mixture is then agitated for 2 minutes.
The resulting foundry mix is formed into standard AFS tensile strength samples using the standard procedure. The tensile strength of the test bars and core hardness are set forth below in Table IV. The composition has a work time of about 15 minutes and a strip time of about 54 minutes.
Example 16
Example 15 is repeated except that about 16.3 parts of citric acid and about 148.7 parts of the boronated aluminum phosphate are employed. The resulting foundry mix is formed into standard AFS tensile strength samples using the standard procedure. The tensile strength of the text bars and core hardness are set forth below in Table IV. The composition has a work time of about 23 minutes and a strip time of about 71 minutes.
Example 17
Example 15 is repeated except that about 2 parts of citric acid and about 163 parts of the boronated aluminum phosphate are employed. The resulting foundry mix is formed into standard AFS tensile strength samples using the standard procedure. The tensile strength of the test bars and core hardness are set forth below in Table IV. The composition has a work time of about 18 minutes and a strip time of about 53 minutes.
Example 18
Example 15 is repeated except that about 4 parts of citric acid and about 161 parts of the boronated aluminum phosphate are employed. The resulting foundry mix is formed into standard AFS tensile strength samples using the standard procedure. The tensile strength of the test bars and core hardness are set forth below in Table IV. The composition has a work time of about 18 minutes and a strip time of about 53 minutes.
Example 19
Example 15 is repeated except that 165 parts of the boronated aluminum phosphate without any citric acid are employed. The resulting foundry mix is formed into standard AFS tensile strength samples using the standard procedure. The tensile strength of the test bars and core hardness are set forth below in Table IV. The composition has a work time of about 14 minutes and a strip time of about 40 minutes.
Example 20
5000 parts of Port Crescent Lake sand and about 35 parts of a mixture of magnesium oxide having a surface area of about 2.3 m.sup.2 /gm (Magmaster 1-A) and calcium aluminate (Refcon) in a ratio of 5 parts of magnesium oxide to 1 part of calcium aluminate are admixed for about 2 minutes. To this mixture are added a mixture of about 156.65 parts of an aluminum phosphate prepared along the lines of the procedure in Example 1 and having a solids content of 66.6%, viscosity of 700-750 centipoises, mole ratio of phosphorus to total moles of aluminum and boron of 3:1, about 20 mole % boron based upon the moles of aluminum, pH of 1.5-2.0 and Gardner color of 2, and about 8.35 parts of oxalic acid. The mixture is then agitated for 2 minutes.
The resulting foundry mix is formed into standard AFS tensile strength samples using the standard procedure. The tensile strength of the test bars and core hardness are set forth below in Table V. The composition has a work time of about 17 minutes and a strip time of about 60 minutes.
Example 21
Example 20 is repeated except that about 16.3 parts of oxalic acid and about 148.7 parts of the boronated aluminum phosphate are employed. The resulting foundry mix is formed into standard AFS tensile strength samples using the standard procedure. The tensile strength of the test bars and core hardness are set forth below in Table V. The composition has a work time of about 26 minutes and a strip time of about 75 minutes.
Example 22
Example 20 is repeated except that about 2 parts of oxalic acid and about 163 parts of the boronated aluminum phosphate are employed. The resulting foundry mix is formed into standard AFS tensile strength samples using the standard procedure. The tensile strength of the test bars and core hardness are set forth below in Table V. The composition has a work time of about 17 minutes and a strip time of about 52 minutes.
Example 23
Example 20 is repeated except that about 4 parts of oxalic acid and about 161 parts of the boronated aluminum phosphate are employed. The resulting foundry mix is formed into standard AFS tensile strength samples using the standard procedure. The tensile strength of the test bars and core hardness are set forth below in Table V. The composition has a work time of about 19 minutes and a strip time of about 51 minutes.
Example 24
Example 20 is repeated except that 165 parts of the boronated aluminum phosphate without any oxalic acid are employed. The resulting foundry mix is formed into standard AFS tensile strength samples using the standard procedure. The tensile strength of the test bars and core hardness are set forth below in Table V. The composition has a work time of about 14 minutes and a strip time of about 40 minutes.
Example 25
To a reaction vessel equipped with a stirrer, thermometer, and reflux condenser are added about 2445 parts of 85% phosphoric acid. Then about 67 parts of sodium borate are added with agitation, and the agitation is continued for about 10 minutes until the borate dissolves in the acid to form a clear solution. To this solution are added about 540 parts of hydrated alumina (Alcoa C-33) under agitation. The reaction proceeds for about 40 minutes with the temperature rising to a maximum of about 220.degree. F due to the reaction exotherm. Then external heat is applied and reaction temperature rises to a maximum of about 245.degree. F. The reaction mass is held at about 245.degree. F for about 2 hours to ensure complete reaction. The reaction mass is then cooled to room temperature and about 3052 parts of a boronated aluminum phosphate having a solids content of about 75%, a viscosity of about 40,000 centipoises, a mole ratio of phosphorus to total moles of aluminum and boron of 3:1 and about 10 mole % boron based upon the moles of aluminum are obtained. This aluminum phosphate is diluted with water to provide a solids content of about 66% and having a viscosity of 400-500 centipoises.
5000 parts of Port Crescent Lake sand and about 30.5 parts of a mixture of magnesium oxide (Magmaster 1-A) and a calcium aluminate containing 58% Al.sub.2 O.sub.3 and 33% CaO (Refcon) in a ratio of 5 parts of magnesium oxide to 1 part of calcium aluminate are mixed for about 2 minutes. To this mixture are added a mixture of about 156.6 parts of the 66% solids solution of the boronated aluminum phosphate prepared above and about 8.4 parts of d-tartaric acid. The mixture is then agitated for 2 minutes. The resulting foundry mix is formed by hand ramming into standard AFS tensile strength samples using the standard procedure. The tensile strength of the test bars and core hardness are set forth below in Table VI. The composition has a work time of about 11 minutes and a strip time of about 32 minutes.
Example 26
Example 25 is repeated except that 165 parts of the boronated aluminum phosphate without any organic carboxylic acid are employed. The resulting foundry mix is formed into standard AFS tensile strength samples using the standard procedure. The tensile strength of the test bars and core hardness are set forth below in Table VI. The composition has a work time of about 13 minutes and a strip time of about 42 minutes.
Example 27
Example 25 is repeated except that a boronated aluminum phosphate containing 20 mole % boron and 20 mole % sodium based upon the aluminum and prepared according to the procedure of Example 25 is employed. The resulting foundry mix is formed by hand ramming into standard AFS tensile strength samples using the standard procedure. The tensile strength of the test bars and core hardness are set forth below in Table VII. The composition has a work time of about 12 minutes and a strip time of about 30 minutes.
Example 28
Example 27 is repeated except that 165 parts of the boronated aluminum phosphate without any organic carboxylic acid are employed. The resulting foundry mix is formed into standard AFS tensile strength samples using the standard procedure. The tensile strength of the test bars and core hardness are set forth below in Table VII. The composition has a work time of about 15 minutes and a strip time of about 38 minutes.
A comparison of Examples 1-3 with 4, Examples 5-8 with 9, Examples 10-13 with 14, Examples 15-18 with 19, Examples 20-23 with 24, Example 25 with 26, and Example 27 with 28 demonstrates that after storage for several hours, the general trend is improvement in physical properties such as tensile strength and core hardness due to the presence of the type of organic carboxylic acids employed in the present invention, although a few of the samples do not fit the general behavior due to some normal experimental error. Although the systems of the present invention may not possess as great initial physical properties as those corresponding systems which do not include the organic carboxylic acids, the higher physical properties after storage for several hours is quite important from a practical and commercial viewpoint.
The following Examples 29-33 demonstrate that the use of organic carboxylic acids outside the scope of the present invention does not result in the type of improved tensile strengths as is obtained by practicing the present invention.
Example 29
3000 parts of Port Crescent Lake sand and about 20 parts of a mixture of magnesium oxide having a surface area of about 2.3 m.sup.2 /gm (Magmaster 1-A) and calcium aluminate (Refcon) in a ratio of 5 parts of magnesium oxide to 1 part of calcium aluminate are admixed for about 2 minutes. To this mixture are added a mixture of about 94.1 parts of an aluminum phosphate prepared along the lines of the procedure in Example 1 and having a solids content of 66.6%, viscosity of 700-750 centipoises, mole ratio of phosphorus to total moles of aluminum and boron of 3:1, about 20 mole % boron based upon the moles of aluminum, pH of 1.5-2.0 and Gardner color of 2, and about 1.9 parts of acetic acid. The mixture is then agitated for 2 minutes.
The resulting foundry mix is formed into standard AFS tensile strength samples using the standard procedure. The tensile strength of the test bars and core hardness are set forth below in Table VIII.
Example 30
Example 29 is repeated except that about 4.8 parts of acetic acid and about 9.12 parts of the boronated aluminum phosphate are employed. The resulting foundry mix is formed into standard AFS tensile strength samples using the standard procedure. The tensile strength of the test bars and core hardness are set forth below in Table VIII.
Example 31
Example 29 is repeated except that about 7.7 parts of acetic acid and about 88.3 parts of the boronated aluminum phosphate are employed. The resulting foundry mix is formed into standard AFS tensile strength samples using the standard procedure. The tensile strength of the test bars and core hardness are set forth below in Table VIII.
Example 32
Example 29 is repeated except that about 9.6 parts of acetic acid and about 86.4 parts of the boronated aluminum phosphate are employed. The resulting foundry mix is formed into standard AFS tensile strength samples using the standard procedure. The tensile strength of the test bars and core hardness are set forth below in Table VIII.
Example 33
Example 29 is repeated except that 96 parts of the boronated aluminum phosphate without any acetic acid are employed. The resulting foundry mix is formed into standard AFS tensile strength samples using the standard procedure. The tensile strength of the test bars and core hardness are set forth below in Table VIII.
Claims
What is claimed is:
1. Process for preparing settable composition comprising: (A) providing aluminum phsophate; (B) providing solid organic carboxylic acid; (C) providing oxygen-containing alkaline earth compound; (D) providing water; and (E) admixing said aluminum phosphate, said solid organic carboxylic acid, said alkaline earth material, and water provided that said solid organic carboxylic acid and said alkaline earth material are not precontacted with each other prior to contact of the alkaline earth material with the aluminum phosphate; and (F) wherein said aluminum phosphate contains 0 to about 40 mole % of boron based upon the moles of aluminum and contains a mole ratio of phosphorus to total moles of aluminum and boron of at least about 2:1; (G) said solid organic carboxylic acid being soluble in aqueous solutions of the aluminum phosphate and containing at least two substituents selected from the group consisting of at lease two carboxylic acid groups; and at lease one carboxylic acid group, and at least one hydroxyl group, or keto tautomers thereof; (H) said alkaline earth metal compound contains alkaline earth metal and an oxide; and is capable of reacting with the aluminum phosphate; and (I) wherein the amount of aluminum phosphate is from about 50 to about 95% by weight based upon the total weight of aluminum phosphate and alkaline earth compound; the amount of alkaline earth compound is from about 50 to about 5% by weight based upon the total weight of aluminum phosphate and alkaline earth compound; the amount of water is from about 15 to about 50% by weight based upon the total weight of aluminum phosphate and water; and the amount of said acid is from about 0.5 to about 25% by weight based upon the total weight of aluminum phosphate, and acid.
2. The process of claim 1 wherein said aluminum phosphate contains boron in an amount from about 3 to about 40 mole % based upon the moles of aluminum.
3. The process of claim 1 wherein said aluminum phosphate contains boron in an amount from about 5 to about 30 mole % based upon the moles of aluminum.
4. The process of claim 1 wherein said aluminum phosphate contains boron in an amount from about 10 to about 25 mole % based upon the moles of aluminum.
5. The process of claim 1 wherein the aluminum phosphate contains a mole ratio of phosphorus to total moles of aluminum and boron of from about 2.5:1 to about 3.5:1.
6. The process of claim 1 wherein the aluminum phosphate contains a mole ratio of phosphorus to total moles of aluminum and boron of from about 2.8:1 to about 3.2:1.
7. The process of claim 1 wherein said aluminum phosphate contains boron in an amount between about 10 and about 25 mole % based upon the moles of aluminum, and wherein the mole ratio of phosphorus to total moles of aluminum and boron is between about 2.8:1 to about 3.2:1.
8. The process of claim 1 wherein the amount of said aluminum phosphate is from about 65 to about 90% by weight based upon the total weight of aluminum phosphate and alkaline earth compound, and the amount of alkaline earth compound is from about 10 to about 35% by weight based upon the total weight of aluminum phosphate and alkaline earth compound.
9. The process of claim 1 wherein said solid organic carboxylic acid contains 2 to about 20 carbon atoms.
10. The process of claim 1 wherein said solid organic carboxylic acid contains from about 2 to about 10 carbon atoms.
11. The process of claim 1 wherein said organic carboxylic acid contains from about 2 to about 20 reactive groups.
12. The process of claim 1 wherein said organic carboxylic acid is selected from the group consisting of tartaric acid, gluconic acid, oxalic acid, citric acid, malonic acid, lactic acid, and mixtures thereof.
13. The process of claim 1 wherein said solid organic carboxylic acid is tartaric acid.
14. The process of claim 1 wherein said solid organic carboxylic acid is gluconic acid.
15. The process of claim 1 wherein the amount of organic carboxylic acid is from about 2 to about 15% by weight based upon the total weight of the aluminum phosphate and organic carboxylic acid.
16. The process of claim 1 wherein said alkaline earth compound includes a free alkaline earth metal oxide or a free alkaline earth metal hydroxide and wherein said oxide or hydroxide has a surface area no greater than about 8.5 m.sup.2 /gram (measured by the BET procedure).
17. The process of claim 16 wherein said alkaline earth metal oxide of free alkaline earth metal hydroxide has a surface area no greater than about 3 m.sup.2 /gram.
18. The process of claim 1 wherein said alkaline earth metal compound is a mixture of a free alkaline earth metal oxide and a material which contains the alkaline earth metal and oxide in combination with another constituent and wherein said alkaline earth compound has a surface area no greater than about 8.5 m.sup.2 /gram.
19. The process of claim 18 wherein said alkaline earth metal oxide is magnesium oxide.
20. The process of claim 18 wherein said mixture contains from about 2 to about 8 parts by weight of the free alkaline earth metal oxide per part by weight of the material containing another constituent in combination with the free metal oxide and/or hydroxide and alkaline earth metal.
21. The process of claim 1 wherein the amount of water is from about 20 to about 40% by weight based upon the total weight of the aluminum phosphate and water.
22. A settable composition comprising: (A) aluminum phosphate containing 0 to about 40 mole % of boron based upon the moles of aluminum and containing a mole ratio of phosphorus to total moles of aluminum and boron of at least about 2:1; (B) solid organic carboxylic acid being soluble in aqueous solutions of the aluminum phosphate and containing at least two substituents selected from the group consisting of at least two carboxylic acid groups; and at least one carboxylic acid group and at least one hydroxyl group; or keto derivatives thereof; (C) oxygen-containing alkaline earth compound containing alkaline earth metal and an oxide; and being capable of reacting with said aluminum phosphate; and (D) water; and wherein the amount of the alkaline earth compound is from about 50 to about 5% by weight based upon the total weight of the aluminum phosphate and alkaline earth compound; the amount of the aluminum phosphate is from about 95 to about 50% by weight based upon the total weight of the aluminum phosphate and alkaline earth compound; the amount of water is from about 15 to about 50% by weight based upon the total weight of the aluminum phosphate and water; and the amount of the solid organic carboxylic acid is from about 0.5 to about 25% by weight based upon the total weight of aluminum phosphate and acid; and wherein said composition is obtained by providing an admixture of said aluminum phosphate, said solid organic carboxylic acid, said alkaline earth material, and said water wherein the solid organic carboxylic acid and alkaline earth material are not precontacted with each other prior to contact of the alkaline earth material with the aluminum phosphate.
23. Molding composition which comprises: (A) a major amount of aggregate; and (B) an effective bonding amount up to about 40% by weight of the aggregate of the composition of claim 22.
24. The process of claim 1 wherein said solid organic carboxylic acid is oxalic acid.
25. The process of claim 1 wherein said solid organic carboxylic acid is citric acid.
26. The process of claim 1 wherein said solid organic carboxylic acid is malonic acid.
27. The process of claim 1 wherein said solid organic carboxylic acid is lactic acid.
28. The process of claim 2 wherein said solid organic carboxylic acid is tartaric acid.
29. The process of claim 2 wherein said solid organic carboxylic acid is gluconic acid.
30. The process of claim 2 wherein said solid organic carboxylic acid is oxalic acid.
31. The process of claim 2 wherein said solid organic carboxylic acid is citric acid.
32. The process of claim 2 wherein said solid organic carboxylic acid is malonic acid.
33. The process of claim 2 wherein said solid organic carboxylic acid is lactic acid.
34. The process of claim 2 wherein said organic carboxylic acid is selected from the group consisting of tartaric acid, gluconic acid, oxalic acid, citric acid, malonic acid, lactic acid, and mixtures thereof.
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