Process for Manufacturing Carbonyl Compounds by Oxidation With Molecular Oxygen of Olefinic Compounds in Liquid Phase in the Presence of Soluble Bimetallic Catalysts
Abstract
Carbonyl compounds are manufactured by oxidation of olefines with molecular oxygen in the presence of a catalytic system comprising both a specific rhodium compound and a specific compound of a metal selected from iron, cobalt, nickel and copper. The reaction is conducted in a substantially anhydrous organic solvent selected from alcohols, polyols and glycol monoethers. where X is chlorine or bromine and olefin is ethylene, propylene, tetrafluorethylene or cyclooctene; for example [RhCl (C.sub.2 H.sub.4).sub.2 ].sub.2 where C.sub.2 H.sub.4 is ethylene. where X is chlorine or bromine, and polyolefin is 1,5-cyclooctadiene, 1,5-hexadiene, butadiene or cyclododecatriene, for example [RhCl (C.sub.8 H.sub.12)].sub.2 where C.sub.8 H.sub.12 is 1,5-cyclooctadiene. where "acac" is an acetylacetonate group and olefin is ethylene or tetrafluorethylene. where HMPT is hexamethylphosphoramide. The present invention concerns a process for manufacturing carbonyl compounds, particularly methyl ketones, in the liquid phase, by the catalytic oxidation of olefins with molecular oxygen, in a substantially anhydrous medium and in the presence of soluble bimetallic catalysts. In the processes of the Wacker type for converting olefins to ketones (U.S. Pat. No. 3,080,425), the catalysts are, for example, palladium chloride or rhodium oxyhydrate associated with copper chloride or iron sulfate; these processes are operated in the aqueous phase and water is the oxidizing agent for the reaction. According to the French Pat. No. 1,210,009, rhodium, iridium or palladium chloride associated with copper chloride is also used as catalyst for oxidizing olefins in the aqueous phase, and water is the oxidizing agent. According to the two above patents, it is essential to operate in a strongly acidic medium (concentrated acids are employed). Other patents also utilize the presence of water to carry out reactions of the same kind in an organic solvent with palladium catalysts of the same type: French Pat. Nos. 1,564,635 and 1,395,129; U.S. Pat. No. 3,370,073. The process according to the invention is performed essentially in the liquid phase, in a water-free solvent, in the presence of a rhodium catalyst, the other noble metals of the VIIIth group being excluded. Thus, by using rhodium instead of palladium, a metal commonly used in liquid phase, processes far higher selectivities are obtained, particularly when converting terminal olefins to methylketones, as well as far higher reaction rates. According to the process of the invention, the catalyst comprises both at least one organometallic salt or complex [A] and at least one organometallic salt or compound [B], of the general formulas: In the salt of complex [A], M.sub.1 is rhodium. Non-limitative examples of rhodium complexes are: In the salt or complex [B] to be used with the complex A: Non-limitative examples are: This invention applies to branched or unbranched olefinic compounds having from 2 to 16 carbon atoms per molecule and whose general formula is R.sub.1 -- CH .dbd. CH -- R.sub.2 where R.sub.1 and R.sub.2 are identical or not and represent either hydrogen atoms or alkyl, aryl, alkylaryl or aralkyl radicals having 1 - 14 carbon atoms per molecule. According to the invention, there are preferably used primary terminal olefins of the above general formula where R.sub.1 = H and R.sub.2 = alkyl, aryl, alkylaryl or aralkyl; they contain 3 - 16 carbon atoms and yield methylketones selectively. They are thus of the formula CH.sub.2 .dbd. CH -- R.sub.2. From ethylene, there is obtained ethanal. Non-limitative examples are ethylene, propylene, 1-butene, 1-pentene, 1-hexene, 1-heptene, 1-octene, 1-nonene, 1-decene, 1-dodecene, 4-methyl-1-pentene, 3,3-dimethyl-1-butene, 5-methyl-1-hexene and styrene. The primary terminal olefins may be used in a pure state or diluted with other inert or olefinic hydrocarbons. Thus oxidizing partially hydrogenated steam cracking C.sub.4 cuts containing a mixture of olefins such as 1-butene and cis and trans 2-butenes and butane leads selectively to the formation of methylethyl ketone obtained by oxidation of 1-butene, the other olefins being only slightly oxidized. The oxidation reaction is conducted in liquid phase in an organic solvent; the catalyst in the form of its two constituents [A] and [B] being solubilized in the medium. The solvent is an alcohol or a polyalcohol. It comprises preferably from 1 to 20 carbon atoms per molecule. The alcohol may be a primary, secondary or tertiary alcohol; the polyalcohol (or polyol) comprises at least 2 alcohol groups. Examples of solvents are: methanol, ethanol, n-propanol, isopropanol, 2-butanol, 3,3-dimethyl-2-butanol, cyclohexanol, methyl phenyl carbinol, ethylene glycol, 1,2-propane diol and glycerol. Other useful solvents are the glycol monoethers (cellosolves) of the formula R -- O -- CH.sub.2 -- CH.sub.2 OH, particularly methylcellosolve of the formula CH.sub.3 -- O -- CH.sub.2 -- CH.sub.2 OH. The alcoholic or polyalcoholic solvents yield better results than those obtained with other conventional solvents such as ketones, ethers and esters. It is essential that the solvent be substantially anhydrous since, irrespective of the solvent, the reaction improves when the water concentration in the medium decreases. Water may be tolerated, however, at concentrations up to 1% b.w. in the solvent, and preferably not above 0.5%, whenever possible not above 0.2%. A dehydration agent may be added to the medium, if necessary, for example 2,2'-dimethoxypropane. The temperature at which the reaction takes place is from about 0.degree. C to about 150.degree. C, preferably from 30.degree. C to 130.degree. C. The oxidation gas may be pure oxygen or oxygen diluted with nitrogen or any inert gas. The oxygen partial pressure is from 0.1 to 25 bars. Conversely to the prior art processes, it is conducted in substantially neutral medium (pH usually between about 6 and 8). In the process according to the invention, the molar ratio [B]/[A] is usefully from 0.5 to 10 and preferably from 1 to 4. The molar ratio [A]/olefine, in mole per liter, is usefully from 10.sup.-3 to 5 .times. 10.sup.-1, preferably from 5 .times. 10.sup.-3 to 10.sup.-1. The present invention is illustrated by the following examples: X is an anionic group, preferably halogen (usually chlorine of fluorine), a carboxylate, a sulfate, a nitrate, a perchlorate, a thiocyanate, a tetrafluoroborate, an acetyl acetonate or a cyclopentadienyl. n is a integer selected from 1, 2 and 3. L is a coordinate, preferably a water molecule or an organic compound selected preferably from the olefins, diolefins, phosphines, dimethylsulfoxide and an acetylacetonate group. m is an integer from 1 to 3. Rhodium fluoride, RhF.sub.3, 3H.sub.2 O rhodium chloride, RhCl.sub.3, 3H.sub.2 O rhodium bromide, RhBr.sub.3, 2H.sub.2 0 M.sub.2 is a transition metal selected from iron, cobalt, nickel and copper, Z is an anionic group, preferably halogen, a carboxylate, a sulfate, a nitrate, a perchlorate or a tetrafluoroborate. p is an integer selected from 1, 2 and 3. L' is a coordinate, preferably a molecule of water or an organic molecule, for example dimethylformamide, hexamethylphosphoramide or dimethylsulfoxide. q is 0 or an integer from 1 to 6. iron, cobalt, nickel and copper perchlorates and nitrates of the general formulas M.sub.2 (ClO.sub.4).sub.2, 6H.sub.2 O and M.sub.2 (NO.sub.3).sub.2, 6H.sub.2 O. copper and iron halides of the formula M.sub.2 Z.sub.p, .sub.q H.sub.2 O with Z = fluorine, chlorine or bromine and M.sub.2 = iron or copper, p is 2 or 3 and q is 0 or an integer from 1 to 6. complexes such as: Cu (ClO.sub.4).sub.2, 4 L'; Fe (ClO.sub.4).sub.2, 4 L' or Cu (NO.sub.3).sub.2, 4 L', where L' is a coordinate such as dimethylformamide, hexamethylphosphoramide or dimethylsulfoxide; for example:
Metadata
Assignee
- Institut Francais du Petrole
Inventors
- Hubert Mimoun
- Do Thao
- Irenee Seree de Rochi
Application Information
Classifications
Patent Drawings
This patent does not have any drawings.
Description
EXAMPLE 1
EXAMPLE 1 - A (for comparison)
EXAMPLE 1 - B
EXAMPLES 2 TO 13
EXAMPLES 14 - 20
EXAMPLES 21 - 28
EXAMPLES 29 AND 30
EXAMPLE 29
EXAMPLE 30
EXAMPLE 31
Claims
Patent Citations (7)
| Patent | Date | Inventor | Cited By |
|---|---|---|---|
| US3154586 | 1964-10-01 | Bander et al. | |
| US3346624 | 1967-10-01 | Schaeffer et al. | |
| US3365499 | 1968-01-01 | Clement et al. | |
| US3927111 | 1975-12-01 | Robinson | |
| US3932521 | 1976-01-01 | Gloyer et al. | |
| DT2,234,249 | 1973-01-01 | ||
| DT2,205,899 | 1972-08-01 |